Citation: Huijuan Wei, Sujuan Xie, Kefeng Liu, Wenjie Xin, Xiujie Li, Shanhe Liu, Shunming Gu, Shenglin Liu, Longya Xu. CTAB modification of MCM-49 zeolite containing HMI and its acylation of anisole[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1766-1776. doi: 10.1016/S1872-2067(15)60887-7 shu

CTAB modification of MCM-49 zeolite containing HMI and its acylation of anisole

Huijuan Wei ^a,b ,
Sujuan Xie ^a ,
Kefeng Liu ^a,c ,
Wenjie Xin ^a ,
Xiujie Li ^a ,
Shanhe Liu ^d ,
Shunming Gu ^d ,
Shenglin Liu ^a ,
Longya Xu ^a,,

1.
a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Longya Xu,
Received Date: 5 April 2015
Available Online: 5 May 2015

A series of MCM-49 zeolite catalysts containing different amounts of the hexamethyleneimine (HMI) template were calcined at different temperatures, and then modified with cetyltrimethylammonium bromide (CTAB). Changes in structural and acidic properties were investigated by XRD, N₂ adsorption, NH₃-TPD, adsorbed pyridine infrared and DRIFTS measurements, and ²⁹Si and ²⁷Al MAS NMR. There were cleaning off of amorphous particles and extraframework Al atoms inserted into the framework of the zeolite due to the CTAB modification. These two effects resulted in more framework Al in the CTAB modified samples than the untreated samples, and a higher Brönsted acid concentration, which was confirmed by the acylation of anisole with acetic anhydride. The catalytic roles of the acid sites located in the different pore systems in the zeolite were investigated. It was verified that the active sites after CTAB modification were mainly in the HMI-free regions.
- MCM-49 zeolite,
- Template,
- Post-treatment,
- CTAB,
- Acylation
1. [1]
  [1] Zhao D S, Wang J L, Zhang J. Catal Lett, 2008, 126: 188
2. [2]
  [2] Wine G, Pham-Huu C, Ledoux M J. Catal Commun, 2006, 7: 768
3. [3]
  [3] Bai G Y, Dou H Y, Qiu M D, He F, Fan X X, Ma Z. Res Chem Intermediat, 2010, 36: 483
4. [4]
  [4] Bejblova M, Prochazkova D, Cejka J. ChemSusChem, 2009, 2: 486
5. [5]
  [5] Serrano D P, Garcia R A, Vicente G, Linares M, Prochazkova D, Cejka J. J Catal, 2011, 279: 366
6. [6]
  [6] Guidotti M, Coustard J M, Magnoux P, Guisnet M. Pure Appl Chem, 2007, 79: 1833
7. [7]
  [7] Bai G Y, Dou H Y, Qiu M D, Fan X X, He F, Niu L B, Ma Z. Catal Lett, 2010, 138: 187
8. [8]
  [8] Sartori G, Maggi R. Chem Rev, 2006, 106: 1077
9. [9]
  [9] Yoo W C, Zhang X Y, Tsapatsis M, Stein A. Microporous Mesoporous Mater, 2012, 149: 147
10. [10]
  [10] Verboekend D, Pérez-Ramírez J. Catal Sci Technol, 2011, 1: 879
11. [11]
  [11] Ivanova I I, Kasyanov I A, Maerle A A, Zaikovskii V I. Microporous Mesoporous Mater, 2014, 189: 163
12. [12]
  [12] Ivanova I I, Knyazeva E E. Chem Soc Rev, 2013, 42: 3671
13. [13]
  [13] Schmidt F, Lohe M R, Büchner B, Giordanino F, Bonino F, Kaskel S. Microporous Mesoporous Mater, 2013, 165: 148
14. [14]
  [14] Ordomsky V V, Ivanova I I, Knyazeva E E, Yuschenko V V, Zaikovskii V I. J Catal, 2012, 295: 207
15. [15]
  [15] Wei H J, Xie S J, Gao N N, Liu K F, Liu X H, Xin W J, Li X J, Liu S L, Xu L Y. Appl Catal A, 2015, 495: 152
16. [16]
  [16] Liu K F, Xie S J, Wei H J, Li X J, Liu S L, Xu L Y. Appl Catal A, 2013, 468: 288
17. [17]
  [17] Liu K F, Xie S J, Xu G L, Li Y N, Liu S L, Xu L Y. Appl Catal A, 2010, 383: 102
18. [18]
  [18] Gao N N, Xie S J, Liu S L, An J, Zhu X X, Hu L Y, Wei H J, Li X J, Xu L Y. Catal Lett, 2014, 144: 1296
