Citation: Honggen Peng, Yue Peng, Xianglan Xu, Xiuzhong Fang, Yue Liu, Jianxin Cai, Xiang Wang. SnO₂ nano-sheet as an efficient catalyst for CO oxidation[J]. Chinese Journal of Catalysis, ;2015, 36(11): 2004-2010. doi: 10.1016/S1872-2067(15)60926-3 shu

SnO₂ nano-sheet as an efficient catalyst for CO oxidation

1.
Institute of Applied Chemistry, College of Chemistry, Nanchang University, Nanchang 330031, Jiangxi, China

Corresponding author: Xiang Wang,
Received Date: 19 April 2015
Available Online: 1 June 2015
Fund Project: 国家自然科学基金(21263015) (21263015) 江西省科技落地计划(KJLD14005) (KJLD14005) 江西省自然科学基金(20151BBE50006, 20122BAB203009). (20151BBE50006, 20122BAB203009)

Polycrystalline SnO₂ fine powder consisting of nano-particles (SnO₂-NP), SnO₂ nano-sheets (SnO₂-NS), and SnO₂ containing both nano-rods and nano-particles (SnO₂-NR+NP) were prepared and used for CO oxidation. SnO₂-NS possesses a mesoporous structure and has a higher surface area, larger pore volume, and more active species than SnO₂-NP, and shows improved activity. In contrast, although SnO₂-NR+NP has only a slightly higher surface area and pore volume, and slightly more active surface oxygen species than SnO₂-NP, it has more exposed active (110) facets, which is the reason for its improved oxidation activity. Water vapor has only a reversible and weak influence on SnO₂-NS, therefore it is a potential catalyst for emission control processes.
- SnO₂ catalyst,
- Nano-sheet,
- Nano-rod,
- Exposed active facet,
- CO oxidation
1. [1]
  [1] Sasikala R, Gupta N M, Kulshreshtha S K. Catal Lett, 2001, 71: 69
2. [2]
  [2] Batzill M, Diebold U. Progr Surf Sci, 2005, 79: 47
3. [3]
  [3] Wang X, Xie Y C. Appl Catal B, 2001, 35: 85
4. [4]
  [4] Yang G, Zhao H B, Zhao B Y. J Mater Sci, 2000, 35: 917
5. [5]
  [5] Shao S F, Qiu X M, He D F, Koehn R, Guan N J, Lu X H, Bao N Z, Grimes C A. Nanoscale, 2011, 3: 4283
6. [6]
  [6] Palacios-Padros A, Altomare M, Tighineanu A, Kirchgeorg R, Shrestha N K, Diez-Perez I, Caballero-Briones F, Sanz F, Schmuki P. J Mater Chem A, 2014, 2: 915
7. [7]
  [7] Wang H K, Rogach A L. Chem Mater, 2014, 26: 123
8. [8]
  [8] Han X, Xu X L, Liu W M, Wang X, Zhang R B. Solid State Sci, 2013, 20: 103
9. [9]
  [9] Xu X L, Zhang R B, Zeng X R, Han X, Li Y C, Liu Y, Wang X. ChemCatChem, 2013, 5: 2025
10. [10]
  [10] Wang X, Xiao L H, Peng H G, Liu W M, Xu X L. J Mater Chem A, 2014, 2: 5616
11. [11]
  [11] Yu J, Zhao D, Xu X L, Wang X, Zhang N. ChemCatChem, 2012, 4: 1122
12. [12]
  [12] Wang X, Tian J S, Zheng Y H, Xu X L, Liu W M, Fang X Z. ChemCatChem, 2014, 6: 1604
13. [13]
  [13] Lan F, Wang X, Xu X L, Zhang R B, Zhang N. React Kinet Mech Catal, 2012, 106: 113
14. [14]
  [14] Ma Y H, Wang X, You X J, Liu J J, Tian J S, Xu X L, Peng H G, Liu W M, Li C Q, Zhou W F, Yuan P, Chen X H. ChemCatChem, 2014, 6: 3366
15. [15]
  [15] Tian J S, Peng H G, Xu X L, Liu W M, Ma Y H, Wang X, Yang X J. Catal Sci Technol, 2015, 5: 2270
16. [16]
  [16] Li Y R, Peng H G, Xu X L, Peng Y, Wang X. RSC Adv, 2015, 5: 25755
17. [17]
  [17] Wang X, Xie Y C. Z Phys Chem, 2002, 216: 919
18. [18]
  [18] Wang X, Xie Y C. Catal Lett, 2001, 75: 73
19. [19]
  [19] Croft G, Fuller M J. Nature, 1977, 269: 585
20. [20]
  [20] Takeguchi T, Takeoh O, Aoyama S, Ueda J, Kikuchi R, Eguchi K. Appl Catal A, 2003, 252: 205
21. [21]
  [21] Lu Z S, Ma D W, Yang L, Wang X B, Xu G L, Yang Z X. Phys Chem Chem Phys, 2014, 16: 12488
22. [22]
  [22] Guo J, Zhang J, Ju D X, Xu H Y, Cao B Q. Powder Technol, 2013, 250: 40
23. [23]
  [23] Zhang L X, Yin Y Y. Sens Actuator B, 2013, 185: 594
24. [24]
  [24] Vuong D D, Trung K Q, Hung N H, Hieu N V, Chien N D. J Alloy Compd, 2014, 599: 195
25. [25]
  [25] Kung M C, Kung H H. Top Catal, 2000, 10: 21
26. [26]
  [26] Ramgir N S, Mulla I S, Vijayamohanan K P. J Phys Chem B, 2005, 109: 12297
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

SnO₂ nano-sheet as an efficient catalyst for CO oxidation