Citation: J. H. Flores, M. E. H. Maia da Costa, M. I. Pais da Silva. Effect of Cu-ZnO-Al₂O₃ supported on H-ferrierite on hydrocarbons formation from CO hydrogenation[J]. Chinese Journal of Catalysis, ;2016, 37(3): 378-388. doi: 10.1016/S1872-2067(15)61032-4 shu

Effect of Cu-ZnO-Al₂O₃ supported on H-ferrierite on hydrocarbons formation from CO hydrogenation

1.
a Departamento de Química, Pontifícia Universidade Católica, 22453-900, Rio de Janeiro, RJ, Brazil;
2.
b Departamento de Física, Pontifícia Universidade Católica, 22453-900, Rio de Janeiro, RJ, Brazil

Corresponding author: M. I. Pais da Silva,
Received Date: 29 October 2015
Available Online: 9 December 2015

Methanol synthesis catalysts based on Cu, Zn and Al were prepared by three methods and subsequently mixed with H-ferrierite zeolite in an aqueous suspension to disperse the catalysts over the support. These materials were characterized by X-ray diffraction, N₂ adsorption, transmission electron microscopy, temperature programmed reduction, NH₃ and H₂ temperature-programmed desorption, and X-ray photoelectron spectroscopy. They were also applied to the CO hydrogenation reaction to produce dimethyl ether and hydrocarbons. The catalysts were prepared by coprecipitation under low and high supersaturation conditions and by a homogeneous precipitation method. The preparation technique was found to affect the precursor structural characteristics, such as purity and crystallinity, as well as the particle size distribution of the resulting catalyst. Low supersaturation conditions favored high dispersion of the Cu species, increasing the methanol synthesis catalyst's metallic surface area and resulting in a homogeneous particle size distribution. These effects in turn were found to modify the zeolite properties, promoting both a low micropore volume and blockage of the zeolite acid sites. The effect of the methanol synthesis catalyst on the reaction was verified by the correlation between the Cu surface area and the CO conversion rate.
- Methanol synthesis catalyst,
- Low supersaturation precipitation,
- High supersaturation precipitation,
- Syngas,
- Hydrotalcite,
- Hydrocarbon
1. [1]
  [1] E. Iglesia, S. L. Soled, R. A. Fiato, J. Catal., 1992, 137, 212-224.
2. [2]
  [2] M. E. Dry, Catal. Today, 2002, 71, 227-241.
3. [3]
  [3] Y. J. Jin, S. Asaoka, X. H. Li, K. Asami, K. Fujimoto, Fuel Process. Technol., 2004, 85, 1151-1164.
4. [4]
  [4] Q. W. Zhang, X. H. Li, K. Asami, S. Asaoka, K. Fujimoto, Fuel Process. Technol., 2004, 85, 1139-1150.
5. [5]
  [5] Q. J. Ge, X. H. Li, H. Kaneko, Fujimoto K., J. Mol. Catal. A, 2007, 278, 215-219.
6. [6]
  [6] Q. W. Zhang, X. H. Li, K. Asami, S. Asaoka, K. Fujimoto, Catal. Lett., 2005, 102, 51-55.
7. [7]
  [7] Q. W. Zhang, X. H. Li, K. Asami, S. Asaoka, K. Fujimoto, Catal. Today, 2005, 104, 30-36.
8. [8]
  [8] Q. J. Ge, Y. Lian, X. D. Yuan, X. H. Li, K. Fujimoto, Catal. Commun., 2008, 9, 256-261.
9. [9]
  [9] S. H. Kang, J. W. Bae, K. W. Jun, H. S. Potdar, Catal. Commun., 2008, 9, 2035-2039.
10. [10]
  [10] J. W. Bae, S. H. Kang, Y. J. Lee, K. W. Jun, Appl. Catal. B, 2009, 90, 426-435.
11. [11]
  [11] J. L. Li, X. G. Zhang, T. Inui, Appl. Catal. A, 1996, 147, 23-33.
12. [12]
  [12] Y. J. Jin, S. Asaoka, X. H. Li, K. Asami, K. Fujimoto, J. Jpn. Petrol. Inst., 2004, 47, 394-402.
13. [13]
  [13] Y. J. Jin, S. Asaoka, X. H. Li, K. Asami, K. Fujimoto, J. Jpn. Petrol. Inst., 2005, 48, 45-52.
14. [14]
  [14] M. Turco, G. Bagnasco, U. Costantino, F. Marmottini, T. Montanari, G. Ramis, G. Busca, J. Catal., 2004, 228, 43-55.
