Citation: Fen Wang, Qiang Wang, Ming Bao, Xingwei Li. Cobalt-catalyzed redox-neutral synthesis of isoquinolines: C-H activation assisted by an oxidizing N-S bond[J]. Chinese Journal of Catalysis, ;2016, 37(8): 1423-1430. doi: 10.1016/S1872-2067(16)62491-9 shu

Cobalt-catalyzed redox-neutral synthesis of isoquinolines: C-H activation assisted by an oxidizing N-S bond

Fen Wang ^a,b, ,
Qiang Wang ^b ,
Ming Bao ^a ,
Xingwei Li ^b

a. School of Chemistry and Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;
b. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received Date: 6 June 2016
Revised Date: 24 June 2016

Fund Project: This work was supported by the Dalian Institute of Chemical Physics, Chinese Academy of Sciences and the National Natural Science Foundation of China (21272231).

A redox-neutral avenue to access isoquinolines has been realized by a Co(III)-catalyzed C-H activation process. Starting from readily available N-sulfinyl imine substrates and alkynes, the reaction occurred via N-S cleavage with broad substrate scope and functional group compatibility in the presence of cost-effective cobalt catalysts.
- Cobalt(III) catalyst,
- Carbon-hydrogen activation,
- N-sulfinyl imine,
- Isoquinoline
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