Citation: Bo Tang, Weili Dai, Xiaoming Sun, Guangjun Wu, Landong Li, Naijia Guan, Michael Hunger. Incorporation of cerium atoms into Al-free Beta zeolite framework for catalytic application[J]. Chinese Journal of Catalysis, ;2015, 36(6): 801-805. doi: 10.1016/S1872-2067(14)60277-1 shu

Incorporation of cerium atoms into Al-free Beta zeolite framework for catalytic application

1.
a Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) & Key Laboratory of Advanced Energy Materials Chemistry of Ministry of Education, College of Chemistry, Nankai University, Tianjin 300071, China;

Corresponding author: Weili Dai,
Received Date: 4 November 2014
Available Online: 4 December 2014
Fund Project: 国家自然科学基金(21373119) (21373119) 教育部创新团队(IRT13022, IRT13R30) (IRT13022, IRT13R30) 111计划(B12015) (B12015)

Ce(IV)-containing zeolite Beta was successfully prepared by a reproducible and scalable two-step post-synthesis strategy. This consists of creating vacant T sites that are associated with silanol groups by the dealumination of the H-Beta zeolite and a subsequent dry impregnation of the resultant Si-Beta zeolite with cerium (IV) isopropoxide. XRD, FT-IR, UV-Vis and ¹H MAS NMR confirmed that Ce(IV) was successfully incorporated into the Beta zeolite framework by the post-synthesis procedures and that they exist as isolated atoms with tetrahedral coordination. The mechanism of Ce incorporation into the framework of Beta zeolite was confirmed by DRIFT spectroscopy. The ring-opening hydration of epoxides to their corresponding 1,2-diols was selected as a model reaction for an evaluation of the catalytic performance of the as-synthesized Ce-Beta zeolite.
- Ce-Beta zeolite,
- Post-synthesis,
- Dealumination,
- Ring-opening hydration,
- Epoxide
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沈阳化工大学材料科学与工程学院沈阳 110142