Citation: Eda Sinirtas, Meltem Isleyen, Gulin Selda Pozan Soylu. Photocatalytic degradation of 2,4-dichlorophenol with V₂O₅-TiO₂ catalysts: Effect of catalyst support and surfactant additives[J]. Chinese Journal of Catalysis, ;2016, 37(4): 607-615. doi: 10.1016/S1872-2067(15)61035-X shu

Photocatalytic degradation of 2,4-dichlorophenol with V₂O₅-TiO₂ catalysts: Effect of catalyst support and surfactant additives

1.
Chemical Engineering Department, Faculty of Engineering, Istanbul University, Avcilar 34320, Istanbul, Turkey

Corresponding author: Gulin Selda Pozan Soylu,
Received Date: 6 October 2015
Available Online: 22 December 2015
Fund Project: 土耳其科学技术研究委员会(111M210 [2011-2013]). (111M210 [2011-2013])

Binary oxide catalysts with various weight percentage V₂O₅ loadings were prepared by solid-state dispersion and the nanocomposites were modified with surfactants. The catalysts were analyzed using X-ray diffraction, diffuse-reflectance spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy, and N₂ adsorption-desorption. The photocatalytic activities of the catalysts were evaluated in the degradation of 2,4-dichlorophenol under ultraviolet irradiation. The photocatalytic activity of 50 wt% V₂O₅-TiO₂ (50V₂O₅-TiO₂) was higher than those of pure V₂O₅, TiO₂, and P25. Interactions between V₂O₅ and TiO₂ affected the photocatalytic efficiencies of the binary oxide catalysts. Cetyltrimethylammonium bromide (CTAB) and hexadecyltrimethylammonium bromide (HTAB) significantly enhanced the efficiency of the 50V₂O₅-TiO₂ catalyst. The highest percentage of 2,4-dichlorophenol degradation (100%) and highest reaction rate (2.22 mg/(L·min)) were obtained in 30 min with the (50V₂O₅-TiO₂)-CTAB catalyst. It is concluded that the addition of a surfactant to the binary oxide significantly enhanced the photocatalytic activity by modifying the optical and electronic properties of V₂O₅ and TiO₂.
- 2,4-Dichlorophenol,
- Degradation,
- Photocatalysis,
- Surfactant,
- Binary oxide,
- Characterization
1. [1]
  [1] J. Zhang, D. Q. Liu, W. J. Bian, X. H. Chen, Desalination, 2012, 304, 49-56.
2. [2]
  [2] L. Ren, J. Zhang, Y. Li, C. L. Zhang, Chem. Eng. J., 2011, 168, 553-561.
3. [3]
  [3] B. H. Hameed, I. A. W. Tan, A. L. Ahmad, Chem. Eng. J., 2008, 144, 235-244.
4. [4]
  [4] S. G. Chung, Y. S. Chang, J. W. Choi, K. Y. Baek, S. W. Hong, S. T. Yun, S. H. Lee, Chem. Eng. J., 2013, 215, 921-928.
5. [5]
  [5] Z. Zhang, Q. H. Shen, N. Cissoko, J. Wo, X. Xu, J. Hazard. Mater., 2010, 182, 252-258.
6. [6]
  [6] T. Zhou, Y. Z. Li, T. T. Lim, Sep. Purif. Technol., 2010, 76, 206-214.
7. [7]
  [7] A. O. Olaniran, E. O. Igbinosa, Chemosphere, 2011, 83, 1297-1306.
8. [8]
  [8] L. Liu, F. Chen, F. Yang, Y. Chen, J. Crittenden, Chem. Eng. J., 2012, 181, 189-195.
9. [9]
  [9] N. Zhang, M. Q. Yang, S. Q. Liu, Y. G. Sun, Y. J. Xu, Chem. Rev., 2015, 115, 10307-10377.
10. [10]
  [10] T. K. Tseng, Y. S. Lin, Y. J. Chen, H. Chu, Int. J. Mol. Sci., 2010, 11, 2336-2361.
11. [11]
  [11] F. Ribonia, L. G. Bettini, D. W. Bahnemann, E. Selli, Catal. Today, 2013, 209, 28-34.
12. [12]
  [12] X. F. Lei, X. X. Xue, Mater. Sci. Semicond. Process., 2008, 11, 117-121.
13. [13]
