Citation: Tao Wu, Jingwei Wan, Xuebing Ma. Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO₄^2-/Zr(OH)₄-Fe₃O₄[J]. Chinese Journal of Catalysis, ;2015, 36(3): 425-431. doi: 10.1016/S1872-2067(14)60222-9 shu

Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO₄^2-/Zr(OH)₄-Fe₃O₄

1.
School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

Corresponding author: Xuebing Ma,
Received Date: 13 July 2014
Available Online: 2 September 2014
Fund Project: 国家自然科学基金(21071116). (21071116)

Magnetic solid acid catalysts SO₄^2-/Zr(OH)₄-Fe₃O₄ were prepared using magnetic Fe₃O₄ nanoparticles, ZrOCl₂·8H₂O, and sulfuric acid as starting materials in the calcination temperature range 110-650 ℃. The properties of the magnetic solid acid, such as loaded SO₄^2- content, acid distribution, surface morphology, and porous structure, were characterized. In the aqueous asymmetric aldol reaction of various benzaldehydes with strong electron-withdrawing groups (R=NO₂ and CN), good to excellent catalytic performance (83%-100% yield, 86.0%-95.6% ee anti, and anti/syn=88-96/12-4) was achieved. These nanomagnetic solid acids can be quantitatively recycled from the reaction mixture using an external magnet and reused five times without significant loss of catalytic activity.
- Solid acid catalyst,
- Magnetism,
- Aldol reaction,
- Asymmetric catalysis,
- Aqueous phase
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Aqueous asymmetric aldol reaction catalyzed by nanomagnetic solid acid SO₄^2-/Zr(OH)₄-Fe₃O₄