Citation: Sanjay Srivastava, Pravakar Mohanty, Jigisha K. Parikh, Ajay K. Dalai, S. S. Amritphale, Anup K. Khare. Cr-free Co-Cu/SBA-15 catalysts for hydrogenation of biomass-derived α-, β-unsaturated aldehyde to alcohol[J]. Chinese Journal of Catalysis, ;2015, 36(7): 933-942. doi: 10.1016/S1872-2067(15)60870-1 shu

Cr-free Co-Cu/SBA-15 catalysts for hydrogenation of biomass-derived α-, β-unsaturated aldehyde to alcohol

1.
a Department of Chemical Engineering, S. V. National Institute of Technology, Ichchhanath, SURAT-395 007, Gujarat, India;

Corresponding author: Jigisha K. Parikh,
Received Date: 13 January 2015
Available Online: 21 April 2015

Cr-free bi-metallic SBA-15-supported Co-Cu catalysts were examined in the conversion of biomass-derived α-, β-unsaturated aldehyde (furfural) to value-added chemical furfuryl alcohol (FOL). Co-Cu/SBA-15 catalysts with a fixed Cu loading of 10 wt% and varying Co loadings (2.5, 5, and 10 wt%) were prepared by the impregnation method. The catalysts were characterized by X-ray diffraction, N₂ sorption, H₂ temperature-programmed reduction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, high-resolution transmission electron microscopy, CO chemisorption, and inductively coupled plasma mass spectrometry. The influence of different reaction parameters such as temperature, pressure, catalyst dosage, and furfural concentration on the catalyst performance was evaluated. Relative to catalysts supported on amorphous silica, the current SBA-15-supported Co-Cu catalysts displayed higher performance, attaining a furfural conversion of 99% and furfuryl alcohol selectivity of 80%. The catalytic reactions were conducted in a 100-mL autoclave at 170 ℃ and 2 MPa H₂ pressure for 4 h.
- Mesoporous catalyst,
- Cobalt,
- Copper,
- SBA-15,
- Furfural,
- Furfuryl alcohol,
- Hydrogenation
1. [1]
  [1] Corma A, Iborra S, Velty A. Chem Rev, 2007, 107: 2411
2. [2]
  [2] Nanda S, Mohanty P, Pant K K, Naik S, Kozinski J A, Dalai A K. Bioenergy Res, 2013, 6: 663
3. [3]
  [3] Butler E, Devlin G, Meier D, McDonnell K. Renew Sustain Energy Rev, 2011, 15: 4171
4. [4]
  [4] Chiaramonti D, Oasmaa A, Solantausta Y. Renew Sustain Energy Rev, 2007, 11: 1056
5. [5]
  [5] Yan K, Wu G S, Lafleur T, Jarvis C. Renew Sustain Energy Rev, 2014, 38: 663
6. [6]
  [6] Yang W, Sen A. ChemSusChem, 2011, 4: 349
7. [7]
  [7] Sharma R V, Das U, Sammynaiken R, Dalai A K. Appl Catal A, 2013, 454: 127
8. [8]
  [8] Borts M S, Gilchenok N D, Ignatev V M, Gurevich G S. J Appl Chem USSR, 1986, 59: 114
9. [9]
  [9] Rao R, Dandekar A, Baker R T K, Vannice M A. J Catal, 1997, 171: 406
10. [10]
  [10] Vaidya P D, Mahajani V V. Ind Eng Chem Res, 2003, 42: 3881
11. [11]
  [11] Rojas H, Martines J J, Reyes P. Dyna, 2010, 163: 151
12. [12]
  [12] Sitthisa S, Sooknoi T, Ma Y, Balbuena P B, Resasco D E. J Catal, 2011, 277: 1
13. [13]
  [13] Villaverde M M, Bertero N M, Garetto T F, Marchi A J. Catal Today, 2013, 213: 87
14. [14]
  [14] Yan K, Chen A C. Energy, 2013, 58: 357
15. [15]
  [15] Seo G, Chon H. J Catal, 1981, 67: 424
16. [16]
