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Citation: Chuang Li, Mingming Zhang, Xin Di, Dongdong Yin, Wenzhen Li, Changhai Liang. One-step synthesis of Pt@ZIF-8 catalyst for the selective hydrogenation of 1,4-butynediol to 1,4-butenediol[J]. Chinese Journal of Catalysis, ;2016, 37(9): 1555-1561. doi: 10.1016/S1872-2067(16)62497-X shu

One-step synthesis of Pt@ZIF-8 catalyst for the selective hydrogenation of 1,4-butynediol to 1,4-butenediol

a. Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;
b. DCBE, Biorenewables Research Laboratory, Iowa State University, Iowa 50011, USA

Received Date: 6 May 2016
Revised Date: 30 June 2016

Fund Project: This work was supported by the National Natural Science Foundation of China(21573031 and 21428301) and the Fundamental Research Funds for the Central Universities(DUT15ZD106 and DUT15RC(4)09).

A catalyst consisting of platinum nanoparticles on a ZIF-8 support(Pt@ZIF-8) was synthesized in a straightforward one-step procedure, by adding a nanostructured platinum sol during the formation of ZIF-8 at room temperature. Pt@ZIF-8 was highly porous and well crystallized. The Pt nanoparticles were well dispersed within the ZIF-8 support. In the hydrogenation of 1,4-butynediol, Pt@ZIF-8 exhibited high activity, excellent selectivity for 1,4-butenediol of greater than 94%, and reusability. The Pt@ZIF-8 catalyst did not require further additives. The favorable catalytic performance was attributed primarily to the modification of the ZIF-8 support by the platinum nanoparticles.
- Platinum sol,
- ZIF-8,
- One-step synthesis,
- 1,4-Butynediol,
- Selective hydrogenation
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