  [13] H. Liu, T. Xia, H. K. Shon, S. Vigneswaran, J. Ind. Eng. Chem., 2011, 17, 461-467.
14. [14]
  [14] L. Li, C. Y. Liu, Y. Liu, Mater. Chem. Phys., 2009, 113, 551-557.
15. [15]
  [15] S. Q. Liu, Z. R. Tang, Y. G. Sun, J. C. Colmenares, Y. J. Xu, Chem. Soc. Rev., 2015, 44, 5053-5075.
16. [16]
  [16] K. Esumi, S. Nakagawa, T. Yoshımu, J. Jpn Soc. Colour Mater., 2004, 77, 13-18.
17. [17]
  [17] Y. Cho, H. Kyung, W. Choi, Appl. Catal. B, 2004, 52, 23-32.
18. [18]
  [18] E. O. Scott-Emuakpor, A. Kruth, M. J. Todd, A. Raab, G. I. Paton, D. E. Macphee, Appl. Catal. B, 2012, 123, 433-439.
19. [19]
  [19] H. Wang, J. P. Lewis, J. Phys: Condens. Matter, 2005, 17, L209-L213.
20. [20]
  [20] C. D. Valentin, G. Pacchioni, A. Selloni, Chem. Mater., 2005, 17, 6656-6665.
21. [21]
  [21] L. Li, C. Y. Liu, Y. Liu, Mater. Chem. Phys., 2009, 113, 551-557.
22. [22]
  [22] D. E. Gu, B. C. Yang, Y. D. Hu, Catal. Lett., 2007, 118, 254-259.
23. [23]
  [23] S. M. Chang, W. S. Liu, Appl. Catal. B, 2011, 101, 333-342.
24. [24]
  [24] J. E. Herrera, T. T. Isimjan, I. Abdullahi, A. Ray, S. Rohani, Appl. Catal. A, 2012, 417, 13-18.
25. [25]
  [25] L. E. Briand, O. P. Tkachenko, M. Guraya, X. Gao, I. E. Wachs, W. Grunert, J. Phys. Chem. B, 2004, 108, 4823-4830.
26. [26]
  [26] T. M. D. Dang, T. M. H. Nguyen, H. P. Nguyen, Adv. Nat. Sci., 2010, 1, 1-10.
27. [27]
  [27] K. R. Gota, S. Suresh, Asian J. Chem., 2014, 26, 7087-7101.
28. [28]
  [28] C. A. H. Aguilar, T. Pandiyan, J. A. Arenas-Alatorre, N. Singh, Sep. Purif. Technol., 2015, 149, 265-278.
29. [29]
  [29] A. Kambur, G. S. Pozan, I. Boz, Appl. Catal. B, 2012, 115, 149-158.
30. [30]
  [30] J. G. Yu, B. Wang, Appl. Catal. B, 2010, 94, 295-302.
31. [31]
  [31] A. P. Zhang, J. Z. Zhang, Spectrochim. Acta Part A, 2009, 73, 336-341.
32. [32]
  [32] V. D. Nithya, R. K. Selvan, C. Sanjeeviraja, D. M. Radheep, S. Arumugam S, Mater. Res. Bull., 2011, 46, 1654-1658.
33. [33]
  [33] F. Bai, D. S. Wang, Z. Y. Huo, W. Chen, L. P. Liu, X. Liang, C. Chen, X. Wang, Q. Peng, Y. D. Li, Angew. Chem. Int. Ed., 2007, 46, 6650-6653.
34. [34]
  [34] N. Molahasani, M. S. Sadjadi, K. Zare, Int. J. Nano Dimens., 2013, 4, 161-166.
35. [35]
  [35] M. Shang, W. Z. Wang, L. Zhou, S. M. Sun, W. Z. Yin, J. Hazard. Mater., 2009, 172, 338-344.
36. [36]
  [36] F. Lei, B. Yan, H. H. Chen, Q. Zhang, J. T. Zhao, Cryst. Growth Des., 2009, 9, 3730-3736.
37. [37]
  [37] M. Kanna, S. Wongnawa, Mater. Chem. Phys., 2008, 110, 166-175.
38. [38]
  [38] G. C. Chen, X. Q. Shan, Y. S. Wang, B. Wen, Z. G. Pei, Y. N. Xie, T. Liu, J. J. Pignatello, Water Res., 2009, 43, 2409-2418.
39. [39]
  [39] P. Venkatesan, J. Santhanalakshmi, Nanosci. Nanotechnol., 2011, 1, 43-47.
40. [40]
  [40] L. Q. Jing, H. G. Fu, B. Q. Wang, D. J. Wang, B. F. Xin, S. Li, J. Z. Sun, Appl. Catal. B, 2006, 62, 282-291.
41. [41]
  [41] Z. Y. Liu, D. D. Sun, P. Guo, J. O. Leckie, Nano Lett., 2007, 7, 1081-1085.
42. [42]
  [42] C. Han, M. Q. Yang, N. Zhang, Y. J. Xu, J. Mater. Chem. A, 2014, 2, 19156-19166.
43. [43]
  [43] C. Han, Z. Chen, N. Zhang, J. C. Colmenares, Y. J. Xu, Adv. Funct. Mater., 2015, 25, 221-229.
44. [44]
