Citation: Shuai Zou, Zaihui Fu, Chao Xiang, Wenfeng Wu, Senpei Tang, Yachun Liu, Dulin Yin. Mild, one-step hydrothermal synthesis of carbon-coated CdS nanoparticles with improved photocatalytic activity and stability[J]. Chinese Journal of Catalysis, ;2015, 36(7): 1077-1085. doi: 10.1016/S1872-2067(15)60827-0 shu

Mild, one-step hydrothermal synthesis of carbon-coated CdS nanoparticles with improved photocatalytic activity and stability

1.
National & Local United Engineering Laboratory for New Petrochemical Materials & Fine Utilization of Resources, Key Laboratory of Resource Fine-Processing and Advanced Materials of Hunan Province and Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, Hunan, China

Corresponding author: Zaihui Fu,
Received Date: 14 January 2015
Available Online: 27 February 2015
Fund Project: 国家自然科学基金(20873040) (20873040) 高等学校博士学科点专项科研基金(20124306110005) (20124306110005) 湖南省自然科学基金(10JJ2007, 14JJ2148) (10JJ2007, 14JJ2148)

Carbon-coated CdS (CdS@C) nanoparticles were conveniently prepared by a one-step hydrothermal carbonization method at temperature as low as 130 ℃, in which cadmium acetate and glucose were used as the cadmium and carbon sources, respectively, and thiourea was used as the sulfur source and catalyst for the hydrothermal carbonization of glucose. The prepared CdS@C particles possess a smaller size, better dispersion, and more uniform distribution than pure CdS particles prepared under the same conditions. Furthermore, the hydrothermal carbonization of glucose easily induces the prior formation of metastable cubic CdS crystals. In addition, the carbonaceous species coated on the surface of CdS expands the range of absorption light and slightly decreases the band gap of CdS, as well as reduces the recombination of the photogenerated electron-hole pairs of CdS and its photo-oxidative corrosion, which can improve the photocatalytic activity and stability of CdS for the photo-oxidative degradation of methyl orange in aqueous solution under visible light irradiation.
- Glucose carbonization,
- Carbon-coated cadmiun sulfide,
- Photo-oxidative degradation,
- Visible light irradiation,
- Methyl orange
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