Citation: Huijuan Wei, Sujuan Xie, Kefeng Liu, Wenjie Xin, Xiujie Li, Shanhe Liu, Shunming Gu, Shenglin Liu, Longya Xu. CTAB modification of MCM-49 zeolite containing HMI and its acylation of anisole[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1766-1776. doi: 10.1016/S1872-2067(15)60887-7 shu

CTAB modification of MCM-49 zeolite containing HMI and its acylation of anisole

Huijuan Wei ^a,b ,
Sujuan Xie ^a ,
Kefeng Liu ^a,c ,
Wenjie Xin ^a ,
Xiujie Li ^a ,
Shanhe Liu ^d ,
Shunming Gu ^d ,
Shenglin Liu ^a ,
Longya Xu ^a,,

1.
a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Longya Xu,
Received Date: 5 April 2015
Available Online: 5 May 2015

A series of MCM-49 zeolite catalysts containing different amounts of the hexamethyleneimine (HMI) template were calcined at different temperatures, and then modified with cetyltrimethylammonium bromide (CTAB). Changes in structural and acidic properties were investigated by XRD, N₂ adsorption, NH₃-TPD, adsorbed pyridine infrared and DRIFTS measurements, and ²⁹Si and ²⁷Al MAS NMR. There were cleaning off of amorphous particles and extraframework Al atoms inserted into the framework of the zeolite due to the CTAB modification. These two effects resulted in more framework Al in the CTAB modified samples than the untreated samples, and a higher Brönsted acid concentration, which was confirmed by the acylation of anisole with acetic anhydride. The catalytic roles of the acid sites located in the different pore systems in the zeolite were investigated. It was verified that the active sites after CTAB modification were mainly in the HMI-free regions.
- MCM-49 zeolite,
- Template,
- Post-treatment,
- CTAB,
- Acylation
1. [1]
  [1] Zhao D S, Wang J L, Zhang J. Catal Lett, 2008, 126: 188
2. [2]
  [2] Wine G, Pham-Huu C, Ledoux M J. Catal Commun, 2006, 7: 768
3. [3]
  [3] Bai G Y, Dou H Y, Qiu M D, He F, Fan X X, Ma Z. Res Chem Intermediat, 2010, 36: 483
4. [4]
  [4] Bejblova M, Prochazkova D, Cejka J. ChemSusChem, 2009, 2: 486
5. [5]
  [5] Serrano D P, Garcia R A, Vicente G, Linares M, Prochazkova D, Cejka J. J Catal, 2011, 279: 366
6. [6]
  [6] Guidotti M, Coustard J M, Magnoux P, Guisnet M. Pure Appl Chem, 2007, 79: 1833
7. [7]
  [7] Bai G Y, Dou H Y, Qiu M D, Fan X X, He F, Niu L B, Ma Z. Catal Lett, 2010, 138: 187
8. [8]
  [8] Sartori G, Maggi R. Chem Rev, 2006, 106: 1077
9. [9]
  [9] Yoo W C, Zhang X Y, Tsapatsis M, Stein A. Microporous Mesoporous Mater, 2012, 149: 147
10. [10]
  [10] Verboekend D, Pérez-Ramírez J. Catal Sci Technol, 2011, 1: 879
11. [11]
  [11] Ivanova I I, Kasyanov I A, Maerle A A, Zaikovskii V I. Microporous Mesoporous Mater, 2014, 189: 163
12. [12]
  [12] Ivanova I I, Knyazeva E E. Chem Soc Rev, 2013, 42: 3671
13. [13]
  [13] Schmidt F, Lohe M R, Büchner B, Giordanino F, Bonino F, Kaskel S. Microporous Mesoporous Mater, 2013, 165: 148
14. [14]
  [14] Ordomsky V V, Ivanova I I, Knyazeva E E, Yuschenko V V, Zaikovskii V I. J Catal, 2012, 295: 207
15. [15]
  [15] Wei H J, Xie S J, Gao N N, Liu K F, Liu X H, Xin W J, Li X J, Liu S L, Xu L Y. Appl Catal A, 2015, 495: 152
16. [16]
  [16] Liu K F, Xie S J, Wei H J, Li X J, Liu S L, Xu L Y. Appl Catal A, 2013, 468: 288
17. [17]
  [17] Liu K F, Xie S J, Xu G L, Li Y N, Liu S L, Xu L Y. Appl Catal A, 2010, 383: 102
18. [18]
  [18] Gao N N, Xie S J, Liu S L, An J, Zhu X X, Hu L Y, Wei H J, Li X J, Xu L Y. Catal Lett, 2014, 144: 1296
19. [19]
  [19] Corma A, Fornes V, Martinez-Triguero J, Pergher S B. J Catal, 1999, 186: 57
20. [20]
  [20] Corma A, Fornes V, Pergher S B, Maesen T L M, Buglass J G. Nature, 1998, 396: 353