  [16] Lee J Y, Lee D W, Lee K Y, Wang Y. Catal Today, 2009, 146: 260
17. [17]
  [17] Yan K, Chen A C. Fuel, 2014, 115: 101
18. [18]
  [18] Burnette L W, Johns I B, Holdren R F, Hixon R M. Ind Eng Chem, 1948, 40: 502
19. [19]
  [19] Dong F, Zhu Y L, Zheng H Y, Zhu Y F, Li X Q, Li Y W. J Mol Catal A, 2015, 398: 140
20. [20]
  [20] Liu B J, Lu L H, Wang B C, Cai T X, Katsuyoshi I. Appl Catal A, 1998, 171: 117
21. [21]
  [21] Thomas D D. US Patent 4146460. 1979
22. [22]
  [22] Erzhanova M S, Beisekov T B. SU Patent 450585. 1974
23. [23]
  [23] Beisekov T B, Masaeva S A, Kuatbekov A M, Pilipenko S V, Utebaeva A. Khim Promst, 1992: 507
24. [24]
  [24] Pljusnin L D, Beisekov T, Jerzhanova M S, Daurenbekov B D. Khim Promst, 1988: 672
25. [25]
  [25] Sitthisa S, Pham T, Prasomsri T, Sookni T, Mallinson R G, Resasco D E. J Catal, 2011, 280: 17
26. [26]
  [26] Sitthisa S, An W, Resasco D E. J Catal, 2011, 284: 90
27. [27]
  [27] Merlo A B, Vetere V, Ruggera J F, Casella M L. Catal Commun, 2009, 10: 1665
28. [28]
  [28] Reddy B M, Reddy G K, Rao K N, Khan A, Ganesh I. J Mol Catal A, 2007, 265: 276
29. [29]
  [29] Wu J, Shen Y M, Liu C H, Wang H B, Geng C J, Zhang Z X. Catal Commum, 2005, 6: 633
30. [30]
  [30] Li H, Chai W M, Luo H S, Li H X. Chin J Chem, 2006, 24: 1704
31. [31]
  [31] Chen X F, Li H X, Luo H S, Qiao M H. Appl Catal A, 2002, 233: 13
32. [32]
  [32] Wei S Q, Cui H Y, Wang J H, Zhuo S P, Yi W M, Wang L H, Li Z H. Particuology, 2011, 9: 69
33. [33]
  [33] Zhao D Y, Feng J L, Huo Q S, Melosh N, Fredrickson G H, Chmelka B F, Stucky G D. Science, 1998, 279: 548
34. [34]
  [34] Vargas-Hernandez D, Rubio-Caballero J M, Santamarıa-Gonzalez J, Moreno-Tost R, Merida-Robles J M, Perez-Cruz M A, Jimenez-Lopez A, Hernandez-Huesca A, Maireles-Torres. J Mol Catal A, 2014, 383-384: 106
35. [35]
  [35] Yan K, Lafleur T, Jarvis C, Wu G S. J Clean Prod, 2014, 72: 230
36. [36]
  [36] Ramachandran P A, Chaudhari R V. Three-Phase Catalytic Reactors. New York: Gordon and Breach, 1983. 427
37. [37]
  [37] Klimova T, Reyes J, Gutierrez O, Lizama L. Appl Catal A, 2008, 335: 159
38. [38]
  [38] Soni K, Mouli K C, Dalai A K, Adjaye J. Catal Lett, 2010, 136: 116
39. [39]
  [39] Dhar G M, Kumaran G M, Kumar M, Rawat K S, Sharma L D, Raju B D, Rama Rao K S. Catal Today, 2005, 99: 309
40. [40]
  [40] Carrero A, Calles J A, Vizcaíno A J. Appl Catal A, 2007, 327: 82
41. [41]
  [41] Zhu Y Y, Wang S R, Zhu L J, Ge X L, Li X B, Luo Z Y. Catal Lett, 2010, 135: 275
42. [42]
  [42] Marchi A J, Di Cosimo J I, Apesteguia C R. Catal Today, 1992, 15: 383
43. [43]
  [43] Cesar D V, Perez C A, Salim V M M, Schmal M. Appl Catal A, 1999, 176: 205
44. [44]
  [44] Iglesia E, Soled S L, Baumgartner J E, Reyes S C. J Catal, 1995, 153: 108
45. [45]
  [45] Tien-Thao N, Zahedi-Niaki M H, Alamdari H, Kaliaguine S. J Catal, 2007, 245: 348
46. [46]
  [46] Xu X D, Mausbeck D, Scholten J J F. Catal Today, 1991, 10: 429
47. [47]
  [47] Baker J E, Burch R, Hibble S J, Loader P K. Appl Catal, 1990, 65: 281
48. [48]
  [48] Mohanty P, Pant K K, Parikh J, Sharma D K. Fuel Process Technol, 2011, 92: 600