15. [15]
  [15] C. Baltes, S. Vukojevic, F. Schüth, J. Catal., 2008, 258, 334-344.
16. [16]
  [16] X. R. Zhang, L. C. Wang, C. Z. Yao, Y. G. Cao, W. L. Dai, H. Y. He, K. N. Fan, Catal. Lett., 2005, 102, 83-89.
17. [17]
  [17] J. P. Shen, C. Song, Catal. Today, 2002, 77, 89-98.
18. [18]
  [18] J. H. Flores, D. P. B. Peixoto, L. G. Appel, R. R. de Avillez, M. I. P. da Silva, Catal. Today, 2011, 172, 218-225.
19. [19]
  [19] M. M. V. M. Souza, K. A. Ferreira, O. R. de Macedo Neto, N. F. P. Ribeiro, M. Schmal, Catal. Today, 2008, 133-135, 750-754.
20. [20]
  [20] M. Behrens, D. Brennecke, F. Girgsdies, S. Kiβner, A. Trunschke, N. Nasrudin, S. Zakaria, N. F. Idris, S. B. A. Hamid, B. Kniep, R. Fischer, W. Busser, M. Muhler, R. Schlögl, Appl. Catal. A, 2011, 392, 93-102.
21. [21]
  [21] F. Cavani, F. Trifirò, A. Vaccari., Catal Today, 1991, 11, 173-301.
22. [22]
  [22] G. J. A. A. Soler-Illia, R.J. Candal, A. E. Regazzoni, M. A. Blesa, Chem. Mater., 1997, 9, 184-191.
23. [23]
  [23] Q. J. Ge, Y. M. Huang, F. Y. Qiu, S. B. Li, Appl. Catal. A, 1998, 167, 23-30.
24. [24]
  [24] P. S. S. Prasad, J. W. Bae, S. H. Kang, Y J. Lee, K. W. Jun, Fuel Process. Technol., 2008, 89, 1291-1286.
25. [25]
  [25] J. H. Flores, G. Solorzano, M. I. P. da Silva, Appl. Surf. Sci., 2008, 254, 6461-6466.
26. [26]
  [26] M. Mühler, L. P. Nielsen, E. Törnqvist, B. S. Clausen, H. Topsoee, Catal. Lett., 1992, 14, 241-249.
27. [27]
  [27] J. P. Shen, C. Song, Catal. Today, 2002, 77, 89-98.
28. [28]
  [28] Y. Lwin, M. A. Yarmo, Z. Yaakob, A. B. Mohamad, W. R. W. Daud, Mater. Res. Bull., 2001, 36, 193-198.
29. [29]
  [29] M. Behrens, I. Kasatkin, S. Kühl, G. Weinberg, Chem. Mater., 2010, 22, 386-397.
30. [30]
  [30] Y. Okamoto, K. Fukino, T. Imanaka, S. Teranishi. J. Phys. Chem., 1983, 87, 3740-3747.
31. [31]
  [31] W. L. Dai, Q. Sun, J. F. Deng, D. Wu, Y. H. Sun, Appl. Surf. Sci., 2001, 177, 172-179.
32. [32]
  [32] G. Moretti, G. Fierro, M. L. O. Jacono, P. Porta, Surf. Interf. Anal., 1989, 14, 325-336.
33. [33]
  [33] A. A. G. Lima, M. Nele, E. L. Moreno, H. M. C. Andrade, Appl. Catal. A, 1998, 171, 31-43.
34. [34]
  [34] G. R. Moradi, S. Nosrati, F. Yaripor, Catal. Commun., 2007, 8, 598-606.
35. [35]
  [35] D. F. Jin, B. Zhu, Z. Y. Hou, J. H. Fei, H. Lou, X. M. Zheng, Fuel, 2007, 86, 2707-2713.
36. [36]
  [36] S. D. Kim, S. C. Baek, Y. J. Lee, K. W. Jun, M. J. Kim, I. S. Yoo, Appl. Catal. A, 2006, 309, 139-143.
37. [37]
  [37] X. R. Zhang, L. C. Wang, C. Z. Yao, Y. Cao, W. L. Dai, H. Y. He, K. N. Fan, Catal. Lett., 2005, 102, 183-190.
38. [38]
  [38] J. Palgunadi, I. Yati, K. D. Jung, Reac. Kinet. Metch. Catal., 2010, 101, 117-128.
39. [39]
  [39] P. Gao, F. Li, F. K. Xiao, N. Zhao, W. Wei, L. S. Zhong, Y. H. Sun, Catal. Today, 2012, 194, 9-15.
40. [40]
  [40] P. Gao, F. Li, H. J. Zhan, N. Zhao, F. K. Xiao, W. Wei, L. S. Zhong, H. Wang, Y. H. Sun, J. Catal., 2013, 298, 51-60.
41. [41]
  [41] P. Gao, R. Xie, H. Wang, L. Zhang, L. Xia, Z. Zhang, W. Wei, Y. Sun, J. CO₂ Utilization, 2015, in press.
42. [42]
  [42] Z. Li, S. W. Yan, M. Fan, Fuel, 2013, 106, 178-186.
43. [43]
  [43] Z. Li, H. Y. Zheng, K. C. Kie, Chin. J. Catal., 2008, 29, 431-435.
44. [44]
  [44] G. Fierro, M. Lo Jacono, M. Inversi, P. Porta, R. Lavecchia, F. Cioci, J. Catal., 1994, 148, 709-721.
45. [45]
  [45] B. Lindström, L. J. Pettersson, P. G. Menon, Appl. Catal. A, 2002, 234, 111-125.
46. [46]
  [46] U. Constantino, F. Marmottini, M. Nocchetti, R. Vivani, Eur. J. Inorg. Chem., 1998, 1439-1446.
47. [47]
