Citation: Mingming Zhang, Ya Gao, Chuang Li, Changhai Liang. Chemical vapor deposition of Pd(C₃H₅)(C₅H₅) for the synthesis of reusable Pd@ZIF-8 catalysts for the Suzuki coupling reaction[J]. Chinese Journal of Catalysis, ;2015, 36(4): 588-594. doi: 10.1016/S1872-2067(14)60292-8 shu

Chemical vapor deposition of Pd(C₃H₅)(C₅H₅) for the synthesis of reusable Pd@ZIF-8 catalysts for the Suzuki coupling reaction

1.
Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

Corresponding author: Changhai Liang,
Received Date: 10 November 2014
Available Online: 29 December 2014
Fund Project: 国家自然科学基金(21073023) (21073023) 中央高校基本科研业务费专项资金(DUT13RC(3)41) (DUT13RC(3)41) 中国博士后科学基金(2013M541220). (2013M541220)

A zeolite-imidazolium-framework-supported Pd-based heterogeneous catalyst (Pd@ZIF-8) was prepared by a metal-organic chemical vapor deposition method under mild conditions using Pd(C₃H₅)(C₅H₅) as the Pd precursor. N₂ adsorption and pore size distribution data showed that ZIF-8 and Pd@ZIF-8 both possessed high surface areas. Transmission electron microscopy images showed that Pd nanoparticles with sizes of about 1.5-3.5 nm were homogeneously dispersed on the ZIF-8 support in Pd@ZIF-8. The Pd@ZIF-8 catalyst showed good activity in Suzuki coupling reactions with several different kinds of aryl halides. It could be reused at least six times without dramatic loss of activity or decomposition of the ZIF-8 structure.
- Palladium,
- ZIF-8,
- Metal-organic chemical vapor deposition,
- Suzuki coupling reaction
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通讯作者: 陈斌, bchen63@163.com

Chemical vapor deposition of Pd(C₃H₅)(C₅H₅) for the synthesis of reusable Pd@ZIF-8 catalysts for the Suzuki coupling reaction