Citation: Fangfang Wei, Weiguo Song, Fang Wei, Changyan Cao. Ordered mesoporous silcalite-1 zeolite assembled from colloidal nanocrystalline precursors[J]. Chinese Journal of Catalysis, ;2015, 36(6): 838-844. doi: 10.1016/S1872-2067(14)60255-2 shu

Ordered mesoporous silcalite-1 zeolite assembled from colloidal nanocrystalline precursors

1.
Beijing National Laboratory for Molecular Sciences, Laboratory for Molecular Nanostructures and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Weiguo Song,
Received Date: 30 September 2014
Available Online: 20 November 2014
Fund Project: 国家自然科学基金(21273244, 21333009和21121063). (21273244, 21333009和21121063)

A series of ordered mesoporous silicalite-1 zeolites has been synthesized by the self-assembly of nanosized zeolite silicalite-1 seeds with different sizes using a two-step procedure. The nanosized silicalite-1 seeds were prepared with an alkali precursor solution that was heated for different periods, and then assembled into ordered mesoporous materials under strongly acidic conditions, similar to that of mesoporous silica SBA-15 which has well ordered hexagonal mesopores and amorphous walls. A significant change in synthesis conditions prevents the continued growth of zeolite seeds and induces assemblage into ordered mesoporous materials templated by triblock copolymers. The samples assembled by zeolite nanoclusters were investigated by X-ray diffraction, electron microscopy, infrared spectroscopy, and N₂ adsorption-desorption isotherms. This "bottom-up" approach yields porous materials that contain ordered micro- and mesopores. The mesoporous zeolite has a large surface area (> 730 m²/g).
- Ordered mesoporous zeolite,
- Self-assembly,
- Bottom-up method,
- Nanosized seed,
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Ordered mesoporous silcalite-1 zeolite assembled from colloidal nanocrystalline precursors

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com