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Citation: Pingjing Chang, Haiyang Cheng, Weiwei Lin, Xiaoru Li, Fengyu Zhao. A stable and active AgxS crystal preparation and its performance as photocatalyst[J]. Chinese Journal of Catalysis, ;2015, 36(4): 564-571. doi: 10.1016/S1872-2067(14)60288-6 shu

A stable and active AgxS crystal preparation and its performance as photocatalyst

  • 1.

    a State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China;

  • Corresponding author: Fengyu Zhao, 
  • Received Date: 23 November 2014
    Available Online: 8 January 2015

    Fund Project: 国家自然科学基金(21273222). (21273222)

  • AgxS crystals were synthesized via hydrothermal (AgxS-H) and in situ ion-exchange (AgxS-IE) methods. The samples were characterized by scanning electron microscopy, X-ray diffraction, ultraviolet-visible-near infrared absorption spectroscopy, N2 adsorption-desorption, X-ray photoelectron spectroscopy and surface photovoltage measurements. The photocatalytic performance was investigated for the decomposition of methyl blue (MB) under visible light irradiation (λ ≥ 420 nm). The AgxS-H had smaller particles, wider band gap and weaker recombination of photoinduced charges than AgxS-IE, resulting in a higher photocatalytic activity. Moreover, AgxS-H was stable, and could be reused five times without loss of photocatalytic activity. Additionally, a possible pathway for the photocatalytic degradation of MB over AgxS has been proposed, that MB was oxidized mainly by hydroxyl radicals and partly via electron holes generated in the AgxS. AgxS-H is an efficient photocatalyst and has great potential for the degradation of harmful organic dyes in wastewater.
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    1. [1]

      [1] Hou Y, Li X Y, Zhao Q D, Chen G H, Raston C L. Environ Sci Technol, 2012, 46: 4042

    2. [2]

      [2] Shannon M A, Bohn P W, Elimelech M, Georgiadis J G, Marinas B J, Mayes A M. Nature, 2008, 452: 301

    3. [3]

      [3] Meshko V, Markovska L, Mincheva M, Rodrigues A E. Water Res, 2001, 35: 3357

    4. [4]

      [4] Cooper P. J Soc Dyers Colour, 1993, 109: 97

    5. [5]

      [5] Patil S S, Shinde V M. Environ Sci Technol, 1988, 22: 1160

    6. [6]

      [6] Moore A T, Vira A, Fogel S. Environ Sci Technol, 1989, 23:403

    7. [7]

      [7] Correia V M, Stephenson T, Judd S J. Environ Technol, 1994, 15: 917

    8. [8]

      [8] Arslan I, Balcioglu I A. Dyes Pigments, 1999, 43: 95

    9. [9]

      [9] Wu F, Deng N S, Zuo Y G. Chemosphere, 1999, 39: 2079

    10. [10]

      [10] Kang S F, Liao C H, Po S T. Chemosphere, 2000, 41: 1287

    11. [11]

      [11] Balanosky E, Fernandez J, Kiwi J, Lopez A. Water Sci Technol, 1999, 40: 417

    12. [12]

      [12] Arslan I, Balcioglu I A, Tuhkanen T. Environ Technol, 1999, 20: 921

    13. [13]

      [13] Ince N H, Gonenc D T. Environ Technol, 1997, 18: 179

    14. [14]

      [14] Kuo W S, Ho P H. Chemosphere, 2001, 45: 77

    15. [15]

      [15] Zhang F L, Zhao J C, Shen T, Hidaka H, Pelizzetti E, Serpone N. Appl Catal B, 1998, 15: 147

    16. [16]

      [16] Qu P, Zhao J C, Shen T, Hidaka H. J Mol Catal A, 1998, 129: 257

    17. [17]

      [17] Galindo C, Jacques P, Kalt A. Chemosphere, 2001, 45: 997

    18. [18]

      [18] Tang W Z, An H. Chemosphere, 1995, 31: 4157

    19. [19]

      [19] Konstantinou I K, Albanis T A. Appl Catal B, 2004, 49: 1

    20. [20]

      [20] Pelaez M, Nolan N T, Pillai S C, Seery M K, Falaras P, Kontos A G, Dunlop P S M, Hamilton J W J, Byrne J A, O'Shea K, Entezari M H, Dionysiou D D. Appl Catal B, 2012, 125: 331

    21. [21]

      [21] Chong M N, Jin B, Chow C W K, Saint C. Water Res, 2010, 44: 2997

    22. [22]

      [22] Wu P G, Xie R C, Imlay J A, Shang J K. Appl Catal B, 2009, 88: 576

    23. [23]

