Citation: Jia Liu, Li Yan, Miao Jiang, Cunyao Li, Yunjie Ding. Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO₂ catalyst[J]. Chinese Journal of Catalysis, ;2016, 37(2): 268-272. doi: 10.1016/S1872-2067(15)61019-1 shu

Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO₂ catalyst

Jia Liu ^a,c ,
Li Yan ^a,b,, ,
Miao Jiang ^a,c ,
Cunyao Li ^a,c ,
Yunjie Ding ^a,b,,

1.
a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
2.
b State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
3.
c University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Li Yan, Yunjie Ding,
Received Date: 24 August 2015
Available Online: 10 November 2015
Fund Project: 国家自然科学基金(21273227, 20903090). (21273227, 20903090)

Rh/SiO₂ catalysts with tethered-phosphines with different alkyl spacer lengths have been prepared, tested and characterized. Lengthening the alkyl spacer of the tethered-phosphine improved the flexibility of tethered-phospine, promoted the formation of active species and enhanced the activity of hydroformylation over other tethered-phosphine modified Rh/SiO₂ catalysts.
- Tethered phosphine,
- Chain length,
- Rhodium,
- Silica,
- Hydroformylation
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Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO2 catalyst

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Effect of lengthening alkyl spacer on hydroformylation performance of tethered-phosphine modified Rh/SiO₂ catalyst