21. [21]
  [21] Maheshwari S, Martinez C, Portilla M T, Llopis F J, Corma A, Tsapatsis M. J Catal, 2010, 272: 298
22. [22]
  [22] Chlubna P, Roth W J, Zukal A, Kubu M, Pavlatova J. Catal Today, 2012, 179: 35
23. [23]
  [23] Maheshwari S, Jordan E, Kumar S, Bates F S, Penn R L, Shantz D F, Tsapatsis M. J Am Chem Soc, 2008, 130: 1507
24. [24]
  [24] Roth W J, Cejka J. Catal Sci Technol, 2011, 1: 43
25. [25]
  [25] Liu K F, Liu S L, Xie S J, Wei H J, Song C, Li X J, Xu L Y. Catal Lett, 2014, 144: 1223
26. [26]
  [26] Liu K F, Xie S J, Liu S L, Xu G L, Gao N N, Xu L Y. J Catal, 2011, 283: 68
27. [27]
  [27] Laforge S, Martin D, Guisnet M. Microporous Mesoporous Mater, 2004, 67: 235
28. [28]
  [28] Matias P, Lopes J M, Laforge S, Magnoux P, Guisnet M, Ramôa Ribeiro F. Appl Catal A, 2008, 351: 174
29. [29]
  [29] Bennett J M, Chang C D, Lawton S L, Leonowicz M E, Lissy D N, Rubin M K. US Patent 5 236 575. 1993
30. [30]
  [30] van Miltenburg A, Pawlesa J, Bouzga A M, Zilkova N, Cejka J, Stöcker M. Top Catal, 2009, 52: 1190
31. [31]
  [31] Garcia-Martinez J, Johnson M, Valla J, Li K H, Ying J Y. Catal Sci Technol, 2012, 2: 987
32. [32]
  [32] Khitev Y P, Kolyagin Y G, Ivanova I I, Ponomareva O A, Thibault-Starzyk F, Gilson J P, Fernandez C, Fajula F. Microporous Mesoporous Mater, 2011, 146: 201
33. [33]
  [33] Inagaki S, Ogura M, Inami T, Sasaki Y, Kikuchi E, Matsukata M. Microporous Mesoporous Mater, 2004, 74: 163
34. [34]
  [34] Chal R, Cacciaguerra T, van Donk S, Gerardin C. Chem Commun, 2010, 46: 7840
35. [35]
  [35] Delitala C, Alba M D, Becerro A I, Delpiano D, Meloni D, Musu E, Ferino I. Microporous Mesoporous Mater, 2009, 118: 1
36. [36]
  [36] Kennedy G J, Lawton S L, Fung A S, Rubin M K, Steuernagel S. Catal Today, 1999, 49: 385
37. [37]
  [37] Ma D, Deng F, Fu R Q, Han X W, Bao X H. J Phys Chem B, 2001, 105: 1770
38. [38]
  [38] Fyfe C A, Feng Y, Grondey H, Kokotailo G T, Gies H. Chem Rev, 1991, 91: 1525
39. [39]
  [39] Lawton S L, Fung A S, Kennedy G J, Alemany L B, Chang C D, Hatzikos G H, Lissy D N, Rubin M K, Timken H K C, Steuernagel S, Woessner D E. J Phys Chem, 1996, 100: 3788
40. [40]
  [40] He Y P, Liu M, Dai C Y, Xu S T, Wei Y X, Liu Z M, Guo X W. Chin J Catal (何英萍, 刘民, 代成义, 徐舒涛, 魏迎旭, 刘中民, 郭新闻. 催化学报), 2013, 34: 1148
41. [41]
  [41] Pérez-Ramírez J, Abelló S, Bonilla A, Groen J C. Adv Funct Mater, 2009, 19: 164
42. [42]
  [42] Lenarda M, Da Ros M, Casagrande M, Storaro L, Ganzerla R. Inorg Chim Acta, 2003, 349: 195
43. [43]
  [43] Nur H, Ramli Z, Efendi J, Rahman A N A, Chandren S, Yuan L S. Catal Commun, 2011, 12: 822
44. [44]
  [44] Emeis C A. J Catal, 1993, 141: 347
45. [45]
  [45] Awayssa O, Al-Yassir N, Aitani A, Al-Khattaf S. Appl Catal A, 2014, 477: 172
46. [46]
  [46] Gora-Marek K, Derewinski M, Sarv P, Datka J. Catal Today, 2005, 101: 131
47. [47]
  [47] Gora-Marek K, Tarach K, Tekla J, Olejniczak Z, Kustrowski P, Liu L C, Martinez-Triguero J, Rey F. J Phys Chem C, 2014, 118: 28043
48. [48]
  [48] Wei H J, Liu K F, Xie S J, Xin W J, Li X J, Liu S L, Xu L Y. J Catal, 2013, 307: 103
1. [1]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
2. [2]
  Chengxiao Zhao , Zhaolin Li , Dongfang Wu , Xiaofei Yang . SBA-15 templated covalent triazine frameworks for boosted photocatalytic hydrogen production. Acta Physico-Chimica Sinica, 2026, 42(1): 100149-0. doi: 10.1016/j.actphy.2025.100149
3. [3]
  Yi RU , Tao MENG , Zhaoteng XUE , Dongsen MAO . Synergistic catalysis of Al distribution and pore structure in ZSM-5 zeolite for bioethanol-to-propylene. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 247-262. doi: 10.11862/CJIC.20250255
