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Citation: Hengpan Yang, Laxia Wu, Huan Wang, Jiaxing Lu. Cathode made of compacted silver nanoparticles for electrocatalytic carboxylation of 1-phenethyl bromide with CO₂[J]. Chinese Journal of Catalysis, ;2016, 37(7): 994-998. doi: 10.1016/S1872-2067(15)61075-0 shu

Cathode made of compacted silver nanoparticles for electrocatalytic carboxylation of 1-phenethyl bromide with CO₂

a. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China;
b. School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, Anhui, China

Received Date: 2 February 2016
Revised Date: 29 February 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21203066, 21373090, 21473060).

Silver nanoparticles prepared by the direct reduction of AgNO₃ in aqueous solution were compacted into coins and used as the cathode for the electrocatalytic carboxylation of 1-phenethyl bromide with CO₂. The influences of the working electrode, charge, current density and temperature were investigated. Under optimized conditions, 98% yield of 2-phenylpropionic acid was obtained. The reaction was performed under very mild conditions and no added catalyst was required in the electrolyte. Yields that varied from moderate to excellent were also achieved with other benzyl bromides. This electrode has good stability and reusability, and the yield and selectivity of 2-phenylpropionic acid could be maintained during reuse for 10 times.
- Electrocatalysis,
- Electrocarboxylation,
- Carbon dioxide,
- Benzyl bromides,
- Silver nanoparticles
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Cathode made of compacted silver nanoparticles for electrocatalytic carboxylation of 1-phenethyl bromide with CO2

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通讯作者: 陈斌, bchen63@163.com

Cathode made of compacted silver nanoparticles for electrocatalytic carboxylation of 1-phenethyl bromide with CO₂