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Citation: M. Ravi Chandra, T. Siva Rao, B. Sreedhar. Recyclable Sn-TiO2/polythiophene nanohybrid material for degradation of organic pollutants under visible-light irradiation[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1668-1678. doi: 10.1016/S1872-2067(15)60944-5 shu

Recyclable Sn-TiO2/polythiophene nanohybrid material for degradation of organic pollutants under visible-light irradiation

  • 1.

    a Department of Inorganic & Analytical Chemistry, School of Chemistry, Andhra University, Visakhapatnam 530003, India;

  • Corresponding author: T. Siva Rao, 
  • Received Date: 23 February 2015
    Available Online: 22 June 2015

  • A Sn-doped TiO2/polythiophene nanohybrid (SPNH) was synthesized by a modified sol-gel process at low temperature. The prepared catalyst was characterized by X-ray diffraction (XRD), infrared (IR) spectroscopy, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible (UV-Vis) diffuse reflectance spectrophotometry (UV-DRS), and Brunauer-Emmett-Teller surface area analysis. The XRD results confirmed that polythiophene (PTh) had no effect on the crystal structure of TiO2. IR spectra and UV-DRS indicated that an interaction occurs between the interface of PTh and metal oxide in SPNH, and doped metal oxide nanoparticles were incorporated into PTh to form a core-shell structure. XPS analysis confirmed the presence of Sn4+ and respective elements of PTh and TiO2 in SPNH. SPNH displayed higher adsorption capacities for pollutants than Sn-doped TiO2 nanoparticles (STN). In addition, SPNH exhibited higher photocatalytic activity and stability than STN towards the degradation of organic pollutants nitrobenzene (NB) and malachite green (MG) under visible-light irradiation. Because of the presence of PTh on STN, there was an increase in the adsorption of NB (24%) and MG (21%) on the surface of SPNH, which led to a higher photocatalytic yield. The recyclability of the photocatalytic activity for the photocatalyst was examined by about five runs and not found any depletion or degradation of PTh under visible light irradiation. The high photocatalytic activity of SPNH makes it an attractive candidate as a photocatalyst for industrial water purification.
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    1. [1]

      [1] Linsebigler A L, Lu G Q, Yates J T. Chem Rev, 1995, 95: 735

    2. [2]

      [2] Lifshitz E, Porteanu H, Glozman A, Weller H, Pflughoefft M, Echymu1ller A. J Phys Chem B, 1999, 103: 6870

    3. [3]

      [3] Zou B S, Volkov V V, Wang Z L. Chem Mater, 1999, 11: 3037

    4. [4]

      [4] O'Regan B, Gratzel M. Nature, 1991, 353: 737

    5. [5]

      [5] Yang H M, Zhang K, Shi R R, Li X W, Dong X D, Yu Y M. J Alloys Compd, 2006, 413: 302

    6. [6]

      [6] Li Y X, Wlodarski W, Galatsis K, Moslih S H, Cole J, Russo S, Rockelmann N. Sens Actuat B, 2002, 83: 160

    7. [7]

      [7] Thompson T L, Yates J T. Chem Rev, 2006, 106: 4428

    8. [8]

      [8] Liang H C, Li X Z. Appl Catal B, 2009, 86: 8

    9. [9]

      [9] Kubacka A, Bachiller-Baeza B, Colon G, Fernandez-Garcia M. Appl Catal B, 2010, 93: 274

    10. [10]

      [10] Hou Y, Li X Y, Zhao Q D, Quan X, Chen G H. Appl Phys Lett, 2009, 95: 093108

    11. [11]

      [11] Sui R H, Young J L, Berlinguette C P. J Mater Chem, 2010, 20: 498

    12. [12]

      [12] Lu S L, Zeng L, Wu T, Ren B F, Niu J F, Liu H Y, Zhao X L, Mao J W. Solar Energy, 2011, 85: 1967

    13. [13]

      [13] Zhu Y F, Xu S B, Jiang L, Pan K L, Dan Y. React Funct Polym, 2008, 68: 1492

    14. [14]

      [14] Song Y Q, Zhang J L, Yang H G, Xu S B, Jiang L, Dan Y. Appl Surf Sci, 2014, 292: 978

    15. [15]

