Citation: Jing Dong, Mingming Zhu, Gaoshuo Zhang, Yongmei Liu, Yong Cao, Su Liu, Yangdong Wang. Highly selective supported gold catalyst for CO-driven reduction of furfural in aqueous media[J]. Chinese Journal of Catalysis, ;2016, 37(10): 1669-1675. doi: 10.1016/S1872-2067(16)62458-0 shu

Highly selective supported gold catalyst for CO-driven reduction of furfural in aqueous media

Jing Dong ^a,b, ,
Mingming Zhu ^a ,
Gaoshuo Zhang ^a ,
Yongmei Liu ^a ,
Yong Cao ^a ,
Su Liu ^b ,
Yangdong Wang ^b

a Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, China;
b SINOPEC Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China

Received Date: 14 April 2016
Revised Date: 10 May 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21273044, 21473035, 91545108), the Research Fund for the Doctoral Program of Higher Education (2012007000011), SINOPEC (X514005), Science & Technology Commission of Shanghai Municipality (08DZ2270500), and the Open Project of State Key Laboratory of Chemical Engineering (SKL-ChE-15C02).

The reductive transformation of furfural (FAL) into furfuryl alcohol (FOL) is an attractive route for the use of renewable bio-sources but it suffers from the heavy use of H₂. We describe here a highly efficient reduction protocol for converting aqueous FAL to FOL. A single phase rutile TiO₂ support with a gold catalyst (Au/TiO₂-R) that used CO/H₂O as the hydrogen source catalyze this reduction efficiently under mild conditions. By eliminating the consumption of fossil fuel-derived H₂, our process has the benefit afforded by using CO as a convenient and cost competitive reducing reagent.
- Furfural,
- Reduction,
- Supported gold catalyst,
- Carbon monoxide,
- Aqueous
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