Citation: Ehsan Amini, Mehran Rezaei. Preparation of mesoporous Fe-Cu mixed metal oxide nanopowder as active and stable catalyst for low-temperature CO oxidation[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1711-1718. doi: 10.1016/S1872-2067(15)60922-6 shu

Preparation of mesoporous Fe-Cu mixed metal oxide nanopowder as active and stable catalyst for low-temperature CO oxidation

Ehsan Amini ,
Mehran Rezaei ^,

1.
Institute of Nanoscience and Nanotechnology, Catalyst and Advanced Materials Research Laboratory, Chemical Engineering Department, Faculty ofEngineering, University of Kashan, Kashan, Iran

Corresponding author: Mehran Rezaei,
Received Date: 13 April 2015
Available Online: 25 May 2015

A series of mesoporous Fe-Cu mixed metal oxide nanopowders with different Cu/Fe molar ratios and high specific surface areas were synthesized via a simple, inexpensive, surfactant-free sol-gel route using propylene oxide as the gelation agent. The catalytic behavior of the nanopowders in low-temperature CO oxidation was investigated using a microreactor-gas chromatography system. The prepared materials were characterized by X-ray diffraction, N₂ adsorption-desorption, thermogravimetric-differential thermal analysis, temperature-programmed reduction, Fourier transform infrared spectroscopy, and transmission electron microscopy. These mesoporous Fe-Cu mixed metal oxide catalysts had nanocrystalline structures, narrow pore size distributions, and high surface areas; they showed high catalytic activities and stabilities in low-temperature CO oxidation. The addition of CuO to iron oxide affected the structure and catalytic performance of the iron oxide. The catalyst containing 15 mol% CuO had the highest specific surface area and catalytic activity, and showed high catalytic stability in low-temperature CO oxidation.
- Iron oxide,
- Copper oxide,
- Metal oxide catalyst,
- Mesoporous nanopowder,
- CO oxidation,
- Sol-gel method
1. [1]
  [1] Gardner S D, Hoflund G B, Schryer D R, Schryer J, Upchurch B T, Kielin E J. Langmuir, 1991, 7: 2135
2. [2]
  [2] Haruta M, Tsubota S, Kobayashi T, Kageyama H, Genet M J, Delmon B. J Catal, 1993, 144: 175
3. [3]
  [3] Wang S R, Huang J, Zhao Y Q, Wang S P, Wang X Y, Zhang T Y, Wu S H, Zhang S M, Huang W P. J Mol Catal A, 2006, 259: 245
4. [4]
  [4] Schryer D R, Upchurch B T, Sidney B D, Brown K G, Hoflund G B, Herz R K. J Catal, 1991, 130: 314
5. [5]
  [5] Schryer D R, Upchurch B T, Van Norman J D, Brown K G, Schryer J. J Catal, 1990, 122: 193
6. [6]
  [6] Han Y F, Kahlich M J, Kinne M, Behm R J. Appl Catal B, 2004, 50: 209
7. [7]
  [7] Zhu H Q, Qin Z F, Shan W J, Shen W J, Wang J G. J Catal, 2004, 225: 267
8. [8]
  [8] Cao J L, Wang Y, Yu X L, Wang S R, Wu S H, Yuan Z Y. Appl Catal B, 2008, 79: 26
9. [9]
  [9] Cheng T, Fang Z Y, Hu Q X, Han K D, Yang X Z, Zhang Y J. Catal Commun, 2007, 8: 1167
10. [10]
  [10] Cao J L, Shao G S, Wang Y, Liu Y P, Yuan Z Y. Catal Commun, 2008, 9: 2555
11. [11]
  [11] Biabani-Ravandi A, Rezaei M. Chem Eng J, 2012, 184: 141
12. [12]
  [12] Guo Q, Liu Y. Appl Catal B, 2008, 82: 19
13. [13]
  [13] Sadeghinia M, Rezaei M, Amini E. Korean J Chem Eng, 2013, 30: 2012
14. [14]
  [14] Li J, Zhu P F, Zuo S F, Huang Q Q, Zhou R X. Appl Catal A, 2010, 381: 261
15. [15]
  [15] Li G N, Li L, Shi J J, Yuan Y Y, Li Y S, Zhao W R, Shi J L. J Mol Catal A, 2014, 390: 97
16. [16]
  [16] Li G N, Li L, Li Y S, Shi J L. New J Chem, 2015, 39: 1742
17. [17]
  [17] Kuhn J N, Tsung C K, Huang W Y, Somorjai G A. J Catal, 2009, 265: 209
18. [18]
  [18] Borodko Y, Jones L, Lee H, Frei H, Somorjai G. Langmuir, 2009, 25: 6665
19. [19]
  [19] Amini E, Rezaei M, Sadeghinia M. Chin J Catal (催化学报), 2013, 34: 1762
20. [20]
  [20] Yentekakis I V, Lambert R M, Konsolakis M, Kallithrakas-Kontos N. Catal Lett, 2002, 81: 181
21. [21]
  [21] Yang Q J, Choi H, Al-Abed S R, Sionysios D D. Appl Catal B, 2009, 88: 462
22. [22]
  [22] Fierro G, Lojacono M, Inversi M, Porta P, Lavecchia R, Cioci F. J Catal, 1994, 48: 709
1. [1]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
2. [2]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
3. [3]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
4. [4]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
5. [5]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
6. [6]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
7. [7]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
8. [8]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
9. [9]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
10. [10]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
11. [11]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
12. [12]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
13. [13]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
14. [14]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
15. [15]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
16. [16]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
17. [17]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
18. [18]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
19. [19]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
20. [20]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(433)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142