Citation: Xin Zhao, Lei Huang, Hongrui Li, Hang Hu, Jin Han, Liyi Shi, Dengsong Zhang. Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1886-1899. doi: 10.1016/S1872-2067(15)60958-5 shu

Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃

Xin Zhao ^a ,
Lei Huang ^a,, ,
Hongrui Li ^a ,
Hang Hu ^a ,
Jin Han ^a ,
Liyi Shi ^b,, ,
Dengsong Zhang ^a,,

1.
a Research Center of Nano Science and Technology, Shanghai University, Shanghai 200444, China;

Corresponding author: Lei Huang, Liyi Shi, Dengsong Zhang,
Received Date: 18 June 2015
Available Online: 25 July 2015
Fund Project: 国家自然科学基金(21303099) (21303099) 国家重点基础研究发展计划(973计划, 2014CB660803) (973计划, 2014CB660803) 上海市教委项目(14ZZ097, B.3704713001) (14ZZ097, B.3704713001) 上海大学创新基金(K.10040713003). (K.10040713003)

Different transition metals were used to modify V₂O₅-based catalysts (M-V, M = Cu, Fe, Mn, Co) on TiO₂ via impregnation, for the selective reduction of NO with NH₃. The introduced metals induced high dispersion in the vanadium species and the formation of vanadates on the TiO₂ support, and increased the amount of surface acid sites and the strength of these acids. The strong acid sites might be responsible for the high N₂ selectivity at higher temperatures. Among these catalysts, Cu-V/TiO₂ showed the highest activity and N₂ selectivity at 225-375 ℃. The results of X-ray photoelectron spectroscopy, NH₃-temperature-programmed desorption, and in-situ diffuse reflectance infrared Fourier transform spectroscopy suggested that the improved performance was probably due to more active surface oxygen species and increased strong surface acid sites. The outstanding activity, stability, and SO₂/H₂O durability of Cu-V/TiO₂ make it a candidate to be a NO_x removal catalyst for stationary flue gas.
- deNO_x,
- Selective catalytic reduction,
- Vanadate,
- Transition metal
1. [1]
  [1] Zhang L, Shi L Y, Huang L, Zhang J P, Gao R H, Zhang D S. ACS Catal, 2014, 4: 1753
2. [2]
  [2] Kamolphop U, Taylor S F R, Breen J P, Burch R, Delgado J J, Chansai S, Hardacre C, Hengrasmee S, James S L. ACS Catal, 2011, 1: 1257
3. [3]
  [3] Deka U, Lezcano-Gonzalez I, Weckhuysen B M, Beale A M. ACS Catal, 2013, 3: 413
4. [4]
  [4] Maitarad P, Zhang D S, Gao R H, Shi L Y, Li H R, Huang L, Rungrotmongkol T, Zhang J P. J Phys Chem C, 2013, 117: 9999
5. [5]
  [5] Chen L, Li J H, Ge M F. J Phys Chem C, 2009, 113: 21177
6. [6]
  [6] Ettireddy P R, Ettireddy N, Boningari T, Pardemann R, Smirniotis P G. J Catal, 2012, 292: 53
7. [7]
  [7] Phil H H, Reddy M P, Kumar P A, Ju L K, Hyo J S. Appl Catal B, 2008, 78: 301
8. [8]
  [8] Bai S L, Zhao J H, Wang L, Zhu Z P. Catal Today, 2010, 158: 393
9. [9]
  [9] Kompio P G W A, Brückner A, Hipler F, Auer G, Löffler E, Grünert W. J Catal, 2012, 286: 237
10. [10]
  [10] Putluru S S R, Schill L, Gardini D, Mossin S, Wagner J B, Jensen A D, Fehrmann R. J Mater Sci, 2014, 49: 2705
11. [11]
  [11] Camposeco R, Castillo S, Mugica V, Mejía-Centeno I, Marín J. Chem Eng J, 2014, 242: 313
12. [12]
  [12] Koh H L, Park H K. J Ind Eng Chem, 2013, 19: 73
13. [13]
  [13] Centeno M A, Malet P, Carrizosa I, Odriozola J A. J Phys Chem B, 2000, 104: 3310
14. [14]
  [14] Lietti L, Nova I, Forzatti P. Top Catal, 2000, 11-12: 111
15. [15]
  [15] Lietti L, Nova I, Ramis G, Dall'Acqua L, Busca G, Giamello E, Forzatti P, Bregani F. J Catal, 1999, 187: 419
