Citation: Lin Li, Jian Lin, Xiaoyu Li, Aiqin Wang, Xiaodong Wang, Tao Zhang. Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review[J]. Chinese Journal of Catalysis, ;2016, 37(12): 2039-2052. doi: 10.1016/S1872-2067(16)62578-0 shu

Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review

Lin Li ^a, ,
Jian Lin ^a ,
Xiaoyu Li ^a,b ,
Aiqin Wang ^a ,
Xiaodong Wang ^a ,
Tao Zhang ^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Science, Beijing 100049, China

Received Date: 22 September 2016
Revised Date: 14 October 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21573232, 21576251, 21676269), National Key Projects for Fundamental Research and Development of China (2016YFA0202801), and Department of Science and Technology of Liaoning province under contract of 2015020086-101.

The formations and transformations of the chemical bonds of reactants and intermediates on catalyst surfaces occur in conjunction with the evolution of heat during catalytic reactions. Measurement of this evolved heat is helpful in terms of understanding the nature of the interactions between the catalyst and the adsorbed species, and provides insights into the reactivity of the catalyst. Although various techniques have previously been applied to assessments of evolved heat, direct measurements using a Tian-Calvet microcalorimeter are currently the most reliable method for this purpose. In this review, we summarize the relationship between the adsorption/reaction energetics determined by microcalorimetry and the reactivities of supported catalysts, and examine the important role of microcalorimetry in understanding catalytic performance from the energetic point of view.
- Catalysis,
- Microcalorimetry,
- Reactivity,
- Energetics,
- Binding strength,
- Catalyst characterization
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