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Citation: Takashi Fujita, Masanori Horikawa, Takashi Takei, Toru Murayama, Masatake Haruta. Correlation between catalytic activity of supported gold catalysts for carbon monoxide oxidation and metal-oxygen binding energy of the support metal oxides[J]. Chinese Journal of Catalysis, ;2016, 37(10): 1651-1655. doi: 10.1016/S1872-2067(16)62521-4 shu

Correlation between catalytic activity of supported gold catalysts for carbon monoxide oxidation and metal-oxygen binding energy of the support metal oxides

Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397, Japan

Received Date: 20 May 2016
Revised Date: 4 August 2016

The effect of a wide variety of metal oxide (MO_x) supports has been discussed for CO oxidation on nanoparticulate gold catalysts. By using typical co-precipitation and deposition-precipitation methods and under identical calcination conditions, supported gold catalysts were prepared on a wide variety of MO_x supports, and the temperature for 50% conversion was measured to qualitatively evaluate the catalytic activities of these simple MO_x and supported Au catalysts. Furthermore, the difference in these temperatures for the simple MO_x compared to the supported Au catalysts is plotted against the metal-oxygen binding energies of the support MO_x. A clear volcano-like correlation between the temperature difference and the metal-oxygen binding energies is observed. This correlation suggests that the use of MO_x with appropriate metal-oxygen binding energies (300-500 kJ/atom O) greatly improves the catalytic activity of MO_x by the deposition of Au NPs.
- Metal oxide-supported gold nanoparticle catalyst,
- Support effects,
- Carbon monoxide oxidation,
- Volcano-like correlation,
- Metal-oxygen binding energy
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