Citation: Bahaa M. Abu-Zied, Abdullah M. Asiri. The role of alkali promoters in enhancing the direct N₂O decomposition reactivity over NiO catalysts[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1837-1845. doi: 10.1016/S1872-2067(15)60963-9 shu

The role of alkali promoters in enhancing the direct N₂O decomposition reactivity over NiO catalysts

Bahaa M. Abu-Zied ^a,b,c,, ,
Abdullah M. Asiri ^a,c

1.
a Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah 21589, Saudi Arabia;

Corresponding author: Bahaa M. Abu-Zied,
Received Date: 5 May 2015
Available Online: 21 August 2015

Direct N₂O decomposition has been investigated over bare NiO and a series of its alkali-promoted catalysts. These catalysts were characterized by X-ray diffractometry, X-ray photoelectron spectroscopy (XPS) and field emission scanning electron microscopy. XPS analysis revealed that surface nickel is present in three forms: metal particles, NiO and Ni(OH)₂. It is suggested that nickel(0) valent atoms are essential for the interaction with N₂O molecules at the catalyst surfaces. Bare NiO exhibited a very low N₂O decomposition reactivity. However, the alkali-containing catalysts exhibited a marked activity enhancement.
- N₂O decomposition,
- Greenhouse gas,
- NiO,
- Alkali-promotion,
- Activity enhancement
1. [1]
  [1] Pérez-Ramírez J. Appl Catal B, 2007, 70: 31
2. [2]
  [2] Yuranov I, Bulushev D A, Renken A, Kiwi-Minsker L. Appl Catal A, 2007, 319: 128
3. [3]
  [3] Wood B R, Reimer J A, Bell A T, Janicke M T, Ott K C. J Catal, 2004, 225: 300
4. [4]
  [4] Kapteijn F, Rodriguez-Mirasol J, Moulijn J A. Appl Catal B, 1996, 9: 25
5. [5]
  [5] Abu-Zied B M, Schwieger W, Unger A. Appl Catal B, 2008, 84: 277
6. [6]
  [6] Abu-Zied B M, Soliman S A. Catal Lett, 2009, 132: 299
7. [7]
  [7] Abu-Zied B M. Microporous Mesoporous Mater, 2011, 139: 59
8. [8]
  [8] Abu-Zied B M. Chin J Catal (催化学报), 2011, 32: 264
9. [9]
  [9] Abu-Zied B M, Soliman S A, Abdellah S E. Chin J Catal (催化学报), 2014, 35: 1105
10. [10]
  [10] Abu-Zied B M, Soliman S A, Abdellah S E. J Ind Eng Chem, 2015, 21: 814
11. [11]
  [11] Asano K, Ohnishi C, Iwamoto S, Shioya Y, Inoue M. Appl Catal B, 2008, 78: 242
12. [12]
  [12] Stelmachowski P, Maniak G, Kotarba A, Sojka Z. Catal Commun, 2009, 10: 1062
13. [13]
  [13] Haber J, Machej T, Janas J, Nattich M. Catal Today, 2004, 90: 15
14. [14]
  [14] Haber J, Nattich M, Machej T. Appl Catal B, 2008, 77: 278
15. [15]
  [15] Pasha N, Lingaiah N, Reddy P S S, Prasad P S S. Catal Lett, 2007, 118: 64
16. [16]
  [16] Cheng H K, Huang Y Q, Wang A Q, Li L, Wang X D, Zhang T. Appl Catal B, 2009, 89: 391
17. [17]
  [17] Pasha N, Lingaiah N, Babu N S, Reddy P S S, Prasad P S S. Catal Commun, 2008, 10: 132
18. [18]
  [18] Pasha N, Lingaiah N, Reddy P S S, Prasad P S S. Catal Lett, 2009, 127: 101
19. [19]
  [19] Yoshino H, Ohnishi C H, Hosokawa S, Wada K, Inoue M. J Mater Sci, 2011, 46:797
20. [20]
  [20] Maniak G, Stelmachowski P, Zasada F, Piskorz W, Kotarba A, Sojka Z. Catal Today, 2011, 176: 369
21. [21]
  [21] Maniak G, Stelmachowski P, Kotarba A, Sojka Z, Rico-Pérez V, Bueno-López A. Appl Catal B, 2013, 136-137: 302
