Citation: Qiuhua Zhu, Hongwei Cheng, Xingli Zou, Xionggang Lu, Qian Xu, Zhongfu Zhou. Synthesis, characterization, and catalytic performance of La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite catalysts in dry reforming of coke oven gas[J]. Chinese Journal of Catalysis, ;2015, 36(7): 915-924. doi: 10.1016/S1872-2067(14)60303-X shu

Synthesis, characterization, and catalytic performance of La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite catalysts in dry reforming of coke oven gas

Qiuhua Zhu ^a ,
Hongwei Cheng ^a,, ,
Xingli Zou ^a ,
Xionggang Lu ^a,, ,
Qian Xu ^a ,
Zhongfu Zhou ^a,b

1.
a Shanghai Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University, Shanghai 200072, China;

Corresponding author: Hongwei Cheng, Xionggang Lu,
Received Date: 23 December 2014
Available Online: 28 January 2015
Fund Project: 国家自然科学基金(51474145) (51474145) 国家杰出青年科学基金(51225401) (51225401) 上海市青年科技启明星计划(15QA1402100) (15QA1402100) 上海市教育委员会科研创新项目(14YZ013). (14YZ013)

The dry reforming of coke oven gas (COG) to produce syngas was performed over La_0.6Sr_0.4Ni_xCo_1-xO₃ catalysts in a fixed-bed reactor at 800 ℃. These perovskite-type oxides were synthesized using a sol-gel method and characterized using X-ray diffraction (XRD), N₂ adsorption-desorption, temperature-programmed reduction of H₂, scanning electron microscopy, transmission electron microscopy, and thermogravimetry-differential scanning calorimetry. XRD results showed that the La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite-type oxides formed quaternary solid solutions. The effects of the degree of Ni substitution (x) and the catalyst calcination temperature on the dry reforming of COG were investigated. XRD analysis of the tested catalysts showed the formation of Ni⁰, Co⁰, and La₂O₂CO₃, of which the latter is the main active phase responsible for the high activity and stability, and the suppression of coke formation under severe reaction conditions. COG rich in H₂ can also reduce the formation of carbon deposits by inhibiting CH₄ decomposition.
- Syngas,
- Catalytic activity,
- Perovskite,
- Dry reforming,
- Coke oven gas,
- Carbon deposit
1. [1]
  [1] Domínguez A, Fernández Y, Fidalgo B, Pis J J, Menéndez J A. Energy Fuels, 2007, 21: 2066
2. [2]
  [2] Zahedinezhad M, Rowshanzamir S, Eikani M H. Int J Hydrogen Energy, 2009, 34: 1292
3. [3]
  [3] Bernudez J M, Ferrera-Lorenzo N, Luque S, Arenillas A, Menendez J A. Fuel Process Technol, 2013, 115: 215
4. [4]
  [4] Tao W, Cheng H W, Zhu Q H, Lu X G, Ding W Z. Appl Mech Mater, 2013, 394: 270
5. [5]
  [5] Modesto M, Nebra S A. Appl Therm Eng, 2009, 29: 2127
6. [6]
  [6] Suttiumporn K, Maneerung T, Kathiraser Y, Kawi S. Int J Hydrogen Energy, 2012, 37: 11195
7. [7]
  [7] Wang Q, Luo J, Zhong Z, Borgna A. Energy Environ Sci, 2011, 4: 42
8. [8]
  [8] Song C S. Catal Today, 2002, 77: 17
9. [9]
  [9] Ni M, Leung D Y C, Leung M K H, Sumathy K. Fuel Process Technol, 2006, 87: 461
10. [10]
  [10] Turpeinen E, Raudaskoski R, Pongracz E, Keiski R L. Int J Hydrogen Energy, 2008, 33: 6635
11. [11]
  [11] Bermudez J M, Fidalgo B, Arenillas A, Menendez J A. Fuel, 2010, 89: 2897
12. [12]
  [12] Yang Z B, Ding W Z, Zhang Y W, Lu X G, Zhang Y W, Shen P J. Int J Hydrogen Energy, 2010, 35: 6239
13. [13]
  [13] Shen J, Wang Z Z, Yang H W, Yao R S. Energy Fuels, 2007, 21: 3588
14. [14]
