Citation: Hiroaki Koga, Kohei Sakata, Yoshinori Ato, Akihide Hayashi, Kohei Tada, Mitsutaka Okumur. Advances in polymer-stabilized Au nano-cluster catalysis: Interplay of theoretical calculations and experiments[J]. Chinese Journal of Catalysis, ;2016, 37(10): 1588-1593. doi: 10.1016/S1872-2067(16)62463-4 shu

Advances in polymer-stabilized Au nano-cluster catalysis: Interplay of theoretical calculations and experiments

a Elements Strategy Initiative for Catalysts and Batteries(ESICB) Kyoto University, 1-30 Goryoohara, Kyoto 615-8245, Japan;
b Department of Chemistry, Graduate School of Science Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan

Received Date: 24 April 2016
Revised Date: 20 May 2016

Polymer-stabilized Au nano clusters (NCs) with mean diameters of 2-10 nm exhibit unique catalytic properties. Several studies have shown that the key factors affecting the catalytic activity of polymer-stabilized Au NCs are control of the Au NC size, appropriate selection of polymers and optimization of the reaction conditions. This is because polymer-stabilized Au NCs exhibit a clear size effect in several catalytic reactions, and the catalytic activity differs with the type of polymer used and the reaction conditions. In order to elucidate the reason underlying the catalytic activity of the polymer-stabilized Au NCs, much attention is being devoted to the interplay of theoretical calculations and experiments in catalysis by polymer stabilized Au NCs. The present article mainly summarizes our progress in understanding this interplay in polymer-stabilized Au NC catalysis.
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
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沈阳化工大学材料科学与工程学院沈阳 110142

Advances in polymer-stabilized Au nano-cluster catalysis: Interplay of theoretical calculations and experiments

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com