Citation: Shuvo Jit Datta, Kyung Byung Yoon. Co-ETS-10 and Co-AM-6 as active catalysts for the oxidation of styrene to styrene oxide and benzaldehyde using molecular oxygen[J]. Chinese Journal of Catalysis, ;2015, 36(6): 897-905. doi: 10.1016/S1872-2067(15)60864-6 shu

Co-ETS-10 and Co-AM-6 as active catalysts for the oxidation of styrene to styrene oxide and benzaldehyde using molecular oxygen

Shuvo Jit Datta ,
Kyung Byung Yoon ^,

1.
Korea Center for Artificial Photosynthesis, Center for Nano Materials, Department of Chemistry, Sogang University, Seoul 121-742, Republic of Korea

Corresponding author: Kyung Byung Yoon,
Received Date: 2 March 2015
Available Online: 16 April 2015
Fund Project: This work was supported by the Ministry of Science, ICT and Future Planning through the National Research Foundation of Korea (no. 2009-0093886, no. 2012R1A2A3A01009806). (no. 2009-0093886, no. 2012R1A2A3A01009806)

Pristine ETS-10 and AM-6 and their Co²⁺-exchanged forms were prepared, and their catalytic activities toward the oxidation of styrene in oxygen atmosphere were studied in dimethylformamide. The catalysts were denoted as Co-E10-n (n = 0, 9, 26, 68, 81) and Co-A6-m (m = 0, 8, 23, 63, 79), where n and m denote the degree of Co²⁺ exchange. The products of the oxidation process were identified as styrene epoxide (E) and benzaldehyde (B). Both the pristine forms, ETS-10 (Co-E10-0) and AM-6 (Co-A6-0), and Co²⁺-exchanged forms displayed catalytic activities. With increasing n or m, the conversion, and hence the rate, increased. Specifically, the rates varied from 6.1 to 12.5 mmol·g^-1·h^-1 with increasing n (Co-E10-n catalysts) and from 5.4 to 12.4 mmol·g^-1·h^-1 with increasing m (Co-A6-m catalysts). In contrast, the E/B ratio decreased with increasing n or m. More specifically, the E/B ratio decreased from 2.1 to 0.1 with increasing n from 0 to 81 (Co-E10-n catalysts) and from 1.3 to 0.1 with increasing m from 0 to 79 (Co-A6-m catalysts). Co-E10-9 displayed the highest E yield and Co-A6-79 generated the highest B yield. The highest turnover frequency obtained was 36.3 Co^-1·h^-1, which was the highest one obtained among those obtained for the Co²⁺-exchanged zeolites and mesoporous silica reference materials studied in this work.
- Heterogeneous catalysis,
- Epoxidation,
- Cobalt,
- C=C activation,
- Zeolite
1. [1]
  [1] Joergensen K A. Chem Rev, 1989, 89: 431
2. [2]
  [2] Neumann R, Dahan M. Nature, 1997, 388: 353
3. [3]
  [3] Hill C L. Nature, 1999, 401: 436
4. [4]
  [4] Ishii Y, Sakaguchi S, Iwahama T. Adv Synth Catal, 2001, 343: 393
5. [5]
  [5] Tang Q H, Wang Y, Liang J, Wang P, Zhang Q H, Wan H L. Chem Commun, 2004: 440
6. [6]
  [6] Tang Q H, Zhang Q H, Wu H L, Wang Y. J Catal, 2005, 230: 384
7. [7]
  [7] Sebastian J, Jinka K M, Jasra R V. J Catal, 2006, 244: 208
8. [8]
  [8] Patil M V, Yadav M K, Jasra R V. J Mol Catal A, 2007, 277: 72
9. [9]
  [9] Jinka K M, Pai S M, Newalkar B L, Choudary N V, Jasra R V. Catal Commun, 2010, 11: 638
10. [10]
  [10] Cui H T, Zhang Y, Zhao L F, Zhu Y L. Catal Commun, 2011, 12: 417
