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Citation: Lanhui Ren, Lianyue Wang, Ying Lü, Guosong Li, Shuang Gao. Direct oxidation of the C_sp₃-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnO_x-N@C catalyst[J]. Chinese Journal of Catalysis, ;2016, 37(8): 1216-1221. doi: 10.1016/S1872-2067(16)62503-2 shu

Direct oxidation of the C_sp₃-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnO_x-N@C catalyst

Lanhui Ren ^a,b, ,
Lianyue Wang ^b ,
Ying Lü ^b ,
Guosong Li ^b ,
Shuang Gao ^b

a. College of Chemistry, Dalian University of Technology, Dalian 116024, Liaoning, China;
b. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received Date: 3 June 2016
Revised Date: 22 June 2016

Fund Project: This work was supported by the National Basic research Program of China (973 Program, 2009CB623505) and the National Natural Science Foundation of China (21273225).

Novel reusable MnO_x-N@C catalyst has been developed for the direct oxidation of N-heterocycles under solvent-free conditions using TBHP as benign oxidant to give the corresponding N-heterocyclic ketones. The catalytic system exhibited a broad substrate scope and excellent regioselectivity, as well as being amenable to gram-scale synthesis. This MnO_x-N@C catalyst also showed good reusability and was successfully recycled six times without any significant loss of activity.
- Oxidation,
- Heterogeneous catalyst,
- Ketone,
- C-H bond,
- Manganese
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
1. [1]
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Direct oxidation of the Csp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst

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通讯作者: 陈斌, bchen63@163.com

Direct oxidation of the C_sp₃-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnO_x-N@C catalyst