22. [22]
  [22] Zhang F F, Wang X P, Zhang X X, Turxun M, Yu H B, Zhao J J. Chem Eng J, 2014, 256: 365
23. [23]
  [23] Wu H P, Qian Z Y, Xu X L, Xu X F. J Fuel Chem Technol, 2011, 39: 115
24. [24]
  [24] Wu H P, Li W J, Guo L, Pan Y F, Xu X F. J Fuel Chem Technol, 2011, 39: 550
25. [25]
  [25] Pachatouridou E, Papista E, Iliopoulou E F, Delimitis A, Goula G, Yentekakis I V, Marnellos G E, Konsolakis M. J Environ Chem Eng, 2015, 3: 815
26. [26]
  [26] Konsolakis M, Aligizou F, Goula G, Yentekakis I V. Chem Eng J, 2013, 230: 286
27. [27]
  [27] Konsolakis M, Drosou C, Yentekakis I V. Appl Catal B, 2012, 123-124: 405
28. [28]
  [28] Sugawara K, Nobukawa T, Yoshida M, Sato Y, Okumura K, Tomishige K, Kunimori K. Appl Catal B, 2007, 69: 154
29. [29]
  [29] Zhang X Y, Shen Q, He C, Ma C Y, Cheng J, Hao Z P. Catal Commun, 2012, 18: 151
30. [30]
  [30] Colombo M, Nova I, Tronconi E, SchmeiBer V, Bandl-Konrad B, Zimmermann L. Appl Catal B, 2012, 111-112: 106
31. [31]
  [31] Debbagh M N, Bueno-López A, de Lecea C S M, Pérez-Ramírez J. Appl Catal A, 2007, 327: 66
32. [32]
  [32] Debbagh M N, de Lecea C S M, Pérez-Ramírez J. Appl Catal B, 2007, 70: 335
33. [33]
  [33] Kögel M, Mönnig R, Schwieger W, Tissler A, Turek T. J Catal, 1999, 182: 470
34. [34]
  [34] Nobukawa T, Sugawara K, Okumura K, Tomishige K, Kunimori K. Appl Catal B, 2007, 70: 342
35. [35]
  [35] Pophal C, Yogo T, Yamada K, Segawa K. Appl Catal B, 1998, 16: 177
36. [36]
  [36] Yamada K, Kondo S, Segawa K. Microporous Mesoporous Mater, 2000, 35-36: 227
37. [37]
  [37] Pekridis G, Kaklidis N, Konsolakis M, Iliopoulou E F, Yentekakis I V, Marnellos G E. Top Catal, 2011, 54: 1135
38. [38]
  [38] Barakat N A M, Abdelkareem M A, El-Newehy M, Kim H Y. Nanoscale Res Lett, 2013, 8: 402/1
39. [39]
  [39] Farzaneh F, Mehraban Z, Norouzi F. Environ Chem Lett, 2010, 8: 69
40. [40]
  [40] Zhou D S, Yan A F, Wu Y, Wu T H. Indian J Chem A, 2013, 52: 51
41. [41]
  [41] Wang Y P, Zhu J W, Yang X J, Lu L D, Wang X. Thermochim Acta, 2005, 437: 106
42. [42]
  [42] Hussein G A M, Nohman A K H, Attyia K M A. J Therm Anal, 1994, 42: 1155
43. [43]
  [43] Mohamed M A, Halawy S A, Ebrahim M M. J Anal Appl Pyr, 1993, 27: 109
44. [44]
  [44] Konsolakis M, Carabineiro S A C, Papista E, Marnellos G E, Tavares P B, Moreira J A, Romaguera-Barcelay Y, Figueiredo J L. Catal Sci Technol, 2015, 5: 3714
45. [45]
  [45] Abu-Zied B M. Appl Catal A, 2008, 334: 234
46. [46]
  [46] Zhai X L, Cheng Y H, Zhang Z T, Jin Y, Cheng Y. Int J Hydrogen Energy, 2011, 36: 7105
47. [47]
  [47] Guil-López R, La Parola V, Peña M A, Fierro J L G. Int J Hydrogen Energy, 2012, 37: 7042
48. [48]
  [48] Lin W W, Cheng H Y, Ming J, Yu Y C, Zhao F Y. J Catal, 2012, 291: 149
49. [49]
  [49] Kaichev V V, Gladky A Y, Prosvirin I P, Saraev A A, Hävecker M, Knop-Gericke A, Schlögl R, Bukhtiyarov V I. Surf Sci, 2013, 609: 113
50. [50]
  [50] Greiner M T, Helander M G, Wang Z B, Tang W M, Lu Z H. J Phys Chem C, 2010, 114: 19777
51. [51]
  [51] Seo H O, Nam J W, Kim K D, Sim J K, Kim Y D, Lim D C. J Mol Catal A, 2012, 361-362: 45