      [15] Xu S B, Jiang L, Yang H G, Song Y Q, Dan Y. Chin J Catal (徐守斌, 江龙, 杨海刚, 宋远卿, 淡宜. 催化学报), 2011, 32: 536

    16. [16]

      [16] Qiao Y, Bao S J, Li C M, Cui X Q, Lu Z S, Guo J. ACS Nano, 2008, 2: 113

    17. [17]

      [17] Wang Y, Jia W Z, Strout T, Ding Y, Lei Y. Sensors, 2009, 9: 6752

    18. [18]

      [18] De Boer B, Facchetti A. Polym Rev, 2008, 48: 423

    19. [19]

      [19] Berlin A, Vercelli B, Zotti G. Polym Rev, 2008, 48: 493

    20. [20]

      [20] Liang H, Li X, Appl Catal B, 2009, 86: 8

    21. [21]

      [21] Wang F, Min S X. Chin Chem Lett, 2007, 18: 1273

    22. [22]

      [22] Wang D S, Wang Y H, Li X Y, Luo Q Z, An J, Yue J X. Catal Commun, 2008, 9: 1162

    23. [23]

      [23] Wen C, Hasegawa K, Kanbara T, Kagaya S, Yamamoto T. J Photochem Photobiol A, 2000, 133: 59

    24. [24]

      [24] Oksuz A U, Mandache S, Oksuz L, Hershkowitz N. Ind Eng Chem Res, 2013, 52: 6610

    25. [25]

      [25] Motaung D E, Malgas G F, Arendse C J, Mavundla S E, Oliphant C J, Knoesen D. Solar Energy Mater Solar Cells, 2009, 93: 1674

    26. [26]

      [26] Chatterjee A, Ebina T, Iwasaki T, Mizukami F. J Chem Phys, 2003, 118: 10212

    27. [27]

      [27] Srivastava S, Sinha R, Roy D. Aquatic Toxicol, 2004, 66: 319

    28. [28]

      [28] Ravi Chandra M, Siva Rao T, Pammi S V N, Sreedhar B. Mater Sci Semicond Process, 2015, 30: 672

    29. [29]

      [29] Wu J C S, Chen C H. J Photochem Photobiol A, 2004, 163: 509

    30. [30]

      [30] Czili H, Horvath A. Appl Catal B, 2008, 81: 295

    31. [31]

      [31] Oksuz A U, Manolache S, Oksuz L, Hershkowitz N. Ind Eng Chem Res, 2013, 52: 6610

    32. [32]

      [32] Gao X D, Chorover J. J Colloid Interf Sci, 2010, 348: 167

    33. [33]

      [33] Li X Z, Li F B, Yang C L, Ge W K. J Photochem Photobiol A, 2001, 141: 209

    34. [34]

      [34] Duan Y D, Fu N Q, Liu Q P, Fang Y Y, Zhou X W, Zhang J B, Lin Y. J Phys Chem C, 2012, 116: 8888

    35. [35]

      [35] Liang H C, Li X Z. Appl Catal B, 2009, 86: 8

    36. [36]

      [36] Zhang S J, Jiang H, Li M J, Yu H Q, Yin H, Li Q R. Environ Sci Technol, 2007, 41: 1977

    37. [37]

      [37] Ju Y M, Yang S G, Ding Y C, Sun C, Zhang A Q, Wang L H. J Phys Chem A, 2008, 112: 11172

    38. [38]

      [38] Liu G, Chen Z G, Dong C L, Zhao Y N, Li F, Lu G Q, Cheng H M. J Phys Chem B, 2006, 110: 20823

    39. [39]

      [39] Salzner U, Lagowski J B, Pickup P G, Poirier R A. Synth Metal, 1998, 96: 177

    40. [40]

      [40] Gao X D, Chorover J. J Colloid Interf Sci, 2010, 348: 167

    41. [41]

      [41] Li W, Bai Y, Liu C, Yang Z H, Feng X, Lu X H, van der Laak N K, Chan K Y. Environ Sci Technol, 2009, 43: 5423

    42. [42]

      [42] Yu C L, Zhou W Q, Yu J C, Liu H, Wei L F. Chin J Catal (余长林, 周晚琴, 余济美, 刘鸿, 魏龙福. 催化学报), 2014, 35: 1609

    43. [43]

      [43] Peng Z, Yu J, Mietek J. Adv Mater, 2014, 26: 4920

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