Citation: Jingmi Wu, Liang Zeng, Dangguo Cheng, Fengqiu Chen, Xiaoli Zhan, Jinlong Gong. Synthesis of Pd nanoparticles supported on CeO₂ nanotubes for CO oxidation at low temperatures[J]. Chinese Journal of Catalysis, ;2016, 37(1): 83-90. doi: 10.1016/S1872-2067(15)60913-5 shu

Synthesis of Pd nanoparticles supported on CeO₂ nanotubes for CO oxidation at low temperatures

1.
a Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China;
2.
b Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University; Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Corresponding author: Dangguo Cheng, Jinlong Gong,
Received Date: 30 April 2015
Available Online: 27 May 2015
Fund Project: 国家自然科学基金(21376209, 21376169) (21376209, 21376169) 浙江省自然科学重点基金(LZ13B060004) (LZ13B060004) 浙江省重点科技创新团队计划(2013TD07) (2013TD07) 高等学校学科创新引智计划(B06006). (B06006)

Developing efficient supported Pd catalysts and understanding their catalytic mechanism in CO oxidation are challenging research topics in recent years. This paper describes the synthesis of Pd nanoparticles supported on CeO₂ nanotubes via an alcohol reduction method. The effect of the support morphology on the catalytic reaction was explored. Subsequently, the performance of the prepared catalysts was investigated toward CO oxidation reaction and characterized by Nitrogen sorption, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and CO-temperature-programmed desorption techniques. The results indicated that the catalyst of Pd on CeO₂ nanotubes exhibits excellent activity in CO oxidation at low temperatures, due to its large surface area, the high dispersion of Pd species, the mesoporous and tubular structure of the CeO₂-nanotube support, the abundant Ce³⁺, formation of Pd-O-Ce bonding, and enhanced metal-support interaction on the catalyst surface.
- Cerium oxide nanotube,
- Palladium nanoparticle,
- Metal-support interaction,
- Carbon monoxide oxidation,
- Low temperature
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Pd nanoparticles supported on CeO2 nanotubes for CO oxidation at low temperatures

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Pd nanoparticles supported on CeO₂ nanotubes for CO oxidation at low temperatures