  [14] Joseck F, Wang M, Wu Y. Int J Hydrogen Energy, 2008, 33: 1445
15. [15]
  [15] Cheng H W, Lu X G, Hu D H, Zhang Y F, Ding W Z, Zhao H L. Int J Hydrogen Energy, 2011, 36: 528
16. [16]
  [16] Matos J, Diaz K, Carcia V, Cordero T C, Brito J L. Catal Lett, 2006, 109: 163
17. [17]
  [17] Pompeo F, Gazzoli D, Nichio N N. Int J Hydrogen Energy, 2009, 34: 2260
18. [18]
  [18] Hirose T, Ozawa Y, Nagai M. Chin J Catal (催化学报), 2011, 32: 771
19. [19]
  [19] Bartholomew C H. Catal Rev Sci Eng, 1982, 24: 67
20. [20]
  [20] Goldwasser M R, Rivas M E, Pietri E, Perez-Zurita M J, Cubeiro M L, Grivobal-Constant A, Leclerq G. J Mol Catal A, 2005, 228: 325
21. [21]
  [21] Moradi G R, Khosravian F, Kahmanzadeh M. Chin J Catal (催化学报), 2012, 33: 797
22. [22]
  [22] Echchahed B, Kaliaguine S, Alamdari H. Int J Chem React Eng, 2006, 4: A29
23. [23]
  [23] Valderrama G, Kiennemann A, Goldwasser M R. Catal Today, 2008, 133: 142
24. [24]
  [24] Sutthiumporn K, Kawi S. Int J Hydrogen Energy, 2011, 36: 14435
25. [25]
  [25] Li Q M, Zhu X F, He X F, Cong Y, Yang W S. J Membr Sci, 2011, 367: 134
26. [26]
  [26] Luo H X, Jiang H Q, Efimov K, Caro J, Wang H H. AIChE J, 2011, 57: 2738
27. [27]
  [27] Zhang Y W, Cheng H W, Lu X G, Ding W Z, Zhou G Z. Rare Metals, 2009, 28: 582
28. [28]
  [28] Cheng H W, Zhang Y W, Lu X G, Ding W Z, Li Q. Energy Fuels, 2009, 23: 414
29. [29]
  [29] Tao W, Cheng H W, Yao W L, Lu X G, Zhu Q H, Li G S, Zhou Z F. Int J Hydrogen Energy, 2014, 39: 18650
30. [30]
  [30] Guo J Z, Hou Z Y, Gao J, Zheng X M. Energy Fuels, 2008, 22: 1444
31. [31]
  [31] Roh H S, Jun K W, Dong W S, Chang J S, Park S E, Joe Y I. J Mol Catal A, 2002, 181: 137
32. [32]
  [32] Bedel L, Roger A C, Estournes C, Kiennemann A. Catal Today, 2003, 85: 207
33. [33]
  [33] Valderrama G, Kiennemann A, Goldwasser M R. J Power Sources, 2010, 195: 1765
34. [34]
  [34] Sokolov S, Kondratenko E V, Pohl M M, Barkschat A, Rodemerk U. Appl Catal B, 2012, 113-114: 19
35. [35]
  [35] Zhang Z L, Verykios X E. Appl Catal A, 1996, 138: 109
36. [36]
  [36] Zhang Z L, Verykios X E, Macdonald S M, Affrossman S. J Phys Chem, 1996, 100: 744
37. [37]
  [37] Orera A, Larraz G, Sanjuán M L. J Eur Ceram Soc, 2013, 33: 2103
38. [38]
  [38] Fierro J L G, Tascon J M D, Tejuca L G. J Catal, 1985, 93: 83
39. [39]
  [39] Sierra Gallego G, Mondragon F, Barrault J, Tatibouet J M, Batiot-Duperyrat C. Appl Catal A, 2006, 311: 164
40. [40]
  [40] Duprez D, Demiccheli M C, Marecot P, Barbier J, Ferretti O A, Ponzi E N. J Catal, 1990, 124: 324
41. [41]
  [41] Valderrama G, Navarro C U, Goldwasser M R. J Power Sources, 2013, 234: 31
42. [42]
  [42] Cheng H W, Feng S H, Tao W, Lu X G, Yao W L, Li G S, Zhou Z F. Int J Hydrogen Energy, 2014, 39: 12604
43. [43]
  [43] Tsyganok A I, Tsunoda T, Hamakawa S, Suzuki K, Takehira K, Hayakawa T. J Catal, 2003, 213: 191
44. [44]
  [44] Slagtern A, Schuurman Y, Leclercq C, Verykios X, Mirodatos C. J Catal, 1997, 172: 118
45. [45]
  [45] Rynkowski J M, Paryjczak T, Lenik M. Appl Catal A, 1995, 126: 257
46. [46]
  [46] Hou Z Y, Yokota O, Tanaka T, Yashima T. Catal Lett, 2003, 89: 121
1. [1]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
2. [2]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 2309045-0. doi: 10.3866/PKU.WHXB202309045
3. [3]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
4. [4]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
