Citation: Xiao-hua Li, Kai Wan, Quan-bing Liu, Jin-hua Piao, Yu-ying Zheng, Zhen-xing Liang. Nitrogen-doped ordered mesoporous carbon: Effect of carbon precursor on oxygen reduction reactions[J]. Chinese Journal of Catalysis, ;2016, 37(9): 1562-1568. doi: 10.1016/S1872-2067(16)62498-1 shu

Nitrogen-doped ordered mesoporous carbon: Effect of carbon precursor on oxygen reduction reactions

a. Key Laboratory on Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, Guangdong, China;
b. School of Food Science and Engineering, South China University of Technology, Guangzhou 510641, Guangdong, China;
c. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, Guangdong, China

Received Date: 31 May 2016
Revised Date: 29 June 2016

Fund Project: This work was supported by the National Natural Science Foundation of China(21476087, 21576101), the Innovation Project of Guangdong Department of Education(2014KTSCX016), the Science & Technology Research Project of Guangdong Province(2013B010405005, 2014A010105041), and the Fundamental Research Funds for the Central Universities.

Aniline, pyrrole and phenanthroline, which have different nitrogen compositions, are used as carbon precursors to synthesize nitrogen-doped ordered mesoporous carbons(NOMCs) by the nanocasting method. The effect of the precursor on the resultant NOMC is extensively investigated by nitrogen adsorption-desorption measurements, scanning electron microscopy, X-ray photoelectron spectroscopy(XPS), cyclic voltammetry and rotating ring-disk electrode measurements. Salient findings are as follows. First, the precursor has a significant influence on the specific surface area and textural properties. The NOMC materials derived from pyrrole(C-PY-900: 765 m²/g) and phenanthroline(C-Phen-900: 746 m²/g) exhibit higher specific surface areas than the aniline analog(C-PA-900: 569 m²/g). Second, the XPS results indicate that the total nitrogen content(ca. 3.1-3.3 at%) is similar for the three carbon sources, except for a slight difference in the nitrogen configuration. Furthermore, the content of the nitrogen-activated carbon atoms is found to closely depend on the precursor, which is the highest for the phenanthroline-derived carbon. Third, the electrochemical results reveal that the electrocatalytic activity follows in the order C-PA-900 < C-PY-900 < C-Phen-900, confirming that the nitrogen-activated carbon atoms are the active sites for the oxygen reduction reaction(ORR). In summary, the precursor has considerable influence on the composition and textural properties of the NOMC materials, of which the ORR electrocatalytic activity can be enhanced through optimization of the NOMCs.
- Electrocatalysis,
- Fuel cell,
- Nitrogen-doped ordered mesoporous carbon,
- Oxygen reduction reaction,
- Precursor
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沈阳化工大学材料科学与工程学院沈阳 110142