11. [11]
  [11] Xu G, Xia Q H, Lu X H, Zhang Q, Zhan H J, J Mol Catal A, 2007, 266: 180
12. [12]
  [12] Qi B, Lu X H, Fang S Y, Lei J, Dong Y L, Zhou D, Xia Q H, J Mol Catal A, 2011, 334: 44
13. [13]
  [13] Tang B, Lu X H, Zhou D, Lei J, Niu Z H, Fan J, Xia Q H. Catal Commun, 2012, 21: 68
14. [14]
  [14] Tang B, Lu X H, Zhou D, Tian P, Niu Z H, Zhang J L, Chen X, Xia Q H. Catal Commun, 2013, 3: 42
15. [15]
  [15] Zhou D, Tang B, Lu X H, Wei X L, Li K, Xia Q H. Catal Commun, 2014, 45: 124
16. [16]
  [16] Wei X L, Lu X H, Ma X T, Peng C, Jiang H Z, Zhou D, Xia Q H, Catal Commun, 2015, 61: 48
17. [17]
  [17] Kuznicki S M. US Patent 4853202. 1989
18. [18]
  [18] Anderson M W, Terasaki O, Ohsuna T, Philippou A, MacKay S P, Ferreira A, Rocha J, Lidin S. Nature, 1994, 367: 347
19. [19]
  [19] Anderson M W, Terasaki O, Ohsuna T, Malley P J O, Philippou A, MacKay S P, Ferreira A, Rocha J, Lidin S. Philos Mag B, 1995,71: 813
20. [20]
  [20] Rocha J, Brandao P, Lin Z, Anderson M W, Alfredsson V, Terasaki O. Angew Chem Int Ed, 1997, 36: 100
21. [21]
  [21] Datta S J, Yoon K B. Angew Chem Int Ed, 2010, 49: 4971
22. [22]
  [22] Datta S J, Yoon K B. J Am Chem Soc, 2012, 134: 17202
23. [23]
  [23] Jeong N C, Lee M H, Yoon K B. Angew Chem Int Ed, 2007, 46: 5868
24. [24]
  [24] Datta S J, Yoon K B. Catal Today, 2013, 204: 60
1. [1]
  Yongheng Ren , Yang Chen , Hongwei Chen , Lu Zhang , Jiangfeng Yang , Qi Shi , Lin-Bing Sun , Jinping Li , Libo Li . Electrostatically driven kinetic Inverse CO2/C2H2 separation in LTA-type zeolites. Chinese Journal of Structural Chemistry, 2024, 43(10): 100394-100394. doi: 10.1016/j.cjsc.2024.100394
2. [2]
  Yu-Yao Li , Xiao-Hui Li , Zhi-Xuan An , Yang Chu , Xiu-Li Wang . Room-temperature olefin epoxidation reaction by two 2D cobalt metal-organic complexes under O₂ atmosphere: Coordination and structural regulation. Chinese Chemical Letters, 2025, 36(4): 109716-. doi: 10.1016/j.cclet.2024.109716
3. [3]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2024.100332
4. [4]
  Jieshuai Xiao , Yuan Zheng , Yue Zhao , Zhuangzhi Shi , Minyan Wang . Asymmetric Nozaki-Hiyama-Kishi (NHK)-type reaction of isatins with aromatic iodides by cobalt catalysis. Chinese Chemical Letters, 2025, 36(5): 110243-. doi: 10.1016/j.cclet.2024.110243
5. [5]
  Shuai Tang , Zian Wang , Mengyi Zhu , Xinyun Zhao , Xiaoyun Hu , Hua Zhang . Synthesis of organoboron compounds via heterogeneous C–H and C–X borylation. Chinese Chemical Letters, 2025, 36(5): 110503-. doi: 10.1016/j.cclet.2024.110503
6. [6]
  Yuhang Li , Yang Ling , Yanhang Ma . Application of three-dimensional electron diffraction in structure determination of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100237-100237. doi: 10.1016/j.cjsc.2024.100237
7. [7]
  Tianyi Zhou , Heng Yang , Guangbin Zhou , Feng Chen , Pan Gao . Recent advances of heterogeneous manganese catalysis in organic synthesis. Chinese Chemical Letters, 2026, 37(6): 112223-. doi: 10.1016/j.cclet.2025.112223
8. [8]
