Citation:
Najmeh Nowrouzi, Mohammad Abbasi, Hadis Latifi. Thiol-free route to diaryl sulfides by Cu catalyzed coupling of sodium thiosulfate with aryl halides[J]. Chinese Journal of Catalysis,
;2016, 37(9): 1550-1554.
doi:
10.1016/S1872-2067(16)62486-5
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A method for the synthesis of diaryl sulfides from aryl halides in polyethylene glycol was reported. Inodorous Na2S2O3·5H2O, which is readily available as a stable salt, is an effective source of sulfur in the presence of CuI as catalyst.
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Keywords:
- Copper catalyst,
- Sulfide,
- Thiol,
- Sodium thiosulfate
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