Citation: Ling Zhang, Xue Liu, Rui-Xia Yang, Nian-Yu Huang, Wei-Qiao Deng. Environmentally benign and economic synthesis of covalent triazine-based frameworks[J]. Chinese Journal of Catalysis, ;2017, 38(3): 583-588. doi: 10.1016/S1872-2067(17)62771-2 shu

Environmentally benign and economic synthesis of covalent triazine-based frameworks

a Hubei Key Laboratory of Natural Products Research and Development, College of Biological and Pharmaceutical Sciences, China Three Gorges University, Yichang 443002, Hubei, China;
b State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received Date: 30 November 2016
Revised Date: 25 December 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21373202, 21525315).

Covalent triazine-based frameworks (CTFs) are important microporous materials with a wide range of applications. Here, we demonstrate an environmentally benign and economic synthetic pathway to CTFs. The monomers used for CTFs, aromatic nitriles, were obtained by cyanation using nontoxic potassium hexacyanoferrate(II) in place of commonly used toxic cyanides. Then, the CTFs were synthesized by trimerization of the corresponding cyano monomers in molten zinc chloride. A series of CTFs was synthesized, and the highest Brunauer-Emmett-Teller surface area measured in this series was 2404 m²/g. Among the synthesized CTFs, CTF_DCP exhibited excellent CO₂ adsorption properties, with a CO₂ uptake of 225 mg/g at 0℃.
- Covalent triazine-based framework,
- Aryl bromide,
- Cyanation,
- Potassium hexacyanoferrate(II),
- Palladium acetate
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