Citation: Xuchuan Chen, Mei Dong, Xianjun Niu, Kai Wang, Gang Chen, Weibin Fan, Jianguo Wang, Zhangfeng Qin. Influence of Zn species in HZSM-5 on ethylene aromatization[J]. Chinese Journal of Catalysis, ;2015, 36(6): 880-888. doi: 10.1016/S1872-2067(14)60289-8 shu

Influence of Zn species in HZSM-5 on ethylene aromatization

Xuchuan Chen ^a,b ,
Mei Dong ^a,, ,
Xianjun Niu ^a,b ,
Kai Wang ^a,b ,
Gang Chen ^a,b ,
Weibin Fan ^a,, ,
Jianguo Wang ^a ,
Zhangfeng Qin ^a

1.
a State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, Shanxi China;

Corresponding author: Mei Dong, Weibin Fan,
Received Date: 27 November 2014
Available Online: 9 January 2015
Fund Project: 国家重点基础研究发展规划(973计划, 2011CB201400) (973计划, 2011CB201400) 国家自然科学基金(21273263, 21273264, 21227002) (21273263, 21273264, 21227002) 山西省自然科学基金(2012011005-2, 2013021007-3). (2012011005-2, 2013021007-3)

Zn-containing HZSM-5 zeolites with different Zn contents were prepared by ion exchange and physically mixing methods, and were characterized by X-ray diffraction, scanning electron microscope, N₂ adsorption-desorption, NH₃temperature programmed desorption, pyridine adsorption infrared spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy and X-ray photoelectron spectroscopy. Zn species introduced into HZSM-5 were identified as ZnO crystals, ZnO clusters in the zeolite channel and Zn(OH)⁺ species formed from a solid state reaction between dispersed ZnO and the protons in the zeolite. The preparation method has a significant influence on the distribution of the Zn species. The catalytic behavior of Zn-containing HZSM-5 with different Zn contents showed that the Zn(OH)⁺ and ZnO species were responsible for aromatic formation from ethylene.
- Ethylene,
- Aromatization,
- Zn species,
- HZSM-5,
- Dehydrogenation
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