      [23] Rizzo L, Sannino D, Vaiano V, Sacco O, Scarpa A, Pietrogiacomi D. Appl Catal B, 2014, 144:369

    24. [24]

      [24] Chen X, Mao S S. Chem Rev, 2007, 107: 2891

    25. [25]

      [25] Fujishima A, Rao T N, Tryk D A. J Photochem Photobiol C, 2000, 1: 1

    26. [26]

      [26] Tong T Z, Zhang J L, Tian B Z, Chen F, He D N. J Hazard Mater, 2008, 155: 572

    27. [27]

      [27] Tian B Z, Li C Z, Gu F, Jiang H B, Hu Y J, Zhang J L. Chem Eng J, 2009, 151: 220

    28. [28]

      [28] Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y. Science, 2001, 293: 269

    29. [29]

      [29] Niu Y X, Xing M Y, Tian B Z, Zhang J L. Appl Catal B, 2012, 115: 253

    30. [30]

      [30] Zhao W, Ma W H, Chen C C, Zhao J C, Shuai Z G. J Am Chem Soc, 2004, 126: 4782

    31. [31]

      [31] Bae E Y, Choi W Y, Park J W, Shin H S, Kim S B, Lee J S. J Phy Chem B, 2004, 108: 14093

    32. [32]

      [32] Zou W W, Zhang J L, Chen F. Mater Lett, 2010, 64: 1710

    33. [33]

      [33] Xie Y, Heo S H, Kim Y N, Yoo S H, Cho S O. Nanotechnology, 2010, 21: 015703

    34. [34]

      [34] Neves M C, Nogueira J M F, Trindade T, Mendonca M H, Pereira M I, Monteiro O C. J Photochem Photobiol A, 2009, 204: 168

    35. [35]

      [35] Hwang I, Seol M, Kim H, Yong K. Appl Phys Lett, 2013, 103: 023902

    36. [36]

      [36] Yang W L, Zhang L, Hu Y, Zhong Y J, Wu H B, Lou X W. Angew Chem Int Ed, 2012, 51: 11501

    37. [37]

      [37] Xing C S, Zhang Y, Wu Z D, Jiang D L, Chen M. Dalton Trans, 2014, 43: 2772

    38. [38]

      [38] Smart R S C, Skinner W M, Gerson A R. Surf Interface Anal, 1999, 28:101

    39. [39]

      [39] Chen Z, Liu S Q, Yang M Q, Xu Y J. ACS Appl Mater Interfaces, 2013, 5: 4309

    40. [40]

      [40] Bao N Z, Shen L M, Takata T, Domen K. Chem Mater, 2008, 20: 110

    41. [41]

      [41] Butler M A, Ginley D S. J Electrochem Soc, 1978, 125: 228

    42. [42]

      [42] Netherco A H. Phys Rev Lett, 1974, 33: 1088

    43. [43]

      [43] Huxter V M, Mirkovic T, Nair P S, Scholes G D. Adv Mater, 2008, 20: 2439

    44. [44]

      [44] Zhang Y J,Liu Y S, Li C Y, Chen X Y, Wang Q B. J Phys Chem C, 2014, 118: 4918

    45. [45]

      [45] Zhang J K, Liu C L, Zhang X, Ke F, Han Y H, Peng G, Ma Y Z, Gao C X. Appl Phys Lett, 2013, 103: 082116

    46. [46]

      [46] Zuo F, Wang L, Wu T, Zhang Z Y, Borchardt D, Feng P Y. J Am Chem Soc, 2010, 132: 11856

    47. [47]

      [47] Wang H K, Dou K P, Teoh W Y, Zhan Y W, Hung T F, Zhang F H, Xu J Q, Zhang R Q, Rogach A L. Adv Funct Mater, 2013, 23: 4847

    48. [48]

      [48] Hagfeldt A, Gratzel M. Chem Rev, 1995, 95: 49

    49. [49]

      [49] Zhang X, Zhang L Z, Xie T F, Wang D J. J Phys Chem C, 2009, 113: 7371

    50. [50]

      [50] Gross D, Mora-Seró I, Dittrich T, Belaidi A, Mauser C, Houtepen A J, Da Como E, Rogach A L, Feldmann J. J Am Chem Soc, 2010, 132: 5981

    51. [51]

      [51] Fan H M, Jiang T F, Li H Y, Wang D J, Wang L L, Zhai J L, He D Q, Wang P, Xie T F. J Phys Chem C, 2012, 116: 2425

    52. [52]

      [52] Khanchandani S, Srivastava P K, Kumar S, Ghosh S, Ganguli A K. Inorg Chem, 2014, 53: 8902

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