  Mudi Wu , Selvi Mushina , Mingwu Tan . Surface engineering of perovskite oxides via in-situ cobalt exsolution for catalytic toluene oxidation. Chinese Chemical Letters, 2026, 37(5): 111923-. doi: 10.1016/j.cclet.2025.111923
9. [9]
  Peng Guo , Shicheng Dong , Xiang-Gui Zhang , Bing-Bin Yang , Jun Zhu , Ke-Yin Ye . Cobalt-catalyzed migratory carbon-carbon cross-coupling of borabicyclo[3.3.1]nonane (9-BBN) borates. Chinese Chemical Letters, 2025, 36(4): 110052-. doi: 10.1016/j.cclet.2024.110052
10. [10]
  Siyu Zong , Xiaowei Yu , Yining Yang , Xin Yang , Jiyang Li . Multi-mode luminescence anti-counterfeiting and visual iron(Ⅲ) ions RTP detection constructed by assembly of CDs&Eu³⁺ in porous RHO zeolite. Chinese Chemical Letters, 2025, 36(6): 110343-. doi: 10.1016/j.cclet.2024.110343
11. [11]
  Heng Yang , Zhijie Zhou , Conghui Tang , Feng Chen . Recent advances in heterogeneous hydrosilylation of unsaturated carbon-carbon bonds. Chinese Chemical Letters, 2024, 35(6): 109257-. doi: 10.1016/j.cclet.2023.109257
12. [12]
  Wen-Jing Li , Jun-Bo Wang , Yu-Heng Liu , Mo Zhang , Zhan-Hui Zhang . Molybdenum-doped carbon nitride as an efficient heterogeneous catalyst for direct amination of nitroarenes with arylboronic acids. Chinese Chemical Letters, 2025, 36(3): 110001-. doi: 10.1016/j.cclet.2024.110001
13. [13]
  Chun Yin , Shuli Wang , Fulin Yang , Ligang Feng . Carbon-constrained heterogeneous Ni-Mo telluride for efficient urea oxidation. Chinese Chemical Letters, 2026, 37(6): 110999-. doi: 10.1016/j.cclet.2025.110999
14. [14]
  Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693
15. [15]
  Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
16. [16]
  Hua Liu , Jian Zhao , Qi Li , Xiang-Yu Zhang , Zhi-Wei Zheng , Kun Huang , Da-Bin Qin , Bin Zhao . Indium-captured zirconium-porphyrin frameworks displaying rare multi-selectivity for catalytic transfer hydrogenation of aldehydes and ketones. Chinese Chemical Letters, 2025, 36(6): 110593-. doi: 10.1016/j.cclet.2024.110593
17. [17]
  Chengyao Zhao , Jingyuan Liao , Yuxiang Zhu , Yiying Zhang , Lianjie Zhai , Junrong Huang , Hengzhi You . Polystyrene-supported phosphoric-acid catalyzed atroposelective construction of axially chiral N-aryl benzimidazoles. Chinese Chemical Letters, 2025, 36(6): 110337-. doi: 10.1016/j.cclet.2024.110337
18. [18]
  Shuangyu Wu , Jian Peng , Yue Jiang , Sijie Lin . The overlooked promotional effects of alcohols to BiOBr catalysts in photocatalytic degradation of organic pollutants. Chinese Chemical Letters, 2025, 36(11): 110819-. doi: 10.1016/j.cclet.2025.110819
19. [19]
  Wei Chen , Pieter Cnudde . A minireview to ketene chemistry in zeolite catalysis. Chinese Journal of Structural Chemistry, 2024, 43(11): 100412-100412. doi: 10.1016/j.cjsc.2024.100412
20. [20]
  Xiang Fu , Jun Yu , Weili Dai . Atomically dispersed cobalt in MFI zeolite framework for sustainable propane dehydrogenation. Chinese Journal of Structural Chemistry, 2025, 44(10): 100683-100683. doi: 10.1016/j.cjsc.2025.100683

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(825)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142