49. [49]
  [49] An K, Somorjai G A. Catal Lett, 2015, 145: 233
50. [50]
  [50] Nagaraja B M, Siva Kumar V, Shasikala V, Padmasri A H, Sreedhar B, Raju B D, Rama Rao K S. Catal Commun, 2003, 4: 287
51. [51]
  [51] Liu D X, Zemlyanov D, Wu T P, Lobo-Lapidus R J, Dumesic J A, Miller J T, Marshall C L. J Catal, 2013, 299: 336
52. [52]
  [52] Vetere V, Merlo A B, Ruggera J F, Casella M L. J Braz Chem Soc, 2010, 21: 914
53. [53]
  [53] Sitthisa S, Resasco D E. Catal Lett, 2011, 141: 784
1. [1]
  Jieshuai Xiao , Yuan Zheng , Yue Zhao , Zhuangzhi Shi , Minyan Wang . Asymmetric Nozaki-Hiyama-Kishi (NHK)-type reaction of isatins with aromatic iodides by cobalt catalysis. Chinese Chemical Letters, 2025, 36(5): 110243-. doi: 10.1016/j.cclet.2024.110243
2. [2]
  Mudi Wu , Selvi Mushina , Mingwu Tan . Surface engineering of perovskite oxides via in-situ cobalt exsolution for catalytic toluene oxidation. Chinese Chemical Letters, 2026, 37(5): 111923-. doi: 10.1016/j.cclet.2025.111923
3. [3]
  Peng Guo , Shicheng Dong , Xiang-Gui Zhang , Bing-Bin Yang , Jun Zhu , Ke-Yin Ye . Cobalt-catalyzed migratory carbon-carbon cross-coupling of borabicyclo[3.3.1]nonane (9-BBN) borates. Chinese Chemical Letters, 2025, 36(4): 110052-. doi: 10.1016/j.cclet.2024.110052
4. [4]
  Hongping Zhao , Weiming Yuan . Merging catalytic electron donor-acceptor complex and copper catalysis: Enantioselective radical carbocyanation of alkenes. Chinese Chemical Letters, 2025, 36(10): 110894-. doi: 10.1016/j.cclet.2025.110894
5. [5]
  Xinlu Zhang , Yongxin Liu , Huan Li , Shutong Chen , Guocheng Wang , Xu Zhang , Chen Cao , Xiaoyuan Chen , Sheng Wang . A hypoxia-activated copper ion nanoexchanger for cancer immunotherapy by in situ precise production of immunogenic cell death inducer. Chinese Chemical Letters, 2026, 37(3): 111404-. doi: 10.1016/j.cclet.2025.111404
6. [6]
  Jun Shi , Xueting Zhou , Bing-Qing Yang , Biaobiao Jiang , Wei Wu , Hai Ren . Single-electron transfer enables enantioselective synthesis of spirooxindoles via dual copper and phosphoric acid catalysis. Chinese Chemical Letters, 2026, 37(4): 111250-. doi: 10.1016/j.cclet.2025.111250
7. [7]
  Xianxin Luo , Jianhao Xu , Qi Luo , Yan Xiao , Feng Wei , Meitong Li , Wenjiao Yuan , Penghui Shao , Shenglian Luo . Efficient copper sorption from saline wastewater using citrate-modified biochar with robust anti-salt interferences. Chinese Chemical Letters, 2026, 37(5): 111914-. doi: 10.1016/j.cclet.2025.111914
8. [8]
  Liangfeng Yang , Liang Zeng , Yanping Zhu , Qiuan Wang , Jinheng Li . Copper-catalyzed photoredox 1,4-amidocyanation of 1,3-enynes with N-amidopyridin-1-ium salts and TMSCN: Facile access to α-amido allenyl nitriles. Chinese Chemical Letters, 2024, 35(11): 109685-. doi: 10.1016/j.cclet.2024.109685
9. [9]
  Lingyun Shen , Shenxiang Yin , Qingshu Zheng , Zheming Sun , Wei Wang , Tao Tu . A rechargeable and portable hydrogen storage system grounded on soda water. Chinese Chemical Letters, 2025, 36(3): 110580-. doi: 10.1016/j.cclet.2024.110580
10. [10]
