Citation: Peter Adeniyi Alaba, Yahaya Muhammad Sani, Wan Mohd Ashri Wan Daud. Synthesis and characterization of hierarchical nanoporous HY zeolites from acid-activated kaolin[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1846-1851. doi: 10.1016/S1872-2067(15)60962-7 shu

Synthesis and characterization of hierarchical nanoporous HY zeolites from acid-activated kaolin

1.
a Department of Chemical Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia;

Corresponding author: Wan Mohd Ashri Wan Daud,
Received Date: 1 May 2015
Available Online: 15 August 2015

Hierarchical nanoporous HY zeolites were synthesized from acid-activated kaolin. The hierarchical factor (HF) was maximized by varying the aging and crystallization time. This was achieved by maximizing the external surface area without greatly reducing the micropore volume. The resulting products were characterized using X-ray diffraction (XRD), X-ray fluorescence, N₂ adsorption, and NH₃ temperature-programmed desorption. The nanoporous HY zeolite with the highest HF was obtained by aging for 48 h and a crystallization time of 24 h. The acidity and crystallinity varied depending on the operating parameters. Incorporation of an appropriate amount of NaCl was also vital in maximizing the HF, crystallinity, and acidity. The sample crystallinities were determined by comparing their XRD peak intensities with those of a conventional Y zeolite. The results show that optimizing this process could lead to a widely acceptable commercial route for HY zeolite production.
- HY zeolite,
- Kaolin,
- Hierarchical mesopore,
- Hierarchical factor,
- Relative crystallinity
1. [1]
  [1] Karami D, Rohani S. Chem Eng Process, 2009, 48: 1288
2. [2]
  [2] Shen S C, Chen Q, Chow P S, Tan G H, Zeng X T, Wang Z, Tan R B H. J Phys Chem C, 2007, 111: 700
3. [3]
  [3] Verhoef M J, Kooyman P J, van der Waal J C, Rigutto M S, Peters J A, van Bekkum H. Chem Mater, 2001, 13: 683
4. [4]
  [4] Groen J C, Moulijn J A, Pérez-Ramírez J. J Mater Chem, 2006, 16: 2121
5. [5]
  [5] Guo W P, Huang L M, Deng P, Xue Z Y, Li Q Z. Microporous Mesoporous Mater, 2001, 44-45: 427
6. [6]
  [6] Huang L M, Guo W P, Deng P, Xue Z Y, Li Q Z. J Phys Chem B, 2000, 104: 2817
7. [7]
  [7] Tan Q F, Bao X J, Song T C, Fan Y, Shi G, Shen B, Liu C H, Gao X H. J Catal, 2007, 251: 69
8. [8]
  [8] Ogura M, Shinomiya S Y, Tateno J, Nara Y, Nomura M, Kikuchi E, Matsukata M. Appl Catal A, 2001, 219: 33
9. [9]
  [9] Jacobsen C J H, Madsen C, Houzvicka J, Schmidt I, Carlsson A. J Am Chem Soc, 2000, 122: 7116
10. [10]
  [10] Han Y, Wu S, Sun Y Y, Li D S, Xiao F S, Liu J, Zhang X Z. Chem Mater, 2002, 14: 1144
11. [11]
  [11] van Donk S, Janssen A H, Bitter J H, de Jong K P. Catal Rev-Sci Eng, 2003, 45: 297
12. [12]
  [12] Xu M C, Cheng M J, Bao X H. Chem Commun, 2000: 1873
13. [13]
  [13] Rong T J, Xiao J K. Mater Lett, 2002, 57: 297
14. [14]
  [14] Lenarda M, Storaro L, Talon A, Moretti E, Riello P. J Colloid Interface Sci, 2007, 311: 537
15. [15]
  [15] Liu X M, Yan Z F, Wang H P, Luo Y T. J Nat Gas Chem, 2003, 12: 63
16. [16]
  [16] Chandrasekhar S, Pramada P. Appl Clay Sci, 2004, 27: 187
17. [17]
  [17] Yu J, Shi J L, Chen H R, Yan J N, Yan D S. Microporous Mesoporous Mater, 2001, 46: 153
18. [18]
  [18] Hosseinpour N, Mortazavi Y, Bazyari A, Khodadadi A A. Fuel Process Technol, 2009, 90: 171
19. [19]
  [19] Frunz L, Prins R, Pirngruber G D. Microporous Mesoporous Mater, 2006, 88: 152
20. [20]
  [20] Zheng J J, Yi Y M, Wang W L, Guo K, Ma J H, Li R F. Microporous Mesoporous Mater, 2013, 171: 44
21. [21]
  [21] Pérez-Ramírez J, Verboekend D, Bonilla A, Abello S. Adv Funct Mater, 2009, 19: 3972
22. [22]
  [22] Zheng J J, Zeng Q H, Yi Y M, Wang Y, Ma J H, Qin B, Zhang X W, Sun W F, Li R F. Catal Today, 2011, 168: 124
23. [23]
  [23] Zheng J J, Zeng Q H, Zhang Y Y, Wang Y, Ma J H, Zhang X W, Sun W F, Li R F. Chem Mater, 2010, 22: 6065
24. [24]
  [24] Konno H, Tago T, Nakasaka Y, Ohnaka R, Nishimura J I, Masuda T. Microporous Mesoporous Mater, 2013, 175: 25
25. [25]
  [25] Konno H, Okamura T, Kawahara T, Nakasaka Y, Tago T, Masuda T. Chem Eng J, 2012, 207-208: 490
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沈阳化工大学材料科学与工程学院沈阳 110142