52. [52]
  [52] Abu-Zied B M, Asiri A M. Thermochim Acta, 2014, 581: 110
53. [53]
  [53] Roy B, Artyushkova K, Pham H N, Li L, Datye A K, Leclerc C A. Int J Hydrogen Energy, 2012, 37: 18815
54. [54]
  [54] Rodríguez J L, Valenzuela M A, Poznyak T, Lartundo L, Chairez I. J Hazard Mater, 2013, 262: 472
55. [55]
  [55] Rocca M, Savio L, Vattuone L, Burghaus U, Palomba V, Novelli N, Buatier de Mongeot F, Valbusa U, Gunnella R, Comelli G, Baraldi A, Lizzit S, Paolucci G. Phys Rev B, 2000, 61: 213
56. [56]
  [56] Liu Y M, Wang T, Sun X, Fang Q Q, Lü Q R, Song X P, Sun Z Q. Appl Surf Sci, 2011, 257: 6540
57. [57]
  [57] Payne B P, Biesinger M C, McIntyre N S. J Electron Spectrosc Relat Phenom, 2012, 185: 159
58. [58]
  [58] Biesinger M C, Payne B P, Lau L W M, Gerson A, Smart R St C. Surf Interf Anal, 2009, 41: 324
59. [59]
  [59] Piumetti M, Bensaid S, Russo N, Fino D. Appl Catal B, 2015, 165: 742
60. [60]
  [60] Yamashita T, Vannic A. J Catal, 1996, 161: 254
61. [61]
  [61] Pietrzyk P, Zasada F, Piskorz W, Kotarba A, Sojka Z. Catal Today, 2007, 119: 219
1. [1]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
2. [2]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
3. [3]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
4. [4]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
5. [5]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
6. [6]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
7. [7]
  Meiran Li , Yingjie Song , Xin Wan , Yang Li , Yiqi Luo , Yeheng He , Bowen Xia , Hua Zhou , Mingfei Shao . Nickel-Vanadium Layered Double Hydroxides for Efficient and Scalable Electrooxidation of 5-Hydroxymethylfurfural Coupled with Hydrogen Generation. Acta Physico-Chimica Sinica, 2024, 40(9): 2306007-0. doi: 10.3866/PKU.WHXB202306007
8. [8]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
9. [9]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
10. [10]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
11. [11]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
12. [12]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
13. [13]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
14. [14]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
15. [15]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-0. doi: 10.3866/PKU.WHXB202407020
16. [16]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
17. [17]
  Zilin Hu , Yaoshen Niu , Xiaohui Rong , Yongsheng Hu . Suppression of Voltage Decay through Ni³⁺ Barrier in Anionic-Redox Active Cathode for Na-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306005-0. doi: 10.3866/PKU.WHXB202306005
18. [18]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
19. [19]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
20. [20]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(376)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

The role of alkali promoters in enhancing the direct N2O decomposition reactivity over NiO catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

The role of alkali promoters in enhancing the direct N₂O decomposition reactivity over NiO catalysts