19. [19]
  [19] Corma A, Fornes V, Martinez-Triguero J, Pergher S B. J Catal, 1999, 186: 57
20. [20]
  [20] Corma A, Fornes V, Pergher S B, Maesen T L M, Buglass J G. Nature, 1998, 396: 353
21. [21]
  [21] Maheshwari S, Martinez C, Portilla M T, Llopis F J, Corma A, Tsapatsis M. J Catal, 2010, 272: 298
22. [22]
  [22] Chlubna P, Roth W J, Zukal A, Kubu M, Pavlatova J. Catal Today, 2012, 179: 35
23. [23]
  [23] Maheshwari S, Jordan E, Kumar S, Bates F S, Penn R L, Shantz D F, Tsapatsis M. J Am Chem Soc, 2008, 130: 1507
24. [24]
  [24] Roth W J, Cejka J. Catal Sci Technol, 2011, 1: 43
25. [25]
  [25] Liu K F, Liu S L, Xie S J, Wei H J, Song C, Li X J, Xu L Y. Catal Lett, 2014, 144: 1223
26. [26]
  [26] Liu K F, Xie S J, Liu S L, Xu G L, Gao N N, Xu L Y. J Catal, 2011, 283: 68
27. [27]
  [27] Laforge S, Martin D, Guisnet M. Microporous Mesoporous Mater, 2004, 67: 235
28. [28]
  [28] Matias P, Lopes J M, Laforge S, Magnoux P, Guisnet M, Ramôa Ribeiro F. Appl Catal A, 2008, 351: 174
29. [29]
  [29] Bennett J M, Chang C D, Lawton S L, Leonowicz M E, Lissy D N, Rubin M K. US Patent 5 236 575. 1993
30. [30]
  [30] van Miltenburg A, Pawlesa J, Bouzga A M, Zilkova N, Cejka J, Stöcker M. Top Catal, 2009, 52: 1190
31. [31]
  [31] Garcia-Martinez J, Johnson M, Valla J, Li K H, Ying J Y. Catal Sci Technol, 2012, 2: 987
32. [32]
  [32] Khitev Y P, Kolyagin Y G, Ivanova I I, Ponomareva O A, Thibault-Starzyk F, Gilson J P, Fernandez C, Fajula F. Microporous Mesoporous Mater, 2011, 146: 201
33. [33]
  [33] Inagaki S, Ogura M, Inami T, Sasaki Y, Kikuchi E, Matsukata M. Microporous Mesoporous Mater, 2004, 74: 163
34. [34]
  [34] Chal R, Cacciaguerra T, van Donk S, Gerardin C. Chem Commun, 2010, 46: 7840
35. [35]
  [35] Delitala C, Alba M D, Becerro A I, Delpiano D, Meloni D, Musu E, Ferino I. Microporous Mesoporous Mater, 2009, 118: 1
36. [36]
  [36] Kennedy G J, Lawton S L, Fung A S, Rubin M K, Steuernagel S. Catal Today, 1999, 49: 385
37. [37]
  [37] Ma D, Deng F, Fu R Q, Han X W, Bao X H. J Phys Chem B, 2001, 105: 1770
38. [38]
  [38] Fyfe C A, Feng Y, Grondey H, Kokotailo G T, Gies H. Chem Rev, 1991, 91: 1525
39. [39]
  [39] Lawton S L, Fung A S, Kennedy G J, Alemany L B, Chang C D, Hatzikos G H, Lissy D N, Rubin M K, Timken H K C, Steuernagel S, Woessner D E. J Phys Chem, 1996, 100: 3788
40. [40]
  [40] He Y P, Liu M, Dai C Y, Xu S T, Wei Y X, Liu Z M, Guo X W. Chin J Catal (何英萍, 刘民, 代成义, 徐舒涛, 魏迎旭, 刘中民, 郭新闻. 催化学报), 2013, 34: 1148
41. [41]
  [41] Pérez-Ramírez J, Abelló S, Bonilla A, Groen J C. Adv Funct Mater, 2009, 19: 164
42. [42]
  [42] Lenarda M, Da Ros M, Casagrande M, Storaro L, Ganzerla R. Inorg Chim Acta, 2003, 349: 195
43. [43]
  [43] Nur H, Ramli Z, Efendi J, Rahman A N A, Chandren S, Yuan L S. Catal Commun, 2011, 12: 822
44. [44]
  [44] Emeis C A. J Catal, 1993, 141: 347
45. [45]
  [45] Awayssa O, Al-Yassir N, Aitani A, Al-Khattaf S. Appl Catal A, 2014, 477: 172
46. [46]
  [46] Gora-Marek K, Derewinski M, Sarv P, Datka J. Catal Today, 2005, 101: 131
47. [47]
  [47] Gora-Marek K, Tarach K, Tekla J, Olejniczak Z, Kustrowski P, Liu L C, Martinez-Triguero J, Rey F. J Phys Chem C, 2014, 118: 28043
48. [48]
  [48] Wei H J, Liu K F, Xie S J, Xin W J, Li X J, Liu S L, Xu L Y. J Catal, 2013, 307: 103
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