Citation: Mahdi Mirzaee, Bahram Bahramian, Marieh Mirebrahimi. Amine-functionalized boehmite nanoparticle-supported molybdenum and vanadium complexes: Efficient catalysts for epoxidation of alkenes[J]. Chinese Journal of Catalysis, ;2016, 37(8): 1263-1274. doi: 10.1016/S1872-2067(16)62451-8 shu

Amine-functionalized boehmite nanoparticle-supported molybdenum and vanadium complexes: Efficient catalysts for epoxidation of alkenes

Department of Chemistry, Shahrood University of Technology, Shahrood, Iran

Received Date: 26 March 2016
Revised Date: 30 April 2016

Boehmite nanoparticles with a high surface area and a high degree of surface hydroxyl groups were covalently functionalized by 3-(trimethoxysilyl)-propylamine to support vanadium-oxo-sulfate and molybdenum hexacarbonyl complexes. These supported catalysts were then characterized by Fourier-transform infrared spectroscopy, powder X-ray diffraction, thermogravimetry and differential thermal analysis, X-ray-photoelectron spectroscopy, elemental analysis, inductively coupled plasma, and transmission electron microscopy techniques. The catalysts were subsequently used for the epoxidation of cis-cyclooctene, and the experimental procedures were optimized. The progress of the reactions was investigated by gas-liquid chromatography. Recycling experiments revealed that these nanocatalysts could be repeatedly used several times for a nearly complete epoxidation of cis-cyclooctene. The optimized experimental conditions were also used successfully for the epoxidation of some other substituted alkenes.
- Boehmite nanoparticles,
- Heterogeneous catalysts,
- Hexa-carbonyl molybdenum,
- Oxo-sulfate vanadium,
- Epoxidation
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