Citation: Yongsheng Peng, Wenguang Leng, Bin Dong, Rile Ge, Hongdong Duan, Yan’an Gao. Bottom-up preparation of gold nanoparticle-mesoporous silica composite nanotubes as a catalyst for the reduction of 4-nitrophenol[J]. Chinese Journal of Catalysis, ;2015, 36(7): 1117-1123. doi: 10.1016/S1872-2067(14)60310-7 shu

Bottom-up preparation of gold nanoparticle-mesoporous silica composite nanotubes as a catalyst for the reduction of 4-nitrophenol

1.
a School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan 250353, Shandong, China;

Corresponding author: Hongdong Duan, Yan’an Gao,
Received Date: 7 January 2015
Available Online: 7 February 2015
Fund Project: 国家自然科学基金(21273235, 21303076, 21403214) (21273235, 21303076, 21403214)

Gold (Au) nanoparticle (NP)-mesoporous silica (SiO₂) composite nanotubes were prepared by a bottom-up approach, in which Au NPs were anchored to the inner wall of mesoporous SiO₂ tubular shells. In this composite, the agglomeration, exfoliation, and grain growth of Au NPs were restricted, and the loading and size of the catalyst NPs were easily tuned. The mesoporous shell, open ends, and one-dimensional passage of the SiO₂ nanotubes all promote the diffusion of reactants, which enhanced the catalytic efficiency of this composite in the reduction of 4-nitrophenol. The Au NP-mesoporous SiO₂ composite nanotubes also demonstrated good reusability, and no leaching or agglomeration of the Au NPs was observed during the catalytic reaction.
- GoldMesoporous silica,
- Nanotube,
- Bottom-up approach,
- Catalyst,
- 4-Nitrophenol reduction,
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沈阳化工大学材料科学与工程学院沈阳 110142