Advanced Search

Citation: Xiaoyan Shi, Hong He, Lijuan Xie. The effect of Fe species distribution and acidity of Fe-ZSM-5 on the hydrothermal stability and SO2 and hydrocarbons durability in NH3-SCR reaction[J]. Chinese Journal of Catalysis, ;2015, 36(4): 649-656. doi: 10.1016/S1872-2067(14)60268-0 shu

The effect of Fe species distribution and acidity of Fe-ZSM-5 on the hydrothermal stability and SO2 and hydrocarbons durability in NH3-SCR reaction

  • 1.

    State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China

  • Corresponding author: Xiaoyan Shi, 
  • Received Date: 4 November 2014
    Available Online: 12 December 2014

    Fund Project: 国家高技术研究发展计划(863计划, 2013AA065301) (863计划, 2013AA065301) 国家自然科学基金(51278486, 51221892). (51278486, 51221892)

  • Fe-exchanged ZSM-5 catalysts prepared from Na+ and H+ forms of ZSM-5 were evaluated for the selective catalytic reduction of NOx by NH3 (NH3-SCR). Fe-H-ZSM-5 showed higher SCR activity than Fe-Na-ZSM-5 both when fresh and after hydrothermal aging at 750 ℃ in 5% H2O/air. The Fe species distribution and acidity of Fe-H-ZSM-5 and Fe-Na-ZSM-5 were found to be different. The dealumination of the zeolite framework of Fe-H-ZSM-5 during hydrothermal aging was found to be more severe compared with that of Fe-Na-ZSM-5. The durability of Fe-H-ZSM-5 and Fe-Na-ZSM-5 in NH3-SCR was compared using SO2 tolerance and hydrocarbon resistance experiments. The effect of water and SO2 on the activity of the two catalysts was similar, such that their activity decreased at low temperatures and increased at high temperatures. Fe-Na-ZSM-5 showed better propene resistance than Fe-H-ZSM-5. The SO2 and propene poisoning of the two Fe-ZSM-5 catalysts were found to be reversible.
  • 加载中
    1. [1]

      [1] Gabrielsson P L T.Top Catal, 2004, 28: 177

    2. [2]

      [2] Brandenberger S, Kröcher O, Tissler A, Althoff R. Catal Rev, 2008, 50: 492

    3. [3]

      [3] Park J H, Park H J, Baik J H, Nam I S, Shin C H, Lee J H, Cho B K, Oh S H. J Catal, 2006, 240: 47

    4. [4]

      [4] Long R Q, Yang R T. J Am Chem Soc, 1999, 121: 5595

    5. [5]

      [5] Torre-Abreu C, Ribeiro M F, Henriques C, Delahay G. Appl Catal B, 1997, 14: 261

    6. [6]

      [6] Coq B, Delahay G, Durand R, Berthomieu D, Ayala-Villagomez E. J Phys Chem B, 2004, 108: 11062

    7. [7]

      [7] Sultana A, Nanba T, Haneda M, Hamada H. Catal Commun, 2009, 10: 1859

    8. [8]

      [8] Sultana A, Nanba T, Haneda M, Sasaki M, Hamada H. Appl Catal B, 2010, 101: 61

    9. [9]

      [9] Sullivan J A, Keane O. Appl Catal B, 2005, 61: 244

    10. [10]

      [10] Brandenberger S, Kröcher O, Casapu M, Tissler A, Althoff R. Appl Catal B, 2010, 101: 649

    11. [11]

      [11] Pieterse J A A, Pirngruber G D, van Bokhoven J A, Booneveld S. Appl Catal B, 2007, 71: 16

    12. [12]

      [12] Krishna K, Seijger G B F, van den Bleek C M, Makkee M, Mul G, Calis H P A. Catal Lett, 2003, 86: 121

    13. [13]

      [13] Chen H, Sachtler W M H. Catal Today, 1998, 42: 73

    14. [14]

      [14] Qi G, Yang R T. Appl Catal B, 2005, 60: 13

    15. [15]

      [15] Lee H T, Rhee H K. Catal Lett, 1999, 61: 71

    16. [16]

      [16] Lobree L J, Hwang I, Reimer J A, Bell A T. J Catal, 1999, 186: 242

    17. [17]

      [17] Brandenberger S, Kröcher O, Tissler A, Althoff R. Appl Catal A, 2010, 373: 168

    18. [18]

      [18] Kumar M S, Schwidder M, Grünert W, Brückner A. J Catal, 2004, 227: 384

    19. [19]

      [19] Castoldi L, Bonzi R, Liett L, Forzatti P, Morandi S, Ghiotti G, Dzwigaj S. J Catal, 2011, 282: 128

