Citation: Shuvo Jit Datta, Kyung Byung Yoon. Co-ETS-10 and Co-AM-6 as active catalysts for the oxidation of styrene to styrene oxide and benzaldehyde using molecular oxygen[J]. Chinese Journal of Catalysis, ;2015, 36(6): 897-905. doi: 10.1016/S1872-2067(15)60864-6 shu

Co-ETS-10 and Co-AM-6 as active catalysts for the oxidation of styrene to styrene oxide and benzaldehyde using molecular oxygen

Shuvo Jit Datta ,
Kyung Byung Yoon ^,

1.
Korea Center for Artificial Photosynthesis, Center for Nano Materials, Department of Chemistry, Sogang University, Seoul 121-742, Republic of Korea

Corresponding author: Kyung Byung Yoon,
Received Date: 2 March 2015
Available Online: 16 April 2015
Fund Project: This work was supported by the Ministry of Science, ICT and Future Planning through the National Research Foundation of Korea (no. 2009-0093886, no. 2012R1A2A3A01009806). (no. 2009-0093886, no. 2012R1A2A3A01009806)

Pristine ETS-10 and AM-6 and their Co²⁺-exchanged forms were prepared, and their catalytic activities toward the oxidation of styrene in oxygen atmosphere were studied in dimethylformamide. The catalysts were denoted as Co-E10-n (n = 0, 9, 26, 68, 81) and Co-A6-m (m = 0, 8, 23, 63, 79), where n and m denote the degree of Co²⁺ exchange. The products of the oxidation process were identified as styrene epoxide (E) and benzaldehyde (B). Both the pristine forms, ETS-10 (Co-E10-0) and AM-6 (Co-A6-0), and Co²⁺-exchanged forms displayed catalytic activities. With increasing n or m, the conversion, and hence the rate, increased. Specifically, the rates varied from 6.1 to 12.5 mmol·g^-1·h^-1 with increasing n (Co-E10-n catalysts) and from 5.4 to 12.4 mmol·g^-1·h^-1 with increasing m (Co-A6-m catalysts). In contrast, the E/B ratio decreased with increasing n or m. More specifically, the E/B ratio decreased from 2.1 to 0.1 with increasing n from 0 to 81 (Co-E10-n catalysts) and from 1.3 to 0.1 with increasing m from 0 to 79 (Co-A6-m catalysts). Co-E10-9 displayed the highest E yield and Co-A6-79 generated the highest B yield. The highest turnover frequency obtained was 36.3 Co^-1·h^-1, which was the highest one obtained among those obtained for the Co²⁺-exchanged zeolites and mesoporous silica reference materials studied in this work.
- Heterogeneous catalysis,
- Epoxidation,
- Cobalt,
- C=C activation,
- Zeolite
1. [1]
  [1] Joergensen K A. Chem Rev, 1989, 89: 431
2. [2]
  [2] Neumann R, Dahan M. Nature, 1997, 388: 353
3. [3]
  [3] Hill C L. Nature, 1999, 401: 436
4. [4]
  [4] Ishii Y, Sakaguchi S, Iwahama T. Adv Synth Catal, 2001, 343: 393
5. [5]
  [5] Tang Q H, Wang Y, Liang J, Wang P, Zhang Q H, Wan H L. Chem Commun, 2004: 440
6. [6]
  [6] Tang Q H, Zhang Q H, Wu H L, Wang Y. J Catal, 2005, 230: 384
7. [7]
  [7] Sebastian J, Jinka K M, Jasra R V. J Catal, 2006, 244: 208
8. [8]
  [8] Patil M V, Yadav M K, Jasra R V. J Mol Catal A, 2007, 277: 72
9. [9]
  [9] Jinka K M, Pai S M, Newalkar B L, Choudary N V, Jasra R V. Catal Commun, 2010, 11: 638
10. [10]
  [10] Cui H T, Zhang Y, Zhao L F, Zhu Y L. Catal Commun, 2011, 12: 417
11. [11]
  [11] Xu G, Xia Q H, Lu X H, Zhang Q, Zhan H J, J Mol Catal A, 2007, 266: 180
12. [12]
  [12] Qi B, Lu X H, Fang S Y, Lei J, Dong Y L, Zhou D, Xia Q H, J Mol Catal A, 2011, 334: 44
13. [13]
  [13] Tang B, Lu X H, Zhou D, Lei J, Niu Z H, Fan J, Xia Q H. Catal Commun, 2012, 21: 68
14. [14]
  [14] Tang B, Lu X H, Zhou D, Tian P, Niu Z H, Zhang J L, Chen X, Xia Q H. Catal Commun, 2013, 3: 42
15. [15]
  [15] Zhou D, Tang B, Lu X H, Wei X L, Li K, Xia Q H. Catal Commun, 2014, 45: 124
16. [16]
  [16] Wei X L, Lu X H, Ma X T, Peng C, Jiang H Z, Zhou D, Xia Q H, Catal Commun, 2015, 61: 48
17. [17]
  [17] Kuznicki S M. US Patent 4853202. 1989
18. [18]
  [18] Anderson M W, Terasaki O, Ohsuna T, Philippou A, MacKay S P, Ferreira A, Rocha J, Lidin S. Nature, 1994, 367: 347
19. [19]
  [19] Anderson M W, Terasaki O, Ohsuna T, Malley P J O, Philippou A, MacKay S P, Ferreira A, Rocha J, Lidin S. Philos Mag B, 1995,71: 813
20. [20]
  [20] Rocha J, Brandao P, Lin Z, Anderson M W, Alfredsson V, Terasaki O. Angew Chem Int Ed, 1997, 36: 100
21. [21]
  [21] Datta S J, Yoon K B. Angew Chem Int Ed, 2010, 49: 4971
22. [22]
  [22] Datta S J, Yoon K B. J Am Chem Soc, 2012, 134: 17202
23. [23]
  [23] Jeong N C, Lee M H, Yoon K B. Angew Chem Int Ed, 2007, 46: 5868
24. [24]
  [24] Datta S J, Yoon K B. Catal Today, 2013, 204: 60
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