Citation: Tongguang Ge, Zile Hua, Xiaoyun He, Yan Zhu, Wenchao Ren, Lisong Chen, Lingxia Zhang, Hangrong Chen, Chucheng Lin, Heliang Yao, Jianlin Shi. One-pot synthesis of hierarchically structured ZSM-5 zeolites using single micropore-template[J]. Chinese Journal of Catalysis, ;2015, 36(6): 866-873. doi: 10.1016/S1872-2067(14)60263-1 shu

One-pot synthesis of hierarchically structured ZSM-5 zeolites using single micropore-template

1.
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Corresponding author: Zile Hua, Jianlin Shi,
Received Date: 30 October 2014
Available Online: 10 December 2014
Fund Project: 国家重点基础研究发展计划(973计划, 2013CB933200) (973计划, 2013CB933200) 国家高技术研究发展计划(863计划, 2012AA062703) (863计划, 2012AA062703) 国家杰出青年科学基金(51225202) (51225202) 重质油国家重点实验室开放课题(SKLOP201402003). (SKLOP201402003)

An easy one-step hydrothermal process has been developed for the first time for the synthesis of hierarchically structured zeolites (HSZs) using a single micropore template of tetrapropylammonium hydroxide. Compared with conventional constructive dual-templating synthesis and destructive post-demetallation methods, this two-in-one process reduces the mass of porogens required and consequent air pollution by combustion of the template, and simplifies the synthesis. The resultant HSZs were characterized by X-ray diffraction, N₂ adsorption, scanning electron microscopy, transmission electron microscopy, X-ray fluorescence, ²⁷Al nuclear magnetic resonance, and NH₃ temperature programmed desorption. The resultant HSZs with uniform shuttle-type morphology showed high hydrothermal stability and excellent catalytic activity with prolonged life-time in the model reaction of 1,3,5- triisopropylbenzene cracking. A "nucleation/growth-demetallation/recrystallization" mechanism was proposed, which is featured with the integration of zeolite crystallization/growth and basic etching into one hydrothermal process for HSZs production.
- Hierarchically structured zeolite,
- ZSM-5,
- Single template,
- Base etching,
- Catalysis
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