    20. [20]

      [20] Eng J, Bartholomew C H. J Catal, 1997, 171: 27

    21. [21]

      [21] Brandenberger S, Kröcher O, Wokaun A, Tissler A, Althoff R. J Catal, 2009, 268: 297

    22. [22]

      [22] Delahay G, Valade D, Guzmán-Vargas A, Coq B. Appl Catal B, 2005, 55: 149

    23. [23]

      [23] Iwasaki M, Yamazaki K, Banbo K, Shinjoh H. J Catal, 2008, 260: 205

    24. [24]

      [24] Iwasaki M, Shinjoh H. Phys Chem Chem Phys, 2010, 12: 2365

    25. [25]

      [25] Cheng Y, Hoard J, Lambert C, Kwak J H, Peden C F F. Catal Today, 2008, 136: 34

    26. [26]

      [26] Schwidder M, Kumar M S, Bentrup U, Pérez-Ramírez J, Brückner A, Grünert W. Microporous Mesoporous Mater, 2008, 111: 124

    27. [27]

      [27] Long R Q, Yang R T. J Catal, 2002, 207: 224

    28. [28]

      [28] Brandenberger S, Kröcher O, Tissler A, Althoff R. Appl Catal B, 2010, 95: 348

    29. [29]

      [29] Høj M, Beier M J, Grunwaldt J D, Dahl S. Appl Catal B, 2009, 93: 166

    30. [30]

      [30] Shi X Y, Liu F D, Shan W P, He H. Chin J Catal (石晓燕, 刘福东, 单文坡, 贺泓. 催化学报), 2012, 33: 454

    31. [31]

      [31] Ma A Z, Grünert W. Chem Commun, 1999: 71

    32. [32]

      [32] Long R Q, Yang R T. J Catal, 1999, 188: 332

    33. [33]

      [33] Long R Q, Yang R T. J Catal, 2000, 194: 80

    34. [34]

      [34] Kim Y J, Kwon H J, Heo I, Nam I S, Cho B K, Choung J W, Cha M S, Yeo G K. Appl Catal B, 2012, 126: 9

    35. [35]

      [35] Heo I, Lee Y, Nam I S, Choung J W, Lee J H, Kim H. Microporous Mesoporous Mater, 2011, 141: 8

    36. [36]

      [36] He C H, Wang Y H, Cheng Y S, Lambert C K, Yang R T. Appl Catal A, 2009, 368: 121

    37. [37]

      [37] Li J H, Zhu R H, Chen Y S, Lambert C K, Yang R T. Environ Sci Technol, 2010, 44: 1799

    38. [38]

      [38] Ma L, Li J H, Cheng Y S, Lambert C K, Fu L X. Environ Sci Technol, 2012, 46: 1747

    39. [39]

      [39] Malpartida I, Marie O, Bazina P, Daturia M, Jeandel X. Appl Catal A, 2011, 102: 190

  • 加载中
    1. [1]

      Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059

    2. [2]

      Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026

    3. [3]

      Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003

    4. [4]

      Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr1-xZrSi2O7∶xDy3+ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096

    5. [5]

      Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V2O5/TiO2 catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

    6. [6]

      Baitong Wei ,  Jinxin Guo ,  Xigong Liu ,  Rongxiu Zhu ,  Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003

    7. [7]

      Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    8. [8]

      Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005

    9. [9]

      Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

    10. [10]

      Lijun Yue ,  Siya Liu ,  Peng Liu . 不同晶相纳米MnO2的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005

    11. [11]

      Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015

    12. [12]

      Xuyang Wang ,  Jiapei Zhang ,  Lirui Zhao ,  Xiaowen Xu ,  Guizheng Zou ,  Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065

    13. [13]

      Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023

    14. [14]

      . 

      CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化

      . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.

    15. [15]

      Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-0. doi: 10.1016/j.actphy.2025.100082

    16. [16]

      Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037

    17. [17]

      Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040

    18. [18]

      Xinyu You ,  Xin Zhang ,  Shican Jiang ,  Yiru Ye ,  Lin Gu ,  Hexun Zhou ,  Pandong Ma ,  Jamal Ftouni ,  Abhishek Dutta Chowdhury . Efficacy of Ca/ZSM-5 zeolites derived from precipitated calcium carbonate in the methanol-to-olefin process. Chinese Journal of Structural Chemistry, 2024, 43(4): 100265-100265. doi: 10.1016/j.cjsc.2024.100265

    19. [19]

      Jiaxi Xu ,  Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049

    20. [20]

      Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(434)
  • HTML views(35)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return