Citation: Dongmei Fu, Feifang Zhang, Lianzhi Wang, Fan Yang, Xinmiao Liang. Simultaneous removal of nitrobenzene and phenol by homogenous catalytic wet air oxidation[J]. Chinese Journal of Catalysis, ;2015, 36(7): 952-956. doi: 10.1016/S1872-2067(15)60835-X shu

Simultaneous removal of nitrobenzene and phenol by homogenous catalytic wet air oxidation

1.
a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Dongmei Fu,
Received Date: 22 March 2015
Available Online: 10 April 2015
Fund Project: 国家自然科学基金(21107108和21267009) (21107108和21267009) 中国科学院知识创新工程(KJCX2-YW-H04). (KJCX2-YW-H04)

The simultaneous wet air oxidation of nitrobenzene (NB) and phenol with homogenous catalyst was carried out in a stainless autoclave in a temperature range of 150-210 ℃ and at a partial oxygen pressure of 1.0 MPa. Compared with the non-catalytic co-oxidation of NB and phenol, the presence of the homogeneous catalyst greatly improved the conversion of both compounds. The transition metal ions Cu²⁺, Co²⁺ and Ni²⁺ were found to be effective catalysts, with Cu²⁺ affording the best results. How phenol was added to the autoclave was investigated and was found to affect the conversion of NB. Adding phenol in smaller portions can help to degrade NB more effectively. As an example, two additions of phenol with Cu²⁺ as the homogenous catalyst allowed 95% conversion of NB at 200 ℃ in 1 h. This catalytic co-oxidation method incorporating the addition of phenol initiator batches therefore provides an alternative and effective means of removing persistent organic pollutants from the environment.
- Catalytic wet air oxidation,
- Co-oxidation,
- Homogenous catalyst,
- Advanced oxidation process,
- Wastewater treatment
1. [1]
  [1] Mu Y, Yu H Q, Zheng J C, Zhang S J, Sheng G P. Chemosphere, 2004, 54: 789
2. [2]
  [2] Latifoglu A, Gurol M D. Water Res, 2003, 37: 1879
3. [3]
  [3] Li Y P, Cao H B, Liu C M, Zhang Y. J Hazard Mater, 2007, 148: 158
4. [4]
  [4] Yuan J, Lü Y K, Li Y, Li J P. Chin J Catal (袁进, 吕永康, 李裕, 李进平), 2010, 31:597
5. [5]
  [5] Restivo J, Rocha R P, Silva A M T, Orfao J J M, Pereira M F R, Figueiredo J L. Chin J Catal (催化学报), 2014, 35: 896
6. [6]
  [6] Chamarro E, Marco A, Esplugas S. Water Res, 2001, 35: 1047
7. [7]
  [7] Contreras S, Rodriguez M, Chamarro E, Esplugas S, Casado J. Water Sci Technol, 2001, 44: 39
8. [8]
  [8] Bandy J, Shemer H, Linden K G. Environ Eng Sci, 2009, 26: 973
9. [9]
  [9] Kim K H, Ihm S K. J Hazard Mater, 2011, 186: 16
10. [10]
  [10] Luck F. Catal Today, 1999, 53: 81
11. [11]
  [11] Oller I, Malato S, Sanchez-Perez J A. Sci Total Environ, 2011, 409: 4141
12. [12]
  [12] Suarez-Ojeda M E, Stüber F, Fortuny A, Fabregat A, Carrera J, Font J. Appl Catal B: Environ, 2005, 58: 105
13. [13]
  [13] Levec J, Pintar A. Catal Today, 2007, 124: 172
14. [14]
  [14] Fu J, Kyzas G Z. Chin J Catal (催化学报), 2014, 35: 1
15. [15]
  [15] Willms R S, Reible D D, Wetzel D M, Harrison D P. Ind Eng Chem Res, 1987, 26: 606
16. [16]
  [16] Birchmeier M J, Hill C G, Houtman C J, Atalla R H, Weinstock I A. Ind Eng Chem Res, 2000, 39: 55
17. [17]
  [17] Oulego P, Collado S, Laca A, Diaz M. J Hazard Mater, 2014, 280: 570
18. [18]
  [18] Fu D M, Chen J P, Liang X M. Chemosphere, 2005, 59: 905
19. [19]
  [19] Fu D M, Liu R H, Xu Q, Xue X Y, Zhang F F, Liang X. M. Fresenius Environ Bull, 2007, 16: 71
20. [20]
  [20] Fu D M, Peng Y R, Liu R H, Zhang F F, Liang X M. Chemosphere, 2009, 75: 701
1. [1]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
2. [2]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
3. [3]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
4. [4]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045
5. [5]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
6. [6]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
7. [7]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
8. [8]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
9. [9]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
10. [10]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
11. [11]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
12. [12]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
13. [13]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
14. [14]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
15. [15]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
16. [16]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
17. [17]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Preparation of Superhydrophobic Surfaces and Their Application in Oily Wastewater Treatment: Design of a Comprehensive Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(2): 34-40. doi: 10.3866/PKU.DXHX202307081
18. [18]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
19. [19]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
20. [20]
  Liu Lin , Zemin Sun , Huatian Chen , Lian Zhao , Mingyue Sun , Yitao Yang , Zhensheng Liao , Xinyu Wu , Xinxin Li , Cheng Tang . Recent Advances in Electrocatalytic Two-Electron Water Oxidation for Green H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(4): 2305019-0. doi: 10.3866/PKU.WHXB202305019

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(330)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142