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
6. [6]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
7. [7]
  Xiaoyang Li , Xiaowei Huang , Yimeng Zhang , Huan Liu , Shao Jin , Junpeng Zhuang . Comprehensive Chemical Experiments on the Synthesis of 1,3-Dibromo-5,5-Dimethylhydantoin and Its Application as a Brominating Reagent. University Chemistry, 2025, 40(7): 286-293. doi: 10.12461/PKU.DXHX202408035
8. [8]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
9. [9]
  Xiangxi Kong , Mingyang He , Yineng Ling , Hui Wang , Qixian Xie , Baili Li , Wurong Ren . Digitally Enhanced Measurement of Ignition Delay Time Measurement for Hypergolic Propellants. University Chemistry, 2026, 41(1): 95-106. doi: 10.12461/PKU.DXHX202505005
10. [10]
  Xuefei Zhao , Xuhong Hu , Zhenhua Jia . 理论与计算化学在傅-克烷基化反应教学中的应用. University Chemistry, 2025, 40(8): 360-367. doi: 10.12461/PKU.DXHX202410008
11. [11]
  Junjie TANG , Yunting ZHANG , Zhengjiang LIU , Jiani WU . Preparation of CeO₂ by starch template method for photo-Fenton degradation of methyl orange. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1617-1631. doi: 10.11862/CJIC.20240420
12. [12]
  Jingxuan Zhang , Weihao Jiang , Siyuan Zhang , Hongye Tian , Ziye Huang , Lin Huang , Qikun Wu , Jing Yang , Yibin Jiang , Cheng Wang . Automation and AI-Assisted Investigation of the Chemical Reactivity of Sulfosalicylic Acid. University Chemistry, 2026, 41(1): 332-345. doi: 10.12461/PKU.DXHX202505108
13. [13]
  Chao WU , Qingxiu SHI , Tao XU , Zhengxi PENG , Zhongping XIONG , Yinglin ZHANG , Yujun SI , Chaozhong GUO . Enhancement of oxygen reduction reaction performance of iron-nitrogen doped carbon based catalysts by sodium carboxymethyl cellulose pre-deoxygenation. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 737-746. doi: 10.11862/CJIC.20250305
14. [14]
  Zhican Lu , Junyu Li , Zijun Huang , Ziyi Zeng , Chi Huang , Chuqing Gong , Yalan Zhong . Digital Experimental Design of Decomposition of Ammonium Perchlorate Catalyzed by MOFs. University Chemistry, 2026, 41(1): 133-143. doi: 10.12461/PKU.DXHX202506017
15. [15]
  Caixia Lin , Ting Liu , Zhaojiang Shi , Hong Yan , Keyin Ye , Yaofeng Yuan . Innovative Experiment of Electrochemical Dearomative Spirocyclization of N-Acyl Sulfonamides. University Chemistry, 2025, 40(4): 359-366. doi: 10.12461/PKU.DXHX202406107
16. [16]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
17. [17]
  Zhenhuan Wang , Weifei Wei , Ruijie Ma , Dou Luo , Zhanxiang Chen , Jun Zhang , Liyang Yu , Gang Li , Zhenghui Luo . 苯并[a]苯嗪受体的核心氰基化实现高效(19.04%)绿色溶剂加工的二元有机太阳能电池. Acta Physico-Chimica Sinica, 2026, 42(2): 100182-0. doi: 10.1016/j.actphy.2025.100182
18. [18]
  Jihua Deng , Xinshi Wu , Dichang Zhong . Exploration of Green Teaching and Ideological and Political Education in Chemical Experiment of “Preparation of Ammonium Ferrous Sulfate”. University Chemistry, 2024, 39(10): 325-329. doi: 10.12461/PKU.DXHX202405046
19. [19]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
20. [20]
  Wenwen Ma , Lian Kong , Jinyang Chu , Li Ma , Ziqing Ma , Heyu Cheng , Xinyuan Li , Zhan Yu , Zhen Zhao . Digitalization-Driven Olefin Production: Digital Design of Catalysts for CO₂-Assisted Oxidation Dehydrogenation of Ethane to Ethylene. University Chemistry, 2026, 41(1): 363-372. doi: 10.12461/PKU.DXHX202506055

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(958)
HTML views(88)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142