Citation: Yinghong Zhu, Jianqing Zhang, Ziying Chen, Anlun Zhang, Chunan Ma. Synthesis of nitrocarbazole compounds and their electrocatalytic oxidation of alcohol[J]. Chinese Journal of Catalysis, ;2016, 37(4): 533-538. doi: 10.1016/S1872-2067(15)61047-6 shu

Synthesis of nitrocarbazole compounds and their electrocatalytic oxidation of alcohol

1.
State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China

Corresponding author: Chunan Ma,
Received Date: 1 December 2015
Available Online: 27 January 2016
Fund Project: 973计划前期研究专项(2012CB722604). (2012CB722604)

Three compounds with nitrocarbazole frameworks were synthesized and their electrochemical reversibility as organic electrocatalysts was studied by cyclic voltammetry. The electrochemical reversibility and oxidation-reduction potential of the compounds were greatly affected by their substituents. The oxidation-reduction potential of the compound with an electron-donating group was negative, while that of the compound with an electron-withdrawing group on the carbazole framework was positive. The electrocatalytic oxidation activities of the nitrocarbazole compounds were investigated through cyclic voltammetry and controlled potential electrolysis at room temperature. The electrocatalysts showed excellent selectivity for p-methoxybenzyl alcohol, converting it to the corresponding aldehyde through electro-oxidation with just 2.5 mol% of the electrocatalysts presented. The electrocatalysts maintained their excellent electroredox activity following recycling.
- Nitro-carbazole compounds,
- Organic electro-catalyst,
- Indirect electro-oxidation,
- Selective electro-oxidation,
- Redox reversibility
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沈阳化工大学材料科学与工程学院沈阳 110142