16. [16]
  [16] Du X S, Gao X, Fu Y C, Gao F, Luo Z Y, Cen K F. J Colloid Interface Sci, 2012, 368: 406
17. [17]
  [17] Li Q, Yang H S, Nie A M, Fan X Y, Zhang X B. Catal Lett, 2011, 141: 1237
18. [18]
  [18] Putluru S S R, Riisager A, Fehrmann R. Catal Lett, 2009, 133: 370
19. [19]
  [19] Gao R H, Zhang D S, Liu X G, Shi L Y, Maitarad P, Li H R, Zhang J P, Cao W G. Catal Sci Technol, 2013, 3: 191
20. [20]
  [20] Lee K J, Kumar P A, Maqbool M S, Rao K N, Song K H, Ha H P. Appl Catal B, 2013, 142-143: 705
21. [21]
  [21] Lee K J, Maqbool M S, Kumar P A, Song K H, Ha H P. Catal Lett, 2013, 143: 988
22. [22]
  [22] Ettireddy P R, Ettireddy N, Mamedov S, Boolchand P, Smirniotis P G. Appl Catal B, 2007, 76: 123
23. [23]
  [23] Vargas M A L, Casanova M, Trovarelli A, Busca G. Appl Catal B, 2007, 75: 303
24. [24]
  [24] Boningari T, Koirala R, Smirniotis P G. Appl Catal B, 2012, 127: 255
25. [25]
  [25] Sagar A, Trovarelli A, Casanova M, Schermanz K. SAE Int J Engines, 2011, 4: 1839
26. [26]
  [26] Yang S J, Wang C Z, Ma L, Peng Y, Qu Z, Yan N Q, Chen J H, Chang H Z, Li J H. Catal Sci Technol, 2013, 3: 161
27. [27]
  [27] Liu Z M, Li Y, Zhu T L, Su H, Zhu J Z. Ind Eng Chem Res, 2014, 53: 12964
28. [28]
  [28] Huang L, Shi L Y, Zhao X, Xu J, Li H R, Zhang J P, Zhang D S. CrystEngComm, 2014, 16: 5128
29. [29]
  [29] Liu F D, He H, Lian Z H, Shan W P, Xie L J, Asakura K, Yang W W, Deng H. J Catal, 2013, 307: 340
30. [30]
  [30] Casanova M, Schermanz K, Llorca J, Trovarelli A. Catal Today, 2012, 184: 227
31. [31]
  [31] Park E, Kim M, Jung H, Chin S, Jurng J. ACS Catal, 2013, 3: 1518
32. [32]
  [32] Zhang J, Xu Q, Li M J, Feng Z C, Li C. J Phys Chem C, 2009, 113: 1698
33. [33]
  [33] Zhang J, Xu Q, Feng Z C, Li M J, Li C. Angew Chem Int Ed, 2008, 47: 1766
34. [34]
  [34] Gao X T, Jehng J M, Wachs I E. J Catal, 2002, 209: 43
35. [35]
  [35] Giakoumelou I, Fountzoula C, Kordulis C, Boghosian S. J Catal, 2006, 239: 1
36. [36]
  [36] Besselmann S, Löffler E, Muhler M. J Mol Catal A, 2000, 162: 401
37. [37]
  [37] Huang L, Zhao X, Zhang L, Shi L Y, Zhang J P, Zhang D S. Nanoscale, 2015, 7: 2743
38. [38]
  [38] Li K R, Wang Y J, Wang S R, Zhu B L, Zhang S M, Huang W P, Wu S H. J Nat Gas Chem, 2009, 18: 449
39. [39]
  [39] Huo C L, Ouyang J, Yang H M. Sci Rep, 2014, 4: 3682
40. [40]
  [40] Zhao W, Zhong Q, Pan Y X, Zhang R. Chem Eng J, 2013, 228: 815
41. [41]
  [41] Zhao Y B, Qin Z F, Wang G F, Dong M, Huang L C, Wu Z W, Fan W B, Wang J G. Fuel, 2013, 104: 22
42. [42]
  [42] Chen S, Chu W, Liu X, Tong D G. J Nat Gas Chem, 2011, 20: 553
43. [43]
  [43] Liu F D, He H, Zhang C B, Feng Z C, Zheng L R, Xie Y N, Hu T D. Appl Catal B, 2010, 96: 408
44. [44]
  [44] Trawczyński J, Bielak B, Miśta W. Appl Catal B, 2005, 55: 277
45. [45]
  [45] Zheng J, Chu W, Zhang H, Jiang C F, Dai X Y. J Nat Gas Chem, 2010, 19: 583
46. [46]
  [46] Li C M, Zhou J Y, Gao W, Zhao J W, Liu J, Zhao Y F, Wei M, Evans D G, Duan X. J Mater Chem A, 2013, 1: 5370
47. [47]
  [47] Palacio L A, Silva J M, Ribeiro F R, Ribeiro M F. Catal Today, 2008, 133-135: 502
48. [48]
  [48] Nguyen L D, Loridant S, Launay H, Pigamo A, Dubois J L, Millet J M M. J Catal, 2006, 237: 38
49. [49]
  [49] Chary K V R, Kumar C P, Rajiah T, Srikanth C S. J Mol Catal A, 2006, 258: 313
