Citation: Tao Chang, Xiaorui Gao, Li Bian, Xiying Fu, Mingxia Yuan, Huanwang Jing. Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids[J]. Chinese Journal of Catalysis, ;2015, 36(3): 408-413. doi: 10.1016/S1872-2067(14)60227-8 shu

Coupling of epoxides and carbon dioxide catalyzed by Brönsted acid ionic liquids

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a Engineering Laboratory for Coalbed Gas Exploitation of Hebei Province, College of Science, Hebei University of Engineering, Handan 056038, Hebei, China;

Corresponding author: Huanwang Jing,
Received Date: 11 August 2014
Available Online: 15 September 2014
Fund Project: 河北省自然科学基金(B2012402001) (B2012402001) 国家自然科学基金(51202054, 21173106). (51202054, 21173106)

A series of Brönsted acid ionic liquids (BAILs) containing a long chain Brönsted acid site in the cationic part and a Lewis basic site in the anionic part were designed, synthesized, and used as catalyst for the coupling of epoxides and carbon dioxide to cyclic carbonates without a co-catalyst or co-solvent. The effects of catalyst structure and other parameters on the catalytic performance were investigated. The long chain 2-(N,N-dimethyldodecylammonium) acetic acid bromide ([(CH₂COOH)DMDA]Br) showed high catalytic activity and good reusability. This protocol was expanded to various epoxides, which gave the corresponding cyclic carbonates in good yields. The acidity of the catalyst influenced its catalytic activity.
- Carbon dioxide fixation,
- Coupling reaction,
- Brönsted acidic ionic liquid,
- Cyclic carbonate,
- Hammett acidity
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