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Citation: Dongfang Niu, Zhijuan Wu, Lipu Zhang, Rongbin Du, Heng Xu, Xinsheng Zhang. Synthesis of cyclic carbonates from epoxides and CO₂ in acetonitrile via the synergistic action of BMIMBr and electrogenerated magnesium[J]. Chinese Journal of Catalysis, ;2016, 37(7): 1076-1080. doi: 10.1016/S1872-2067(15)61070-1 shu

Synthesis of cyclic carbonates from epoxides and CO₂ in acetonitrile via the synergistic action of BMIMBr and electrogenerated magnesium

a. State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;
b. Collaborative Innovation Center for Petrochemical New Materials, Anqing 246011, Anhui, China

Received Date: 24 January 2016
Revised Date: 1 March 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21303053) and the Open Project of State Key Laboratory of Chemical Engineering (SKLChE-14C02).

Using 1-butyl-3-methyl- imidazolium bromide (BMIMBr) as the supporting electrolyte and magnesium as the sacrificial anode, a new and highly efficient electrochemically catalytic route was developed for the synthesis of cyclic carbonates from epoxides and CO₂. Based on the cooperative action of BMIMBr and an electrogenerated magnesium salt obtained under a N₂ atmosphere, CO₂ reacted with a wide range of epoxides to readily generate cyclic carbonates in moderate to excellent yields under mild conditions.
- Electrogenerated magnesium salt,
- Imidazolium bromide,
- Carbon dioxide,
- Epoxide,
- Carboxylation,
- Cyclic carbonate
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Synthesis of cyclic carbonates from epoxides and CO2 in acetonitrile via the synergistic action of BMIMBr and electrogenerated magnesium

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通讯作者: 陈斌, bchen63@163.com

Synthesis of cyclic carbonates from epoxides and CO₂ in acetonitrile via the synergistic action of BMIMBr and electrogenerated magnesium