50. [50]
  [50] Palacio L A, Silva E R, Catalão R, Silva J M, Hoyos D A, Ribeiro F R, Ribeiro M F. J Hazard Mater, 2008, 153: 628
51. [51]
  [51] Casanova M, Schermanz K, Llorca J, Trovarelli A. Catal Today, 2012, 184: 227
52. [52]
  [52] Cai S X, Zhang D S, Zhang L, Huang L, Li H R, Gao R H, Shi L Y, Zhang J P. Catal Sci Technol, 2014, 4: 93
53. [53]
  [53] Fang C, Zhang D S, Shi L Y, Gao R H, Li H R, Ye L P, Zhang J P. Catal Sci Technol, 2013, 3: 803
54. [54]
  [54] Zhang D S, Zhang L, Shi L Y, Fang C, Li H R, Gao R H, Huang L, Zhang J P. Nanoscale, 2013, 5: 1127
55. [55]
  [55] Zhang L, Zhang D S, Zhang J P, Ca i S X, Fang C, Huang L, Li H R, Gao R H, Shi L Y. Nanoscale, 2013, 5: 9821
56. [56]
  [56] Fang C, Zhang D S, Cai S X, Zhang L, Huang L, Li H R, Maitarad P, Shi L Y, Gao R H, Zhang J P. Nanoscale, 2013, 5: 9199
57. [57]
  [57] Shan W P, Liu F D, He H, Shi X Y, Zhang C B. Catal Today, 2012, 184: 160
58. [58]
  [58] Shan W P, Liu F D, He H, Shi X Y, Zhang C B. Appl Catal B, 2012, 115-116: 100
59. [59]
  [59] Tronconi E, Nova I, Ciardelli C, Chatterjee D, Weibel M. J Catal, 2007, 245: 1
60. [60]
  [60] Koebel M, Madia G, Raimondi F, Wokaun A. J Catal, 2002, 209: 159
61. [61]
  [61] Schwidder M, Heikens S, De Toni A, Geisler S, Berndt M, Brückner A, Grünert W. J Catal, 2008, 259: 96
62. [62]
  [62] Shi X Y, Liu F D, Xie L J, Shan W P, He H. Environ Sci Technol, 2013, 47: 3293
63. [63]
  [63] Liu F D, Asakura K, He H, Liu Y C, Shan W P, Shi X Y, Zhang C B. Catal Today, 2011, 164: 520
64. [64]
  [64] Long R Q, Yang R T. J Catal, 2002, 207: 158
65. [65]
  [65] Cheng L S, Yang R T, Chen N. J Catal, 1996, 164: 70
66. [66]
  [66] Liu F D, He H. J Phys Chem C, 2010, 114: 16929
67. [67]
  [67] Chmielarz L, Dziembaj R, Grzybek T, Klinik J, Łojewski T, Olszewska D, Węgrzyn A. Catal Lett, 2000, 70: 51
68. [68]
  [68] Wu Z B, Jiang B Q, Liu Y, Wang H Q, Jin R B. Environ Sci Technol, 2007, 41: 5812
69. [69]
  [69] Chen L, Li J H, Ge M F. Environ Sci Technol, 2010, 44: 9590
70. [70]
  [70] Peng Y, Wang C Z, Li J H. Appl Catal B, 2014, 144: 538
71. [71]
  [71] Zhu J, Gao F, Dong L H, Yu W J, Qi L, Wang Z, Dong L, Chen Y. Appl Catal B, 2010, 95: 144
72. [72]
  [72] Gu T T, Jin R B, Liu Y, Liu H F, Weng X L, Wu Z B. Appl Catal B, 2013, 129: 30
73. [73]
  [73] Liu F D, He H, Ding Y, Zhang C B. Appl Catal B, 2009, 93: 194
74. [74]
  [74] Larrubia M A, Ramis G, Busca G. Appl Catal B, 2001, 30: 101
75. [75]
  [75] Qi G, Yang R T, Chang R. Appl Catal B, 2004, 51: 93
76. [76]
  [76] Long R Q, Yang R T. J Catal, 2002, 207: 224
77. [77]
  [77] Zhou G Y, Zhong B C, Wang W H, Guan X J, Huang B C, Ye D Q, Wu H J. Catal Today, 2011, 175: 157
78. [78]
  [78] Foo R, Vazhnova T, Lukyanov D B, Millington P, Collier J, Rajaram R, Golunski S. Appl Catal B, 2015, 162: 174
79. [79]
  [79] Burkardt A, Weisweiler W, van den Tillaart J A A, Schäfer- Sindlinger A, Lox E S. Top Catal, 2001, 16-17: 369
80. [80]
  [80] Si Z C, Weng D, Wu X D, Li J, Li G. J Catal, 2010, 271: 43
81. [81]
  [81] Zhang Q L, Song Z X, Ning P, Liu X, Li H, Gu J J. Catal Commun, 2015, 59: 170
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通讯作者: 陈斌, bchen63@163.com

Highly dispersed V₂O₅/TiO₂ modified with transition metals (Cu, Fe, Mn, Co) as efficient catalysts for the selective reduction of NO with NH₃