Citation: Ting Yi, Yibo Zhang, Jingwei Li, Xiangguang Yang. Promotional effect of H₃PO₄ on ceria catalyst for selective catalytic reduction of NO by NH₃[J]. Chinese Journal of Catalysis, ;2016, 37(2): 300-307. doi: 10.1016/S1872-2067(15)60977-9 shu

Promotional effect of H₃PO₄ on ceria catalyst for selective catalytic reduction of NO by NH₃

Ting Yi ^a ,
Yibo Zhang ^a,b,, ,
Jingwei Li ^a ,
Xiangguang Yang ^a,b,,

1.
a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China;
2.
b Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China

Corresponding author: Yibo Zhang, Xiangguang Yang,
Received Date: 24 July 2015
Available Online: 24 September 2015
Fund Project: 国家自然科学基金(21177120) (21177120)

A series of H₃PO₄-modified CeO₂ samples were prepared by impregnation of CeO₂ with H₃PO₄ solution, and evaluated for the selective catalytic reduction of NO_x by NH₃. The samples were characterized by X-ray diffraction, N₂ adsorption-desorption, infrared spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, temperature-programmed desorption of NH₃, and temperature-programmed reduction of H₂. The results showed that more than 80% NO conversion was achieved in the temperature range 250-550℃ over the H₃PO₄-CeO₂ catalyst. The enhanced catalytic performance could be ascribed to the increase in acidic strength, especially Brönsted acidity, and reduction in redox properties of the CeO₂ after H₃PO₄ modification.
- Ammonia,
- Selective catalytic reduction,
- Ceria,
- Phosphoric acid,
- Redox,
- Acidity
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Promotional effect of H₃PO₄ on ceria catalyst for selective catalytic reduction of NO by NH₃