5. [5]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
6. [6]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
7. [7]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . Highly Efficient, Targeted, and Traceable Perovskite Nanocrystals for Photoelectrocatalytic Oncotherapy. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-0. doi: 10.1016/j.actphy.2024.100042
8. [8]
  Weicheng Feng , Jingcheng Yu , Yilan Yang , Yige Guo , Geng Zou , Xiaoju Liu , Zhou Chen , Kun Dong , Yuefeng Song , Guoxiong Wang , Xinhe Bao . Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(6): 2306013-0. doi: 10.3866/PKU.WHXB202306013
9. [9]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . Emerging Irreversible and Reversible Ion Migrations in Perovskites. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-0. doi: 10.3866/PKU.WHXB202311011
10. [10]
  Nengmin ZHU , Wenhao ZHU , Xiaoyao YIN , Songzhi ZHENG , Hao LI , Zeyuan WANG , Wenhao WEI , Xuanheng CHEN , Weihai SUN . Preparation of high-performance CsPbBr₃ perovskite solar cells by the aqueous solution solvent method. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1131-1140. doi: 10.11862/CJIC.20240419
11. [11]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
12. [12]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-0. doi: 10.1016/j.actphy.2025.100074
13. [13]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
14. [14]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
15. [15]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
16. [16]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110
17. [17]
  Qilin YU , Yifei XU , Pengjun ZHANG , Shuwei HAO , Chongqiang ZHU , Chunhui YANG . Effect of regulating K⁺/Na⁺ ratio on the structure and optical properties of double perovskite Cs₂NaBiCl₆: Mn²⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1058-1067. doi: 10.11862/CJIC.20240418
18. [18]
  Mingxuan Qi , Lanyu Jin , Honghe Yao , Zipeng Xu , Teng Cheng , Qi Chen , Cheng Zhu , Yang Bai . Recent progress on electrical failure and stability of perovskite solar cells under reverse bias. Acta Physico-Chimica Sinica, 2025, 41(8): 100088-0. doi: 10.1016/j.actphy.2025.100088
19. [19]
  Ximeng CHI , Jianwei WEI , Yunyun WANG , Wenxin DENG , Jiayi DAI , Xu ZHOU . First-principles study of the electronic structure and optical properties of Au and I doped-inorganic lead-free double perovskite Cs₂NaBiCl₆. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1371-1379. doi: 10.11862/CJIC.20240401
20. [20]
  Ying Liang , Yuheng Deng , Shilv Yu , Jiahao Cheng , Jiawei Song , Jun Yao , Yichen Yang , Wanlei Zhang , Wenjing Zhou , Xin Zhang , Wenjian Shen , Guijie Liang , Bin Li , Yong Peng , Run Hu , Wangnan Li . Machine learning-guided antireflection coatings architectures and interface modification for synergistically optimizing efficient and stable perovskite solar cells. Acta Physico-Chimica Sinica, 2025, 41(9): 100098-0. doi: 10.1016/j.actphy.2025.100098

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(475)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, characterization, and catalytic performance of La0.6Sr0.4NixCo1-xO3 perovskite catalysts in dry reforming of coke oven gas

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, characterization, and catalytic performance of La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite catalysts in dry reforming of coke oven gas