Citation: Wanshuo Zhang, Shangyao Gao, Sujuan Xie, Hui Liu, Xiangxue Zhu, Yongchen Shang, Shenglin Liu, Longya Xu, Ye Zhang. A shaped binderless ZSM-11 zeolite catalyst for direct amination of isobutene to tert-butylamine[J]. Chinese Journal of Catalysis, ;2017, 38(1): 168-175. doi: 10.1016/S1872-2067(17)62756-6 shu

A shaped binderless ZSM-11 zeolite catalyst for direct amination of isobutene to tert-butylamine

Wanshuo Zhang ^a,b, ,
Shangyao Gao ^b,c ,
Sujuan Xie ^b ,
Hui Liu ^b,d ,
Xiangxue Zhu ^b ,
Yongchen Shang ^a ,
Shenglin Liu ^b ,
Longya Xu ^b ,
Ye Zhang ^e

a College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, Heilongjiang, China;
b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
c University of Chinese Academy of Sciences, Beijing 100049, China;
d Research and Development Center, Sinochem Quanzhou Petrochemical Co., Ltd., Quanzhou 362103, Fujian, China;
e PetroChina Fushun Petrochemical Company, Fushun 113008, Liaoning, China

Received Date: 20 October 2016
Revised Date: 22 November 2016

Fund Project: This work was supported by K.C.Wong Education Foundation, Hong Kong (201611), and Youth Innovation Promotion Association, CAS (20120155).

A shaped binderless and two binder-containing ZSM-11 zeolite catalysts were prepared and char-acterized by powder X-ray diffraction, N₂ adsorption-desorption, and pyridine adsorption-infrared measurements. The binderless catalyst was synthesized using a dry-gel conversion technique, in which 1,6-hexanediamine and tetrabutylammonium bromide were used as structure-directing agents and no other alkaline materials were added. The catalytic performance of the zeolites in the direct amination of isobutene to tert-butylamine was evaluated in a fixed-bed reactor. By virtue of its high crystallinity as well as its good mechanical strength, the shaped binderless ZSM-11 catalyst showed a higher rate of formation of tert-butylamine than did the binder-containing catalysts.
- Binderless zeolite,
- ZSM-11,
- Amination,
- Isobutene,
- Tert-butylamine
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