  Zunjie Zhang , Mengran Liu , Bingcheng Ge , Tianfang Yang , Shuaitong Wang , Yang Liu , Shuyan Gao . In-situ reconstructed Cu/NiO nanosheets synergistically boosting nitrate electroreduction to ammonia. Chinese Chemical Letters, 2025, 36(8): 110657-. doi: 10.1016/j.cclet.2024.110657
11. [11]
  Gangsheng Li , Xiang Yuan , Fu Liu , Zhihua Liu , Xujie Wang , Yuanyuan Liu , Yanmin Chen , Tingting Wang , Yanan Yang , Peicheng Zhang . Three-step synthesis of flavanostilbenes with a 2-cyclohepten-1-one core by Cu-mediated [5 + 2] cycloaddition/decarboxylation cascade. Chinese Chemical Letters, 2025, 36(2): 109880-. doi: 10.1016/j.cclet.2024.109880
12. [12]
  Chengxiao Zhao , Zhaolin Li , Dongfang Wu , Xiaofei Yang . SBA-15 templated covalent triazine frameworks for boosted photocatalytic hydrogen production. Acta Physico-Chimica Sinica, 2026, 42(1): 100149-0. doi: 10.1016/j.actphy.2025.100149
13. [13]
  Minghui Zhang , Na Zhang , Qian Zhao , Chao Wang , Alexander Steiner , Jianliang Xiao , Weijun Tang . Cobalt pincer complex-catalyzed highly enantioselective hydrogenation of quinoxalines. Chinese Chemical Letters, 2025, 36(4): 110081-. doi: 10.1016/j.cclet.2024.110081
14. [14]
  Hai-Bo Huang , Fang-Long Sun , Ze Luo , Meng-Yu Sun , Ben-Hao Liu , Xu-Sheng Wang , Hua Tang . MOF@MOF hierarchical heterotructures for enhanced photocatalytic H2O2 production and furfuryl alcohol oxidation. Chinese Journal of Structural Chemistry, 2025, 44(11): 100717-100717. doi: 10.1016/j.cjsc.2025.100717
15. [15]
  Ling Fang , Sha Wang , Shun Lu , Fengjun Yin , Yujie Dai , Lin Chang , Hong Liu . Efficient electroreduction of nitrate via enriched active phases on copper-cobalt oxides. Chinese Chemical Letters, 2024, 35(4): 108864-. doi: 10.1016/j.cclet.2023.108864
16. [16]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-0. doi: 10.3866/PKU.WHXB202408004
17. [17]
  Kun Yang , Anhui Li , Peng Zhang , Guilin Liu , Liusai Huang , Yumeng Fo , Luyuan Yang , Xiangyang Ji , Jian Liu , Weiyu Song . Hierarchical zeolites stabilized cobalt(Ⅱ) as propane dehydrogenation catalyst: Enhanced activity and coke tolerance via alkaline post-treatment. Chinese Chemical Letters, 2025, 36(5): 110663-. doi: 10.1016/j.cclet.2024.110663
18. [18]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
19. [19]
  Huiyuan Deng , Na Zhao , Junjie You , Zhicheng Pan , Bo Xing , Yuling Ye , Bo Lai , Yuxi Wang , Tongrui Lu , Xiaonan Liu . Removal of bisphenol a through peroxymonosulfate activation with N-doped graphite carbon spheres coated cobalt nanoparticles catalyst: Synergy of nonradicals. Chinese Chemical Letters, 2025, 36(8): 110650-. doi: 10.1016/j.cclet.2024.110650
20. [20]
  Ming Huang , Xiuju Cai , Yan Liu , Zhuofeng Ke . Base-controlled NHC-Ru-catalyzed transfer hydrogenation and α-methylation/transfer hydrogenation of ketones using methanol. Chinese Chemical Letters, 2024, 35(7): 109323-. doi: 10.1016/j.cclet.2023.109323

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(826)
HTML views(25)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142