Citation: Bingyang Bai, Qi Qiao, Junhua Li, Jiming Hao. Synthesis of three-dimensional ordered mesoporous MnO₂ and its catalytic performance in formaldehyde oxidation[J]. Chinese Journal of Catalysis, ;2016, 37(1): 27-31. doi: 10.1016/S1872-2067(15)61026-9 shu

Synthesis of three-dimensional ordered mesoporous MnO₂ and its catalytic performance in formaldehyde oxidation

Bingyang Bai ^a,b ,
Qi Qiao ^a,b,, ,
Junhua Li ^c,, ,
Jiming Hao ^c

1.
a State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China;
2.
b Key Laboratory of Eco-Industry of the Ministry of Environmental Protection, Chinese Research Academy of Environmental Sciences, Beijing 100012, China;
3.
c State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, China

Corresponding author: Qi Qiao, Junhua Li,
Received Date: 28 May 2015
Available Online: 7 July 2015
Fund Project: 国家自然科学基金(21325731, 21221004, 51478241). (21325731, 21221004, 51478241)

Three-dimensional (3D) ordered mesoporous MnO₂ was prepared using KIT-6 mesoporous molecular sieves as a hard template. The material was used for catalytic oxidation of HCHO. The material has high surface areas and the mesoporous characteristics of the template, with cubic symmetry (ia3d). It consists of a β-MnO₂ crystalline phase corresponding to pyrolusite, with a rutile structure. Transmission electron microscopy and X-ray photoelectron spectroscopy showed that the 3D-MnO₂ catalyst has a large number of exposed Mn⁴⁺ ions on the (110) crystal plane surfaces, with a lattice spacing of 0.311 nm; this enhances oxidation of HCHO. Complete conversion of HCHO to CO₂ and H₂O was achieved at 130 ℃ on 3D-MnO₂; the same conversions on α-MnO₂ and β-MnO₂ nanorods were obtained at 140 and 180 ℃, respectively, under the same conditions. The specific mesoporous structure, high specific surface area, and large number of surface Mn⁴⁺ ions are responsible for the catalytic activity of 3D-MnO₂ in HCHO oxidation.
- Three-dimensional ordered material,
- Mesoporous structure,
- Manganese oxide,
- Formaldehyde,
- Catalytic oxidation
1. [1]
  [1] R. T. Huang, Y. Y. Liu, Z. W. Chen, D. Y. Pan, Z. Li, M. H. Wu, C. H. Shek, C. M. L. Wu, J. K. L. Lai, ACS Appl. Mater. Interfaces, 2015, 7, 3949.
2. [2]
  [2] Z. W. Chen, Z. Jiao, D. Y. Pan, Z. Li, M. H. Wu, C. H. Shek, C. M. L. Wu, J. K. L. Lai, Chem. Rev., 2012, 112, 3833.
3. [3]
  [3] Y. Y. Liu, Z. W. Chen, C. H. Shek, C. M. L. Wu, J. K. L. Lai, ACS Appl. Mater. Interfaces, 2014, 6, 9776.
4. [4]
  [4] C. Chen, G. J. Ding, D. Zhang, Z. Jiao, M. H. Wu, C. H. Shek, C. M. L. Wu, J. K. L. Lai, Z. W. Chen, Nanoscale, 2012, 4, 2590.
5. [5]
  [5] Z. W. Chen, Z. Jiao, M. H. Wu, C. H. Shek, C. M. L. Wu, J. K. L. Lai, Prog. Mater. Sci., 2011, 56, 901.
6. [6]
  [6] B. Y. Bai, J. H. Li, J. M. Hao, Appl. Catal. B, 2015, 164, 241.
7. [7]
  [7] Q. Ye, J. S. Zhao, F. F. Huo, D. Wang, S. Y. Cheng, T. F. Kang, H. X. Dai, Microporous Mesoporous Mater., 2013, 172, 20.
8. [8]
  [8] J. G. Deng, L. Zhang, H. X. Dai, Y. S. Xia, H. Y. Jiang, H. Zhang, H. He, J. Phys. Chem. C, 2010, 114, 2694.
9. [9]
  [9] F. Jiao, P. G. Bruce, Adv. Mater., 2007, 19, 657.
10. [10]
  [10] X. F. Tang, X. M. Huang, J. J. Shao, J. L. Liu, Y. G. Li, Y. D. Xu, W. J. Shen, Chin. J. Catal., 2006, 27, 97.
11. [11]
  [11] B. Y. Bai, J. H. Li, ACS Catal., 2014, 4, 2753.
12. [12]
  [12] X. F. Tang, J. L. Chen, X. M. Huang, Y. D. Xu, W. J. Shen, Appl. Catal. B, 2008, 81, 115.
13. [13]
  [13] B. Y. Bai, H. Arandiyan, J. H. Li, Appl. Catal. B, 2013, 142-143, 677.
14. [14]
  [14] X. Wang, Y. D. Li, J. Am. Chem. Soc., 2002, 124, 2880.
15. [15]
  [15] C. Wang, L. Sun, Q. Q. Cao, B. Q. Hu, Z. W. Huang, X. F. Tang, Appl. Catal. B, 2011, 101, 598.
16. [16]
  [16] A. E. Espinal, L. C. Zhang, C. H. Chen, A. Morey, Y. F. Nie, L. Espinal, B. O. Wells, R. Joesten, M. Aindow, S. L. Suib, Nat. Mater., 2010, 9, 54.
17. [17]
  [17] L. Ma, D. S. Wang, J. H. Li, B. Y. Bai, L. X. Fu, Y. D. Li, Appl. Catal. B, 2014, 148-149, 36.
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Synthesis of three-dimensional ordered mesoporous MnO₂ and its catalytic performance in formaldehyde oxidation