Citation: Kazem Karami, Samaneh Dehghani Najvani, Nasrin Haghighat Naeini, Pablo Hervés. Palladium particles from oxime-derived palladacycle supported on Fe₃O₄/oleic acid as a catalyst for the copper-free Sonogashira cross-coupling reaction[J]. Chinese Journal of Catalysis, ;2015, 36(7): 1047-1053. doi: 10.1016/S1872-2067(15)60837-3 shu

Palladium particles from oxime-derived palladacycle supported on Fe₃O₄/oleic acid as a catalyst for the copper-free Sonogashira cross-coupling reaction

1.
a Department of Chemistry, Isfahan University of Technology, Isfahan 84156/83111, Iran;

Corresponding author: Kazem Karami,
Received Date: 7 January 2015
Available Online: 4 March 2015
Fund Project:

An oxime-derived palladacycle was synthesized using 4-bromobenzoxime and pyridine in CHCl₃, and characterized by FT-IR and ¹H NMR spectroscopy. This Pd complex was supported on Fe₃O₄/oleic acid and shown to be an efficient catalyst for the copper-free Sonogashira cross-coupling reaction of various aryl halides with phenylacetylene in air and in ethanol or mixed aqueous medium. The oxime-derived palladacycle gave highly active palladium nanoparticles for the organic synthesis. The coupling products were obtained in high yields with low Pd loading and the heterogeneous catalyst can be separated by an external magnet and reused six times without loss of its activity. The characterization of the catalyst was carried out by XRD, SEM and TEM. Both TEM and XRD revealed that the palladium nanoparticles were well dispersed with diameters from 5 to 10 nm and average size 9.97 nm.
- Oxime-derived palladacycle,
- Sonogashira cross-coupling reaction,
- Copper-free,
- Magnetite/oleic acid,
- Low Pd loading
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沈阳化工大学材料科学与工程学院沈阳 110142

Palladium particles from oxime-derived palladacycle supported on Fe3O4/oleic acid as a catalyst for the copper-free Sonogashira cross-coupling reaction

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通讯作者: 陈斌, bchen63@163.com

Palladium particles from oxime-derived palladacycle supported on Fe₃O₄/oleic acid as a catalyst for the copper-free Sonogashira cross-coupling reaction