  [44] H. Benhebal, M. Chai, T. Salmon, J. Geens, A. Leonard, S. D. Lambert, M. Crine, B. Heinrichs, Alexandria Eng. J., 2013, 52, 517-523.
45. [45]
  [45] J. B. Zhong, J. Z. Li, Z. H. Xiao, W. Hu, X. B. Zhou, X. W. Zheng, Mater. Lett., 2012, 91, 301-303.
46. [46]
  [46] W. F. Yao, X. H. Xiao, H. Wang, J. T. Zhou, X. N. Yang, Y. Zhang, S. X. Shang, B. B. Huang, Appl. Catal. B, 2004, 52, 109-116.
47. [47]
  [47] M. D. Hernandez-Alonso, I. Tejedor-Tejedor, J. M. Coronado, J. Soria, M. A. Anderson, Thin Solid Films, 2006, 502, 125-131.
48. [48]
  [48] L. Kokporka, S. Onsuratoom, T. Puangpetch, S. Chavadej, Mater. Sci. Semicond. Process, 2013, 16, 667-678.
49. [49]
  [49] B. Neppolian, Q. Wang, H. Yamashita, H. Choi, Appl. Catal. A, 2007, 333, 264-271.
50. [50]
  [50] J. C. Wu, C. S. Chung, C. L. Ay, I. K. Wang, J. Catal., 1984, 87, 98-107.
51. [51]
  [51] Y. Xu, C. H. Langford, J. Phys. Chem., 1995, 99, 11501-11507.
52. [52]
  [52] Y. Xu, C. H. Langford, J. Phys. Chem., 1997, 101, 3115-3121.
53. [53]
  [53] DY. Xu, C. H. Langford, Langmuir, 2001, 17, 897-902.
54. [54]
  [54] J. Yu, A. Kudo, Adv. Funct. Mater., 2006, 16, 2163-2169.
55. [55]
  [55] D. L. Liao, B. Q. Liao, J. Photochem. Photobiol. A, 2007, 187, 363-369.
56. [56]
  [56] J. S. Valente, F. Tzompantzi, J. Prince, J. G. H. Cortez, R. Gomez, Appl. Catal. B, 2009, 90, 330-338.
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
3. [3]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . 二维共价有机框架作为光催化剂在有机合成中的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-. doi: 10.1016/j.actphy.2025.100086
4. [4]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
5. [5]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
7. [7]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-. doi: 10.1016/j.actphy.2025.100052
8. [8]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
9. [9]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
10. [10]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ^-壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081
11. [11]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
12. [12]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
13. [13]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
14. [14]
  Xia ZHANG , Yushi BAI , Xi CHANG , Han ZHANG , Haoyu ZHANG , Liman PENG , Shushu HUANG . Preparation and photocatalytic degradation performance of rhodamine B of BiOCl/polyaniline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 913-922. doi: 10.11862/CJIC.20240255
15. [15]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
16. [16]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
17. [17]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
18. [18]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
19. [19]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
20. [20]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(356)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Photocatalytic degradation of 2,4-dichlorophenol with V2O5-TiO2 catalysts: Effect of catalyst support and surfactant additives

Metrics

通讯作者: 陈斌, bchen63@163.com

Photocatalytic degradation of 2,4-dichlorophenol with V₂O₅-TiO₂ catalysts: Effect of catalyst support and surfactant additives