Citation: Huiru Zhao, Shumei Shi, Jinxiong Wu, Yue Ding, Niu Li. Charge compensation dominates the distribution of silica in SAPO-34[J]. Chinese Journal of Catalysis, ;2016, 37(2): 227-233. doi: 10.1016/S1872-2067(15)61025-7 shu

Charge compensation dominates the distribution of silica in SAPO-34

Huiru Zhao ^a ,
Shumei Shi ^a,b ,
Jinxiong Wu ^a ,
Yue Ding ^a ,
Niu Li ^a,b,,

1.
a Institute of New Catalytic Material Science, School of Materials Science and Engineering, Nankai University, Tianjin 300071, China;
2.
b National Institute for Advanced Materials, Nankai University, Tianjin 300071, China

Corresponding author: Niu Li,
Received Date: 13 November 2015
Available Online: 23 November 2015
Fund Project: 天津市自然科学基金(12JCYBJC 12700). (12JCYBJC 12700)

The distribution of Si atoms in the SAPO-34 framework determines its acidity and catalytic effects. This was investigated using the charge balance between the inorganic framework and trapped template ions. Three types of templates, which yielded R⁺, 2R⁺ and 2R²⁺ positive charges in the cages of SAPO-34, were obtained from single crystal data and they were used to direct the synthesis of SAPO-34 with different Si contents and formation of isolated Si atoms and Si islands in the lattice. The concentration limits of SiO₂ in the gel for constituting isolated Si atoms were calculated and verified experimentally. Si islands, including 5-Si, 8-Si, 11-Si, 14-Si island were described on the basis of host-guest charge compensation. An overall view of the distribution of Si atoms in SAPO-34 was given and a criterion for the strength and density of acid sites in SAPO-34 for it to be an efficient catalyst for MTO was made available.
- SAPO-34,
- Si distribution,
- Synthesis,
- Silicon island,
- Methanol to olefins
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