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Citation: Celia F. Braganza, A. V. Salker. Vapor phase methylation of phenol on Fe-substituted ZrO₂ catalyst[J]. Chinese Journal of Catalysis, ;2016, 37(11): 1991-1996. doi: 10.1016/S1872-2067(16)62527-5 shu

Vapor phase methylation of phenol on Fe-substituted ZrO₂ catalyst

Department of Chemistry, Goa University, Goa-403206, India

Received Date: 2 June 2016
Revised Date: 5 August 2016

Fe-doped ZrO₂ compounds were prepared by a co-precipitation method. The compounds were characterized by X-ray diffraction, N₂ adsorption-desorption, ultraviolet diffuse reflectance infrared Fourier transform spectroscopy, scanning electron microscopy-energy-dispersive X-ray spectros-copy, transmission electron microscopy, NH₃ temperature-programmed desorption, X-ray photoe-lectron spectroscopy, and in situ Fourier transform infrared spectroscopy. The incorporation of Fe into ZrO₂ lattice favored and effectively stabilized the formation of purely ZrO₂ tetragonal phase. Subsequently, the catalytic activity of the Fe-doped ZrO₂ compounds was evaluated toward vapor phase methylation of phenol. The catalytic activity was governed by Fe content and related to the Lewis acidity of the prepared catalyst.
- Zirconia,
- Iron doped,
- Methylation,
- Phenol,
- Xylenol
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Vapor phase methylation of phenol on Fe-substituted ZrO2 catalyst

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Vapor phase methylation of phenol on Fe-substituted ZrO₂ catalyst