Citation: Huiran Zhou, Xiaofeng Yang, Aiqin Wang, Shu Miao, Xiaoyan Liu, Xiaoli Pan, Yang Su, Lin Li, Yuan Tan, Tao Zhang. Pd/ZnO catalysts with different origins for high chemoselectivity in acetylene semi-hydrogenation[J]. Chinese Journal of Catalysis, ;2016, 37(5): 692-699. doi: 10.1016/S1872-2067(15)61090-7 shu

Pd/ZnO catalysts with different origins for high chemoselectivity in acetylene semi-hydrogenation

Huiran Zhou ^a,b ,
Xiaofeng Yang ^a,, ,
Aiqin Wang ^a,, ,
Shu Miao ^a ,
Xiaoyan Liu ^a ,
Xiaoli Pan ^a ,
Yang Su ^a ,
Lin Li ^a ,
Yuan Tan ^a ,
Tao Zhang ^a

1.
a State Key Laboratory of Catalysis, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
2.
b University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Xiaofeng Yang, Aiqin Wang,
Received Date: 26 February 2016
Available Online: 28 March 2016
Fund Project: 国家自然科学基金(21573232). (21573232)

The heterogeneity of active sites is the main obstacle for selectivity control in heterogeneous catalysis. Single atom catalysts (SACs) with homogeneous isolated active sites are highly desired in chemoselective transformations. In this work, a Pd₁/ZnO catalyst with single-atom dispersion of Pd active sites was achieved by decreasing the Pd loading and reducing the sample at a relatively low temperature. The Pd₁/ZnO SAC exhibited excellent catalytic performance in the chemoselective hydrogenation of acetylene with comparable chemoselectivity to that of PdZn intermetallic catalysts and a greatly enhanced utilization of Pd metal. Such unusual behaviors of the Pd₁/ZnO SAC in acetylene semi-hydrogenation were ascribed to the high-valent single Pd active sites, which could promote electrostatic interactions with acetylene but restrain undesired ethylene hydrogenation via the spatial restrictions of σ-chemical bonding toward ethylene.
- Single atom catalyst,
- Acetylene semi-hydrogenation,
- Chemoselectivity,
- Palladium,
- Zinc oxide
1. [1]
  [1] G. A. Somorjai, J. Y. Park, Angew. Chem. Int. Ed., 2008, 47, 9212-9228.
2. [2]
  [2] H. S. Wei, X. Wei, X. F. Yang, G. Z. Yin, A. Q. Wang, X. Y. Liu, Y. Q. Huang, T. Zhang, Chin. J. Catal., 2015, 36, 160-167.
3. [3]
  [3] J. Gao, H. B. Zhao, X. F. Yang, B. E. Koel, S. G. Podkolzin, Angew. Chem. Int. Ed., 2014, 53, 3641-3644.
4. [4]
  [4] S. R. Zhang, L. Nguyen, J. X. Liang, J. J. Shan, J. Y Liu, A. I. Frenkel, A. Patlolla, W. X. Huang, J. Li, F. Tao, Nat. Commun., 2015, 6, 7938.
5. [5]
  [5] J. Osswald, R. Giedigkeit, R. E. Jentoft, M. Armbrüster, F. Girgsdies, K. Kovnir, T. Ressler, Y. Grin, R. Schlögl, J. Catal., 2008, 258, 210-218.
6. [6]
  [6] H. R. Zhou, X. F. Yang, L. Li, X. Y. Liu, Y. Q. Huang, X. L. Pan, A. Q. Wang, J. Li, T. Zhang, ACS Catal., 2016, 6, 1054-1061.
7. [7]
  [7] A. Borodziński, G. C. Bond, Catal. Rev.-Sci. Eng., 2006, 48, 91-144.
8. [8]
  [8] A. Borodziński, G. C. Bond, Catal. Rev.-Sci. Eng., 2008, 50, 379-469.
9. [9]
  [9] S. A. Nikolaev, L. N. Zanaveskin, V. V. Smirnov, V. A. Averyanov, K. L. Zanaveskin, Russ. Chem. Rev., 2009, 78, 231-247.
10. [10]
  [10] M. Crespo-Quesada, F. Cárdenas-Lizana, A. L. Dessimoz, L. Kiwi-Minsker, ACS Catal., 2012, 2, 1773-1786.
11. [11]
  [11] M. Armbrüster, M. Behrens, F. Cinquini, K. Föttinger, Y. Grin, A. Haghofer, B. Klötzer, A. Knop-Gericke, H. Lorenz, A. Ota, S. Penner, J. Prinz, C. Rameshan, Z. Révay, D. Rosenthal, G. Rupprechter, P. Sautet, R. Schlögl, L. Shao, L. Szentmiklósi, D. Teschner, D. Torres, R. Wagner, R. Widmer, G. Wowsnick, ChemCatChem, 2012, 4, 1048-1063.
