Citation: Giorgio Chelucci, Gérard A. Pinna, Giansalvo Pinna, Maurizio Solinas, Barbara Sechi. Osmium complexes in catalysis of olefin hydrogenation and isomerization[J]. Chinese Journal of Catalysis, ;2016, 37(11): 1824-1836. doi: 10.1016/S1872-2067(16)62542-1 shu

Osmium complexes in catalysis of olefin hydrogenation and isomerization

a Dipartimento di Agraria, Università di Sassari, viale Italia 39, I-07100 Sassari, Italy;
b Dipartimento di Chimica e Farmacia, Università di Sassari, Via F. Muroni 23/A, 07100 Sassari, Italy;
c CNR, Istituto di Chimica Biomolecolare UOS Sassari, Traversa La Crucca 3, I-07100 Sassari, Italy

Received Date: 25 July 2016
Revised Date: 18 August 2016

Fund Project: This work was supported by Fondazione di Sardegna.

This review focuses on the evolution of the use of osmium complexes as catalysts in the hydrogena-tion and isomerization of olefins. Osmium systems show good catalytic activities and selectivities in the hydrogenation of olefins via both dihydrogen and transfer hydrogenation. Such systems there-fore have significant potential to become a powerful tool in organic synthesis.
- Osmium complexes,
- Hydrogenation,
- Transfer hydrogenation,
- Alkene isomerization
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