Citation: Dongmei Fu, Feifang Zhang, Lianzhi Wang, Fan Yang, Xinmiao Liang. Simultaneous removal of nitrobenzene and phenol by homogenous catalytic wet air oxidation[J]. Chinese Journal of Catalysis, ;2015, 36(7): 952-956. doi: 10.1016/S1872-2067(15)60835-X shu

Simultaneous removal of nitrobenzene and phenol by homogenous catalytic wet air oxidation

1.
a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Dongmei Fu,
Received Date: 22 March 2015
Available Online: 10 April 2015
Fund Project: 国家自然科学基金(21107108和21267009) (21107108和21267009) 中国科学院知识创新工程(KJCX2-YW-H04). (KJCX2-YW-H04)

The simultaneous wet air oxidation of nitrobenzene (NB) and phenol with homogenous catalyst was carried out in a stainless autoclave in a temperature range of 150-210 ℃ and at a partial oxygen pressure of 1.0 MPa. Compared with the non-catalytic co-oxidation of NB and phenol, the presence of the homogeneous catalyst greatly improved the conversion of both compounds. The transition metal ions Cu²⁺, Co²⁺ and Ni²⁺ were found to be effective catalysts, with Cu²⁺ affording the best results. How phenol was added to the autoclave was investigated and was found to affect the conversion of NB. Adding phenol in smaller portions can help to degrade NB more effectively. As an example, two additions of phenol with Cu²⁺ as the homogenous catalyst allowed 95% conversion of NB at 200 ℃ in 1 h. This catalytic co-oxidation method incorporating the addition of phenol initiator batches therefore provides an alternative and effective means of removing persistent organic pollutants from the environment.
- Catalytic wet air oxidation,
- Co-oxidation,
- Homogenous catalyst,
- Advanced oxidation process,
- Wastewater treatment
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沈阳化工大学材料科学与工程学院沈阳 110142