12. [12]
  [12] N. López, C. Vargas-Fuentes, Chem. Commun., 2012, 48, 1379-1391.
13. [13]
  [13] J. Lin, A. Q. Wang, B. T. Qiao, X. Y. Liu, X. F. Yang, X. D. Wang, J. X. Liang, J. Li, J. Y. Liu, T. Zhang, J. Am. Chem. Soc., 2013, 135, 15314-15317.
14. [14]
  [14] B. T. Qiao, A. Q. Wang, X. F. Yang, L. F. Allard, Z. Jiang, Y. T. Cui, J. Y. Liu, J. Li, T. Zhang, Nat. Chem., 2011, 3, 634-641.
15. [15]
  [15] B. T. Qiao, J. Lin, A. Q. Wang, Y. Chen, T. Zhang, J. Y. Liu, Chin. J. Catal., 2015, 36, 1505-1511.
16. [16]
  [16] X. F. Yang, A. Q. Wang, B. T. Qiao, J. Li, J. Y. Liu, T. Zhang, Acc. Chem. Res., 2013, 46, 1740-1748.
17. [17]
  [17] H. S. Wei, X. Y. Liu, A. Q. Wang, L. L. Zhang, B. T. Qiao, X. F. Yang, Y. Q. Huang, S. Miao, J. Y. Liu, T. Zhang, Nat. Commun., 2014, 5, 5634.
18. [18]
  [18] Y. Boudeville, F. Figueras, M. Forissier, J. L. Portefaix, J. C. Vedrine, J. Catal., 1979, 58, 52-60.
19. [19]
  [19] X. Y. Liu, C. Y. Mou, S. Lee, Y. Li, J. Secrest, B. W. L. Jang, J. Catal., 2012, 285, 152-159.
20. [20]
  [20] G. X. Pei, X. Y. Liu, A. Q. Wang, A. F. Lee, M. A. Isaacs, L. Li, X. L. Pan, X. F. Yang, X. D. Wang, Z. J. Tai, K. Wilson, T. Zhang, ACS Catal., 2015, 5, 3717-3725.
21. [21]
  [21] C. T. Hong, C. T. Yeh, F. H. Yu, Appl. Catal., 1989, 48, 385-396.
22. [22]
  [22] M. Armbrüster, M. Behrens, K. Föttinger, M. Friedrich, E. Gaudry, S. K. Matam, H. R. Sharma, Catal. Rev.-Sci. Eng., 2013, 55, 289-367.
23. [23]
  [23] M. L. Cubeiro, J. L. G. Fierro, J. Catal., 1998, 179, 150-162.
24. [24]
  [24] Y. H. Chin, R. Dagle, J. L. Hu, A. C. Dohnalkova, Y. Wang, Catal. Today, 2002, 77, 79-88.
25. [25]
  [25] Y. Uemura, Y. Inada, Y. Niwa, M. Kimura, K. K. Bando, A. Yagishita, Y. Iwasawa, M. Nomura, Phys. Chem. Chem. Phys., 2012, 14, 2152-2158.
26. [26]
  [26] M. Crespo-Quesada, S. Yoon, M. S. Jin, Y. N. Xia, A. Weidenkaff, L. Kiwi-Minsker, ChemCatChem, 2014, 6, 767-771.
27. [27]
  [27] I. S. Mashkovsky, G. N. Baeva, A. Y. Stakheev, M. N. Vargaftik, N. Y. Kozitsyna, I. I. Moiseev, Mendeleev Commun., 2014, 24, 355-357.
28. [28]
  [28] M. W. Tew, H. Emerich, J. A. van Bokhoven, J. Phys. Chem. C, 2011, 115, 8457-8465.
29. [29]
  [29] A. I. Frenkel, C. W. Hills, R. G. Nuzzo, J. Phys. Chem. B, 2001, 105, 12689-12703.
30. [30]
  [30] A. Sarkany, Z. Zsoldos, B. Furlong, J. W. Hightower, L. Guczi, J. Catal., 1993, 141, 566-582.
31. [31]
  [31] L. N. Protasova, E. V. Rebrov, K. L. Choy, S. Y. Pung, V. Engels, M. Cabaj, A. E. H. Wheatley, J. C. Schouten, Catal. Sci. Technol., 2011, 1, 768-777.
32. [32]
  [32] C. Rameshan, W. Stadlmayr, C. Weilach, S. Penner, H. Lorenz, M. Hävecker, R. Blume, T. Rocha, D. Teschner, A. Knop-Gericke, R. Schlögl, N. Memmel, D. Zemlyanov, G. Rupprechter, B. Klötzer, Angew. Chem. Int. Ed., 2010, 49, 3224-3227.
33. [33]
  [33] N. Iwasa, S. Masuda, N. Ogawa, N. Takezawa, Appl. Catal. A, 1995, 125, 145-157.
34. [34]
  [34] N. Wongwaranon, O. Mekasuwandumrong, P. Praserthdam, J. Panpranot, Catal. Today, 2008, 131, 553-558.
35. [35]
  [35] Q. W. Zhang, J. Li, X. X. Liu, Q. M. Zhu, Appl. Catal. A, 2000, 197, 221-228.
36. [36]
  [36] Y. N. Li, B. W. L. Jang, Appl. Catal. A, 2011, 392, 173-179.
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