  [47] M. M. Günter, T. Ressler, R. E. Jentoft, B. Bems, J. Catal., 2001, 203, 133-149.
48. [48]
  [48] J. Agrell, H. Birgersson, M. Boutonnet, I. Meliàn-Cabrera, R. M. Navarro, J. L. G. Fierro, J. Catal., 2003, 219, 389-403.
49. [49]
  [49] W. Fu, Z. H. Bao, W. Z. Ding, K. C. Chou, Q. Li, Catal. Commun., 2011, 12, 505-509.
50. [50]
  [50] Y. Y. Liu, T. Hayakawa, K. Suzuki, S. Hamakawa, T. Tsunoda, T. Ishii, M. Kumagai, Appl. Catal. A, 2002, 223, 137-145.
51. [51]
  [51] W. R. A. M. Robinson, J. C. Mol, Appl. Catal., 1991, 76, 117-129.
52. [52]
  [52] K. Fujimoto, H. Kaneko, Q. W. Zhang, Q. J. Ge, X. H. Li, Stud. Surf. Sci. Catal., 2007, 167, 349-354.
53. [53]
  [53] J. M. Fougerit, N. S. Gnep, M. Guisnet, Microporous Mesoporous Mater., 1999, 29, 79-89.
54. [54]
  [54] K. Asami, Q. W. Zhang, X. H. Li, S. Asaoka, K. Fujimoto, Stud. Surf. Sci. Catal., 2004, 147, 427-432.
55. [55]
  [55] Q. J. Ge, T. Tomonobu, K. Fujimoto, X. H. Li, Catal. Commun., 2008, 9, 1775-1778.
56. [56]
  [56] C. M. Li, K. Fujimoto, Energy Fuels, 2014, 28, 1331-1337.
57. [57]
  [57] C. M. Li, K. Fujimoto, Catal. Sci. Technol., 2015, 5, 4501-4510.
58. [58]
  [58] V. M. Mysov, S. I. Reshetnikov, V. G. Stepanov, K. G. Ione, Chem. Eng. J., 2005, 107, 63-71.
1. [1]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
2. [2]
  Honghong Zhang , Zhen Wei , Derek Hao , Lin Jing , Yuxi Liu , Hongxing Dai , Weiqin Wei , Jiguang Deng . Recent advances in synergistic catalytic valorization of CO₂ and hydrocarbons by heterogeneous catalysis. Acta Physico-Chimica Sinica, 2025, 41(7): 100073-. doi: 10.1016/j.actphy.2025.100073
3. [3]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . 二维共价有机框架作为光催化剂在有机合成中的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-. doi: 10.1016/j.actphy.2025.100086
4. [4]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
5. [5]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
6. [6]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
7. [7]
  Xiaofang Li , Zhigang Wang . Modulating d_z²-orbital occupancy of Au cocatalysts for enhanced photocatalytic H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-. doi: 10.1016/j.actphy.2025.100080
8. [8]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
9. [9]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
10. [10]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
11. [11]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
12. [12]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
13. [13]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
14. [14]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
15. [15]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
16. [16]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
17. [17]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
18. [18]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
19. [19]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
20. [20]
  Zhilian Liu , Wengui Wang , Hongxiao Yang , Yu Cui , Shoufeng Wang . Ideological and Political Education Design for the Synthesis of Irinotecan Drug Intermediate 7-Ethyl Camptothecin. University Chemistry, 2024, 39(2): 89-93. doi: 10.3866/PKU.DXHX202306012

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(468)
HTML views(45)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Cu-ZnO-Al2O3 supported on H-ferrierite on hydrocarbons formation from CO hydrogenation

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Cu-ZnO-Al₂O₃ supported on H-ferrierite on hydrocarbons formation from CO hydrogenation