Citation: Lingling Fu, Yijuan Lu, Zhigang Liu, Runliang Zhu. Influence of the metal sites of M-N-C (M = Co, Fe, Mn) catalysts derived from metalloporphyrins in ethylbenzene oxidation[J]. Chinese Journal of Catalysis, ;2016, 37(3): 398-404. doi: 10.1016/S1872-2067(15)61029-4 shu

Influence of the metal sites of M-N-C (M = Co, Fe, Mn) catalysts derived from metalloporphyrins in ethylbenzene oxidation

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a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan, China;
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b Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China

Corresponding author: Zhigang Liu,
Received Date: 15 October 2015
Available Online: 24 November 2015
Fund Project: 国家自然科学基金(21103045,1210040,1103312) (21103045,1210040,1103312)中国石油大学重质油国家重点实验室(SKCHOP201504) (SKCHOP201504)中国科学院广州地球与化学研究所中国科学院矿物学与成矿学重点实验室(KLMM20150103). (KLMM20150103)

Transition metal catalysts M-N-C (M = Co, Fe, Mn) were synthesized by a template-free method by heating meso-tetraphenyl porphyrins (i.e. CoTPP, FeTPPCl, MnTPPCl) precursors. The catalysts were characterized by N₂ adsorption-desorption, thermogravimetry, high-resolution transmission electron microscopy, and Raman and X-ray photoelectron spectroscopy. The selective oxidation of ethylbenzene with molecular oxygen under a solvent-free condition was carried out to explore the catalytic performance of the M-N-Cs, which exhibited different catalytic performance. That was ascribed to the difference in M (Co, Fe, Mn) and different graphitization degree forming during the heating process, in which M (Co, Fe, Mn) might have different catalytic activity on the formation of the M-N-C catalyst. All the M-N-C composites had remarkable recyclability in the selective oxidation of ethylbenzene.
- M(cobalt, iron, manganese)-N-C,
- Transition metal,
- Nitrogen-doped carbon,
- Porphyrin,
- Ethylbenzene oxidation
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